Process for production of sugars and optionally cellulose and lignin from lignocellulosic raw materials

• US 4,520,105 A
• Filed: 08/10/1983
• Issued: 05/28/1985
• Est. Priority Date: 08/17/1977
• Status: Expired due to Fees

• Current Assignee: BAU- und Forschungsgesellschaft Thermoform AG
• Original Assignee: BAU- und Forschungsgesellschaft Thermoform AG
• Inventors: Puls, Jurgen, Sinner, Michael, Brachthauser, Karl-Heinz, Dietrichs, Hans-Hermann, Schweers, Werner
• Primary Examiner(s): Smith, William F.
• Application Number:
  US06/521,657
• Time in Patent Office: 657 Days
• Field of Search: 162/17, 162/18, 162/19, 162/72, 162/77, 127/37, 435/161, 435/163
• US Class Current: 435/163
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: C13K 13/002 Xylose
• CPC Class Codes: D21C 3/20 with organic solvents or in solvent environment

Abstract

A process for the production of sugars, and optionally cellulose and lignin, from lignocellulosic vegetable materials which comprises subjecting the vegetable materials to a chemical pretreatment with a mixture of water and lower aliphatic alcohols and/or ketones at a temperature from 100° to 190° C. for a period of from 4 hours to 2 minutes with control of the breakdown of the hemicellulose components followed by separation of residue and a subsequent main chemical treatment with a similar solvent mixture at elevated temperatures for a further period of from 6 hours to 2 minutes.

Claims

1. A process for treating vegetable material essentially comprised of cellulose, lignin and hemicelluloses, comprising the steps of:

(a) treating said vegetable material under elevated pressure with a first solution comprising (i) water and acetone in a volume ratio between about 70;

30 and 30;

70, and (ii) at least one acid, said acid having a concentration, relative to the total volume of said first solution, of between about 0.001 and about 1N, at a temperature between about 170° and

about 220°

C., such that substantially all of said lignin and said hemicelluloses are dissolved in said first solution and a residue comprising microcrystalline cellulose is formed;

(b) separating said residue from said first solution; and

(c) after step (b), treating said residue with a second solution comprising (i) water and acetone in a volume ratio between about 70;

30 and 30;

70, and (ii) at least one acid, said acid having a concentration, relative to the total volume of said first solution, of between about 0.001 and about 1N, at a temperature between about 170° and

about 220°

C., such that said microcrystalline cellulose is substantially completely hydrolyzed to glucose, said glucose being dissolved in said second solution.

2. A process according to claim 1, further comprising after step (a) vacuum distilling said first solution such that said lignin separates from said first solution.

3. A process according to claim 1, further comprising after step (c) the steps of (d) separating at least said acetone from said second solution to form an aqueous solution containing said glucose and (e) fermenting said glucose to alcohol.

4. A process according to claim 3, wherein step (d) comprises separating said acetone and said acid from said second solution.

5. A process according to claim 1, wherein step (a) is carried out at a temperature between about 180°

and about 200°

C., and for a period between about 5 and about 30 minutes.

6. A process according to claim 1, wherein step (c) is carried out at a temperature between about 180°

and about 210°

C., and for a period of between about 5 and about 60 minutes.

7. A process according to claim 1, wherein said concentration of said acid in said first solution is between about 0.01 and about 0.5N, and said concentration of said acid in said second solution is between about 0.01 and about 0.1N.

8. A process according to claim 1, wherein step (c) comprises stepwise treating said residue in a plurality of separate volumes of said second solution by replacing said solution with fresh solution every 3 to 15 minutes.

9. A process according to claim 8, wherein said replacing of said solution is carried out in a continuous manner.

10. A process according to claim 1, wherein said acid in each of said first and second solutions is separately selected from the group consisting of nitric acid, phosphoric acid, sulfuric acid, and hydrochloric acid.

11. A process according to claim 10, wherein said acid is hydrochloric acid or sulfuric acid.