Method and apparatus for regulating the NH.sub.3 content in scrubbing liquid used in a gas scrubbing process

• US 4,522,638 A
• Filed: 05/22/1984
• Issued: 06/11/1985
• Est. Priority Date: 10/21/1981
• Status: Expired due to Fees

• Current Assignee: Linde AG (Linde Plc)
• Original Assignee: Linde AG (Linde Plc)
• Inventors: Karwat, Heinz
• Primary Examiner(s): Therkorn, Ernest G.
• Application Number:
  US06/612,885
• Time in Patent Office: 385 Days
• Field of Search: 55/36, 55/37, 55/46, 55/48, 55/68, 55/70, 55/73, 55/228, 71/40, 71/41, 71/43, 210/702, 423/226, 423/227, 423/228, 423/237, 423/238, 423/549, 423/550, 423/312, 423/313
• US Class Current: 95/166
• CPC Class Codes: B01D 53/1412 Controlling the absorption process
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1456 Removing acid components

Abstract

A process for regulating the NH₃ content in an organic liquid that acts as a physical scrubbing agent and is used in a procedure for absorbing sour gases from gaseous mixtures. To ensure undisturbed and reliable carrying out of the scrubbing process, an ammonia-precipitating precipitant is added to the scrubbing agent and the precipitate is then separated from the scrubbing agent. Preferred precipitants include sulphuric acid and phosphuric acid. The ammonia salts are effective fertilizers.

Claims

1. A process for regulating the NH₃ content of an organic liquid which acts as a physical scrubbing agent and is used in a procedure for removing sour gases from gaseous mixtures, said liquid being freed from the absorbed gaseous components after the scrubbing procedure and being reused in the circuit, comprising adding an acid precipitant to the scrubbing agent to precipitate ammonia salts thereform and separating the resultant precipitant from the scrubbing agent, further comprising cooling the scrubbing agent after precipitation to a temperature in the range of about 0°

to -95°

C., preferably 0°

to -40°

, said scrubbing agent containing reaction products, ammonia being removed from the scrubbing agent to the extent of leaving a residue of 300-2000 mg/kg, preferably 500-1000 mg/kg, which combines with the scrubbing agent to enchance scrubbing effectiveness.

2. The process of claim 1 wherein precipitant is added to only a portion of the scrubbing agent in the circuit.

3. The process of claim 1 wherein the precipitant comprises sulphuric acid.

4. The process of claim 1 wherein the precipitant comprises phosphoric acid.

5. The process of claim 1 wherein the precipitate is removed from the scrubbing agent by decanting.

6. The process of claim 1 wherein the precipitate is removed from the scrubbing agent by filtering.

7. The process of claim 1 wherein the precipitate is removed from the scrubbing agent by centrifuging.

8. The process of claim 1 wherein the step of separating the precipitate comprises evaporating the scrubbing agent.

9. The process of claim 1 wherein the ammonia is precipitated at temperatures in the range of about 0°

-60°

C., preferably in the range of 10°

-50°

C.