Non-aqueous electrochemical cell and electrolyte

• US 4,520,083 A
• Filed: 03/02/1983
• Issued: 05/28/1985
• Est. Priority Date: 03/02/1983
• Status: Expired due to Fees

• Current Assignee: Standard Oil Company (BP PLC)
• Original Assignee: Standard Oil Company (BP PLC)
• Inventors: Connolly, John F., Thrash, Robert J., Prater, Keith B.
• Primary Examiner(s): Hearn, Brian E.
• Assistant Examiner(s): Kalafut, Stephen J.
• Application Number:
  US06/471,429
• Time in Patent Office: 818 Days
• Field of Search: 429/101, 429/105, 429/194, 429/196, 429/197, 429/198, 429/199, 429/201, 429/203
• US Class Current: 429/101
• CPC Class Codes: H01M 10/36 Accumulators not provided for in groups H01M10/05-H01M10/34
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Disclosed is an ambient temperature, rechargeable non-aqueous electrochemical cell having an active metal anode of the second kind, a cathode depolarizer, positive electrode current collector and an electrolyte comprising a solvent, a supporting electrolyte salt, and an active metal salt. Also disclosed is an electrolyte for non-aqueous active metal cells.

Claims

1. A non-aqueous, rechargeable electrochemical cell comprising:

(a) an active metal anode;

(b) a positive electrode current collector;

and

(c) an electrolyte comprising a salt of said active metal, an ionizing solvent comprising sulfur dioxide, and a supporting electrolyte salt comprising at least one component of the general form R⁺ X^-, wherein R⁺ is a cation different from the cation of said active metal, and X^- is an anion which forms a salt with the cation of said active metal which is less soluble in said cell than R⁺ X^- ;

wherein the saturated concentration of said active metal cation in said electrolyte is between about 10^-9 eq/l and about 10^-1 eq/l, and said electrolyte is substantially saturated with respect to the active metal cation, whereby an insoluble product is formed at the anode upon discharge of the cell.

2. The cell of claim 1 wherein said anode comprises at least one metal selected from the group consisting of lithium, sodium, potassium, beryllium, magnesium, and calcium.

3. The cell of claim 2 wherein said electrolyte comprises:

(a) an ionizing solvent comprising sulfur dioxide;

(b) a salt of said active metal having at least one cationic component comprising the cation of the active anode metal, and at least one anionic component comprising the anion of the supporting electrolyte salt; and

(c) a supporting electrolyte salt wherein R⁺ comprises at least one cation selected from the group consisting of metal ion complexes and nitrogen and phosphorus organic cations, and X^- comprises at least one anion selected from the group consisting of anions of oxyhalides and oxyacids.

4. The cell of claim 3 wherein said ionizing solvent consists essentially of sulfur dioxide.

5. The cell of claim 3 wherein said active metal comprises lithium and said active metal salt comprises at least one compound selected from the group consisting of LiClO₄ and Li₂ S₂ O₄.

6. The cell of claim 3 wherein R⁺ comprises at least one material selected from the group of cations consisting of alkali metals complexed with crown ethers, alkali metals complexed with cryptands, transition metals complexed with ligands and chelates, transition metals complexed with chelating ligands, the cations of quaternary ammonium and phosphonium salts and N-hydrocarbo heterocyclic cations.

7. The cell of claim 6 wherein R⁺ comprises at least one cation selected from the group consisting of Mn(2,2'"'"'-dipyridyl)₃⁺⁺, Mn(1,10-phenanthroline)₃⁺⁺ and (n-butyl)₄ N⁺.

8. The cell of claim 6 wherein R⁺ comprises Mn(2,2'"'"'-dipyridyl)₃⁺⁺.

9. The cell of claim 6 wherein R⁺ comprises Mn(1,10-phenanthroline)₃⁺⁺.

10. The cell of claim 6 wherein R⁺ comprises (n-butyl)₄ N⁺.

11. The cell of claim 6 wherein R⁺ comprises a quaternary ammonium cation.

12. The cell of claim 6 wherein X^- comprises at least one anion selected from the group consisting of perchlorate and dithionite.