Low severity delayed coking

• US 4,519,898 A
• Filed: 05/20/1983
• Issued: 05/28/1985
• Est. Priority Date: 05/20/1983
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Allan, David E.
• Primary Examiner(s): Gantz, D. E.
• Assistant Examiner(s): Caldarola, Glenn A.
• Application Number:
  US06/496,570
• Time in Patent Office: 739 Days
• Field of Search: 208/131, 208/50, 208/106
• US Class Current: 208/131
• CPC Class Codes: C10B 55/00 Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material cracking oils C10G

Abstract

A delayed coking process is conducted at a relatively low temperature with the introduction of a gas into the coking drum to strip volatile matter from the coke product and to form coke containing 6 to 12 weight percent volatile matter. Low temperature delayed coking decreases the amount of coke yield, calculated on a volatile-free basis, and increases liquid yield.

Claims

1. In a delayed coking process which comprises the steps of:

(a) preheating a hydrocarbonaceous oil feed to a coking temperature, and

(b) introducing the resulting preheated oil into a coking drum operated at delayed coking conditions to form coke and a vapor phase product,

the improvement which comprises;

said oil feed being preheated to a temperature ranging from about 775°

to 920°

F., and introducing a gas into said coking drum during step (b), in an amount ranging from about 10 to about 20 weight percent of said preheated oil to maintain the content of volatile matter of said coke in the range of about 5 to about 15 weight percent.

2. The process of claim 1 wherein said gas is selected from the group consisting of steam, nitrogen, normally gaseous hydrocarbons and mixtures thereof.

3. The process of claim 1 wherein said oil feed is preheated to a temperature ranging from about 850°

to about 900°

F.

4. The process of claim 1 wherein said gas comprises steam.

5. The process of claim 1 wherein said hydrocarbonaceous oil has a Conradson carbon content of at least about 5 weight percent.

6. The process of claim 1 wherein the volatile matter of said coke ranges from about 6 to about 12 weight percent.

7. The process of claim 1 wherein said gas is added to said preheated oil of step (b).

8. The process of claim 1 wherein said gas is added to said oil feed prior to said preheating step.