Hydrocarbon gas separation

• US 4,519,824 A
• Filed: 11/07/1983
• Issued: 05/28/1985
• Est. Priority Date: 11/07/1983
• Status: Expired due to Fees

• Current Assignee: The Randall Corporation
• Original Assignee: The Randall Corporation
• Inventors: Huebel, Robert R.
• Primary Examiner(s): Sever, Frank
• Application Number:
  US06/549,044
• Time in Patent Office: 568 Days
• Field of Search: 62/9, 62/11, 62/23, 62/24, 62/27, 62/28, 62/29, 62/30, 62/31, 62/32, 62/33, 62/34, 62/38, 62/39, 62/26, 62/25
• US Class Current: 62/621
• CPC Class Codes: C07C 7/09 by fractional condensation
• CPC Class Codes: C07C 9/02 with one to four carbon atoms liquefied petroleum gas C10L3/12
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2210/06 Splitting of the feed stream, e.g. for treating or cooling in different ways
• CPC Class Codes: F25J 2210/12 Refinery or petrochemical off-gas
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0219 Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more

Abstract

A cryogenic process for separating methane from ethane and heavier hydrocarbons in which a high pressure gas feed is divided into two gas streams. The gas is cooled either before or after it is divided and this step may include some condensation in which case the condensate is separated from the gas. One of the divided gas streams is expanded through a work expansion machine down to the pressure of the fractionation column. Any separated condensate is also expanded to the column pressure. The second divided gas stream is further cooled by heat exchange and then expanded down to an intermediate pressure whereby a portion is condensed. This condensate is separated from the remaining gas and then expanded to the column pressure. The remaining gas is further cooled and expanded and fed to the column as the top feed.

Claims

1. In a process for the separation of a feed gas containing methane and ethane into a volatile residue gas containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said ethane wherein methane and ethane together comprise a major portion of said feed gas and wherein said feed gas is cooled under relatively high pressure and then expanded to a relatively low pressure whereby it is further cooled and said further cooled feed stream is fractionated at said relatively low pressure in a fractionation column wherein the overhead temperature is maintained at a temperature whereby the major portion of said ethane is recovered in said less volatile fraction at the bottom of said fractionation column;

the improvement comprising;

(a) dividing said feed gas into first and second cooled gaseous streams,

(b) expanding said first gaseous stream to said relatively low pressure,

(c) further cooling said second gaseous stream at said relatively high pressure and then expanding to an intermediate pressure such that a portion of said second gaseous stream is condensed,

(d) separating said condensed portion from the remaining gaseous portion of said second gaseous stream,

(e) expanding said separated condensed portion of said second gaseous steam to said relatively low pressure,

(f) further cooling said separated remaining gaseous portion of said second gaseous stream and then expanding to said relatively low pressure, and

(g) feeding said expanded first gaseous stream (b), said expanded condensed portion of said second gaseous stream (e) and said expanded remaining gaseous portion of said second gaseous stream (f) to said fractionation column at first, second and third feed points, respectively, said third feed point being the top column feed and said second and third feed point being at lower column positions.

2. In a process according to claim 1 wherein said second feed point is above said first feed point.

3. In a process according to claim 1 wherein said feed gas is cooled prior to dividing said feed gas into said first and second cooled gaseous streams.

4. In a process according to claim 3 wherein said feed gas is cooled sufficiently to condense a portion thereof and said condensed portion of said feed gas is separated from the remaining gaseous portion of said feed gas prior to dividing said feed gas into said first and second cooled gaseous streams.

5. In a process according to claim 4 wherein said condensed portion of said feed gas is expanded to said relatively low pressure and fed to said fractionation column at a fourth feed point below said first, second and third feed points.

6. In a process according to claim 4 wherein said condensed portion of said feed gas is expanded to said relatively low pressure and combined with said expanded first gaseous stream (b) for feed to said fractionation column.

7. In a process according to claim 1 wherein that portion of said second gaseous stream which is condensed (c) comprises from 30 to 60% liquid on a molar basis.

8. In a process according to claim 1 wherein said first gaseous stream (b) is expanded in a work expansion machine.