Lubricant compositions containing both hydrocarbyl substituted mono and bissuccinimide having polyamine chain linked hydroxacyl radicals, and neopentyl derivative

• US 4,521,318 A
• Filed: 11/14/1983
• Issued: 06/04/1985
• Est. Priority Date: 11/14/1983
• Status: Expired due to Fees

• Current Assignee: Texaco Incorporated (Chevron Corp.)
• Original Assignee: Texaco Incorporated (Chevron Corp.)
• Inventors: Karol, Thomas J.
• Primary Examiner(s): Niebling, John F.
• Application Number:
  US06/551,543
• Time in Patent Office: 568 Days
• Field of Search: 252/51.5 A, 252/46.7
• US Class Current: 508/291
• CPC Class Codes: C10M 133/56 Amides; Imides
• CPC Class Codes: C10M 141/10 at least one of them being an organic phosphorus-containing compound
• CPC Class Codes: C10M 2215/04 having amino groups bound to acyclic or cycloaliphatic carbon atoms
• CPC Class Codes: C10M 2215/042 containing hydroxy groups; Alkoxylated derivatives thereof
• CPC Class Codes: C10M 2215/26 Amines
• CPC Class Codes: C10M 2215/28 Amides; Imides
• CPC Class Codes: C10M 2217/046 Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
• CPC Class Codes: C10M 2217/06 Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
• CPC Class Codes: C10M 2225/041 Hydrocarbon polymers

Abstract

A lubricant composition comprising a major amount of a lubricating oil and an effective dispersant amount of both a hydrocarbyl-substituted mono- and bis-succinimide having polyamine chain linked hydroxyacyl radicals, and a polyol derivative prepared by contacting an aliphatic polyolefin with P₂ S₅ in the presence of sulfur and P₂ S₅, contacting the resultant polyolefin-P₂ S₅ reaction product with a steam, removing inorganic phosphorus acid from the steam treated polyolefin P₂ S₅ reaction product, and contacting the polyolefin P₂ S₅ reaction product with a neopentyl polyol. The combination of succinimide and polyol derivative exhibit enhanced dispercancy and/or detergency over either additive alone.

Claims

1. A lubricant composition comprising a major amount of a lubrication oil from about 0.06 to 0.07 weight percent based on nitrogen of a hydrocarbyl-substituted mono- and bis-succinimide having polyamine chain linked hydroxyacyl radicals represented by the formula:

##STR9## in which R is a hydrocarbyl radical having from about 8 to 400 carbon atoms, X is a divalent alkylene or secondary hydroxy substituted alkylene radical having from 2 to 3 carbon atoms, A is hydrogen or a hydroxyacyl radical selected from the group consisting of glycolyl, lactyl, 2-hydroxy-methyl propionyl and 2,2'"'"'-bis-hydroxymethyl propionyl radicals and in which at least 30 percent of said radicals represented by A are said hydroxyacyl radicals, x is a number from 1 to 6, and R'"'"' is a radical selected from the group consisting of --NH₂, --NHA, or a hydrocarbyl substituted succinyl radical having the formula;

##STR10## in which R has the values noted above; and

from about 1 to 3 weight percent of a polyol derivative prepared by the method comprising (a) contacting an aliphatic polyolefin of an average molecular weight between about 250 and 50,000 with P₂ S₅ in the presence of between about 0.1 and 5 wt. percent sulfur at a temperature of between about 100° and

320°

C., P₂ S₅ comprising between about 5 and 40 wt. percent of the reaction mixture, (b) contacting the resultant polyolefin-P₂ S₅ reaction product with steam at a temperature between about 100° and

260°

C. utilizing at least about a mole ratio excess of steam in respect to said polyolefin-P₂ S₅ reaction product, (c) removing inorganic phosphorus acid from the steam treated polyolefin-P₂ S₅ reaction product, (d) contacting the inorganic acid free, steam hydrolyzed polyolefin-P₂ S₅ reaction product with a neopentyl polyol of the formula;

##STR11## where R'"'"'" and R^IV are selected from the group consisting of alkylol and alkyl of from 1 to 20 carbon atoms at a temperature between about 180° and

220°

C. in a mole ratio of said inorganic phosphorus acid free, steam hydrolyzed P₂ S₅ -polyolefin reaction product to said polyol of between about 1;

0.33 and 1;

2 to form said polyol derivative.

2. The lubricant composition of claim 1 in which at least 50 percent of said radicals represented by A in said succinimide are hydroxyacyl radicals.

3. The lubricant composition of claim 1 in which substantially all of said radicals represented by A in said succinimide are hydroxyacyl radicals.

4. The lubricant composition of claim 1 in which 50 to 100 percent of said radicals represented by A in said succinimide are glycolyl radicals.

5. The lubricant composition of claim 1 in which at least 70 percent of said radicals represented by A in said succinimide are glycolyl radicals.

6. The lubricant composition of claim 1 in which 50 to 100 percent of said radicals represented by A in said succinimide are lactyl radicals.

7. The lubricant composition of claim 1 in which R is an alkenyl radical having from about 50 to 200 carbon atoms, X is a divalent --CH₂ --CH₂ --, or --CH₂ --CHOH--CH₂ -- radical, A is hydrogen or a glycolyl radical in which 50 to 100 percent of said radicals represented by A is said glycolyl radical, x is a number from 2 to 4, and R'"'"' is a radical selected form the group consisting of --NH₂ and --NHA in which A has the value noted above.

8. The lubricant composition of claim 1 in which R is an alkenyl radical having from about 50 to 200 carbon atoms, X is a divalent --CH₂ --CH₂ --, or a divalent --CH₂ --CHOH--CH₂ -- radical, A is hydrogen or a glycolyl radical in which at least 70 percent of said radicals represented by A are said glycolyl radical, x is a number from 2 to 4 and R'"'"' is a radical selected from the group consisting of --NH₂ and --NHA in which A has the value noted above.

9. The lubricant composition of claim 1 in which during the preparation of said polyol derivative the polyolefin-P₂ S₅ reaction mixture of said "a" step, prior to contact with steam in said "b" step, is diluted with a mineral lubricating oil of an SUS viscosity between about 50 to 1000 to form a diluted polyolefin-P₂ S₅ reaction mixture having a mineral lubricating oil content of between about 25 and 75 wt. percent and contacting the resultant lubricating oil solution in accordance with said "b", "c" and "d" steps.

10. The lubricant composition of claim 9 in which said polyolefin is polyisobutene said polyol is trimethylol propane.

11. The lubricant composition of claim 9 in which said polyolefin is polyisobutene and said polyol is pentaerythritol.

12. The lubricant composition of claim 9 in which said polyolefin is polyisobutene and said polyol is neopentyl glycol.

13. A concentrate comprising from about 1 to about 80 percent by weight of said succinimide and from about 10 to about 80 percent by weight of said derivative of polyol as set forth in claim 1, with the remainder comprising a lubricating oil.