Conductive elastomeric ink composition

• US 4,518,833 A
• Filed: 07/21/1983
• Issued: 05/21/1985
• Est. Priority Date: 07/18/1983
• Status: Expired due to Fees

• Current Assignee: Gates Corporation The
• Original Assignee: Gates Data Products Incorporated
• Inventors: Watkins, Richard L.
• Primary Examiner(s): BARR, JOSEPHINE
• Application Number:
  US06/515,823
• Time in Patent Office: 670 Days
• Field of Search: 252/513, 200/5 R, 200/5 A, 200/159 B, 200/329, 200/340, 200/302, 200/265, 524/439, 524/440, 106/20
• US Class Current: 200/5.00A
• CPC Class Codes: C08K 3/08 Metals
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H01H 13/702 with contacts carried by or formed from layers in a multilayer structure, e.g. membrane switches
• CPC Class Codes: H01H 13/785 characterised by the material of the contacts, e.g. conductive polymers
• CPC Class Codes: H01H 2201/032 Conductive polymer; Rubber
• CPC Class Codes: H01H 2215/008 Part of substrate or membrane
• CPC Class Codes: H01H 2217/02 After travel
• CPC Class Codes: H01H 2221/006 Adhesive
• CPC Class Codes: H01H 2227/014 Conductive particles
• CPC Class Codes: H01H 2227/018 Printed contacts; Metal foil
• CPC Class Codes: H01H 2229/004 Conductive ink
• CPC Class Codes: H01H 2229/058 Curing or vulcanising of rubbers
• CPC Class Codes: H01H 2233/022 with limited freedom
• CPC Class Codes: H05K 1/095 for polymer thick films, i.e. having a permanent organic polymeric binder

Abstract

A conductive elastomeric ink is described comprised of very fine nickel particles admixed in a silicone binder. The ink has utility in elastomeric switch control devices, printed circuits and the like.

Claims

1. A switch device comprising at least one contact and movable contactor for engagement therewith, at least the contact or contactor comprising a dry electrically conductive elastomeric ink composition which comprises an elastomeric cured silicone binder and finely divided nickel particles interspersed therein in an amount from about 25 to about 90 percent by weight based on the weight of the composition, the nickel particles having a size in the range from about 0.05 to about 32 microns.

2. The switch device of claim 1 wherein the size of the nickel particles is in the range from about 0.1 to about 10 microns.

3. The switch device of claim 1 wherein the nickel particles are coated on a particulate substrate.

4. The switch device of claim 3 wherein the substrate is comprised of graphite.

5. The switch device of claim 1 wherein the binder is formed of an addition cured elastomeric silicone polymer which has undergone linear shrinkage of at least about 3 percent during cure.

6. A flexible switch control device movable contactor to which is adhered a layer of the ink composition of claim 1.

7. The switch control device of claim 6 wherein the nickel particles are coated on a particulate substrate.

8. The switch control device of claim 7 wherein the substrate is comprised of graphite.

9. The switch control device of claim 6 wherein the binder is formed of an addition cured elastomeric silicone polymer which has undergone linear shrinkage of at least about 3 percent during cure.

10. A keyboard assembly comprising:

a printed circuit board having conductive traces and contacts thereon; and

a plurality of keyswitch assemblies individually overlying contact of the printed circuit board, and individually comprising a keyholder housing having an aperture therein, a switch control device contained within the housing and having a movable contactor portion, and a key top mounted to said housing and including means passable through said aperture for transmitting force applied to the key top to the switch control device, for actuating a switch device; and

wherein

at least one of said conductive traces, contact or contactor portion comprises a dry electrically conductive elastomeric ink composition which comprises an elastomeric cured silicone binder and finely divided nickel particles interspersed therein in an amount from about 25 to about 90 percent by weight based on the weight of the composition and wherein the nickel particles have a size from about 0.05 to about 32 microns.

11. A switch device comprising an elastomeric switch control device having a movable contactor portion thereon, and at least one contact engageable with said movable contactor, at least the contactor comprising a dry electrically conductive elastomeric ink composition which is normally conductive when the movable contactor and contact are engaged together, which ink composition comprises an elastomeric cured silicone binder and finely divided nickel particles interspersed therein in a amount from about 25 to about 90 percent by weight based on the weight of the composition, the nickel particles having a size in the range from about 0.1 to about 10 microns, the binder being formed of a cured elastomeric silicone polymer which has undergone linear shrinkage of at least about 3 percent during cure, and the ink composition being self-adhered to the elastomeric switch control device.

12. The switch device of claim 11 wherein the finely divided nickel particles have a size in the range from about 0.1 to about 1 microns.

13. The switch device of claim 11 wherein the nickel particles are coated on a particulate carbonaceous substrate.

14. The switch device of claim 13 wherein the carbonaceous substrate is graphite.

15. The switch device of claim 11 wherein the elastomeric switch control device is formed of silicone polymer and wherein the binder of the ink composition is formed of an addition cured elastomeric silicone polymer which has undergone linear shrinkage of at least about 6 percent during cure.

16. A switch device comprising a contact member and an elastomeric switch control device having a movable contactor thereon for engagement with the contact member, at least the contactor comprising a dry electrically conductive elastomeric ink composition which comprises an elastomeric cured silicone binder and conductive particles interspersed therein comprising particulate graphite on which is coated on the surface thereof finely divided nickel particles having a size in the range from about 0.05 to about 5 microns, the nickel coated graphite particles being interspersed in the silicone binder in an amount from about 25 to about 90 percent by weight based on the weight of the ink composition.

17. The switch device of claim 16 wherein the ink composition is self-adhered to the elastomeric switch control device, and both the elastomeric switch control device and the binder forming a portion of the ink composition are formed of an addition cured elastomeric silicone polymer which has undergone linear shrinkage of at least about 3 percent during cure.