Thin layer electrochemical cell for rapid detection of toxic chemicals

• US 4,521,290 A
• Filed: 03/16/1984
• Issued: 06/04/1985
• Est. Priority Date: 03/16/1984
• Status: Expired due to Term

• Current Assignee: Honeywell Incorporated (Honeywell International Inc.)
• Original Assignee: Honeywell Incorporated (Honeywell International Inc.)
• Inventors: Venkatasetty, Hanumanthiya V.
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US06/590,309
• Time in Patent Office: 445 Days
• Field of Search: 204/412, 204/415, 204/411, 204/431, 204/432
• US Class Current: 204/412
• CPC Class Codes: G01N 27/4045 for gases other than oxygen

Abstract

A thin-layer electrochemical cell for rapid detection of toxic chemicals and chemical agents having a large area thin-film sensing electrode in contact with a very thin layer of nonaqueous aprotic organic based electrolyte solution, and having the reference electrode on the same plane and the counter electrode positioned in a different plane beyond the edge of the large area sensing electrode.

Claims

1. A nonaqueous electrochemical cell sensor structure for detection of toxic gas or vapor molecules in the surrounding atmosphere comprising:

an enclosure for electrochemical cell means, said enclosure having an opening on one face for admitting gases and vapors to be sensed from the surrounding atmosphere;

a porous polymer membrane having an outer and an inner surface, a substantial portion of the inner surface of said membrane being coated with an inert thin conducting film which forms a sensing electrode, the outer surface at said opening being in communication with said atmosphere which may at times contain molecules of gas or vapor sought to be detected;

a reference electrode fabricated on a separate portion of said inner surface by coating said membrane separate portion with a metal/metal ion film;

a counter electrode inert film located beyond the edge of said membrane and electrically separated from said sensing and reference electrodes; and

,

a thin layer of nonaqueous electrolyte solution in said enclosure in contact with said electrodes.

2. The structure according to claim 1 in which said porous polymer membrane is polytetrafluoroethylene.

3. The structure according to claim 1 in which said film of inert conducting material is selected from the group consisting of platinum, gold and carbon.

4. The structure according to claim 1 in which said inert conducting material is platinum.

5. The structure according to claim 1 in which said metal/metal ion film is silver/silver ion.

6. The structure according to claim 1 in which said metal/metal ion film is silver/silver chloride.

7. The structure according to claim 1 in which the membrane is of a non-wetting material with respect to said nonaqueous electrolyte solution.

8. The structure according to claim 1 in which said reference electrode is planar with said sensing electrode.

9. The structure according to claim 1 in which said nonaqueous electrolyte solution consists of a solvent selected from the group consisting of γ

-butyrolactone, propylene carbonate and N,N'"'"' dimethylformamide, and of an electrolyte selected from the group consisting of lithium perchlorate, tetraalkyl ammonium perchlorate and tetraethylammonium perchlorate.

10. A nonaqueous electrochemical cell sensor structure for detection of toxic gas or vapor molecules in the surrounding atmosphere comprising:

a porous polymer membrane permeable to molecules of gas or vapor sought to be detected, said membrane having an outer surface in communication with said atmosphere which may at times contain molecules of said gas or vapor, said membrane having an inner surface of which a major portion is coated with a thin film of an inert conducting material which forms a permeable sensing electrode on said inner surface;

a thin-film reference electrode planar with said sensing electrode fabricated on a remaining and separate portion of said inner surface near the edge of said membrane, by coating the separate portion with a metal/metal ion film to form the reference electrode;

a counter electrode inert conducting material film located beyond the edge of said membrane and electrically separated from said sensing and reference electrodes; and

,

a thin layer of nonaqueous electrolyte solution in contact with said sensing, reference and counter electrodes.

11. The structure according to claim 10 in which said porous polymer membrane is polytetrafluoroethylene.

12. The structure according to claim 10 in which said film of inert conducting material is selected from the group consisting of platinum, gold and carbon.

13. The structure according to claim 10 in which said inert conducting material is platinum.

14. The structure according to claim 10 in which said metal/metal ion film is silver/silver ion.

15. The structure according to claim 10 in which said metal/metal ion film is silver/silver chloride.

16. The structure according to claim 10 in which the membrane is of a non-wetting material with respect to said nonaqueous electrolyte solution.

17. The structure according to claim 10 in which said reference electrode is planar with said sensing electrode.

18. The structure according to claim 10 in which said nonaqueous electrolyte solution consists of a solvent selected from the group consisting of γ

-butyrolactone, propylene carbonate and N,N'"'"' dimethylformamide, and of an electrolyte selected from the group consisting of lithium perchlorate and tetraethylammonium perchlorate.

19. A nonaqueous electrochemical cell sensor structure for detection of trace quantities of gas or vapor molecules comprising:

an electrochemical cell structure which includes a two-electrode supporting polymer membrane, said membrane being porous to molecules of gas or vapor sought to be detected;

said porous membrane having an outer and an inner surface, the outer surface of which is in communication with an atmosphere which may contain molecules of said gas or vapor, the inner surface being coated in large measure by an inert thin conducting film forming a sensing electrode, and said inner surface being coated at a smaller separate area by a metal/metal ion film forming a reference electrode;

said cell structure also including a counter electrode located beyond the edge of said membrane and in a plane different from said membrane and electrodes, said counter electrode comprising a film coating of conductive inert material; and

,

a thin layer of nonaqueous electrolyte solution adjacent and enveloping said sensing and reference electrode and also extending to envelop said counter electrode.

20. A nonaqueous electrochemical cell sensor structure for detection of toxic gas or vapor molecules in the surrounding atmosphere comprising:

an enclosure for electrochemical cell means, said enclosure having an opening on one face for admitting gases and vapors to be sensed from the surrounding atmosphere;

a porous polytetrafluoroethylene membrane having an outer and an inner surface, a substantial portion of the inner surface of said membrane being coated with an inert thin conducting film which forms a sensing electrode, the film material being selected from the group consisting of platinum, gold, and carbon, the outer surface at said opening being in communication with said atmosphere which may at times contain molecules of gas or vapor sought to be detected;

a reference electrode coated on a separate portion of said inner surface by coating said membrane separate portion with a silver/silver ion film, said silver/silver ion film being planar with said sensing electrode;

a counter electrode inert film located beyond the edge of said membrane and electrically separated from said sensing and reference electrodes; and

,

a thin layer of nonaqueous electrolyte solution in said enclosure in contact with said electrodes.

21. The structure according to claim 20 in which said nonaqueous electrolyte solution consists of a solvent selected from the group consisting of γ

-butyrolactone, propylene carbonate and N,N'"'"' dimethylformamide, and of an electrolyte selected from the group consisting of lithium perchlorate, tetraalkyl ammonium perchlorate and tetraethylammonium perchlorate.

22. The structure according to claim 20 wherein said silver/silver ion is silver/silver chloride.