Rope batteries

• US 4,522,897 A
• Filed: 10/14/1983
• Issued: 06/11/1985
• Est. Priority Date: 10/14/1983
• Status: Expired due to Fees

• Current Assignee: Cape Cod Research, Inc.
• Original Assignee: Cape Cod Research, Inc.
• Inventors: Walsh, Myles A.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/541,902
• Time in Patent Office: 606 Days
• Field of Search: 429/127, 429/119
• US Class Current: 429/119
• CPC Class Codes: H01M 4/08 Processes of manufacture
• CPC Class Codes: H01M 4/46 Alloys based on magnesium or aluminium
• CPC Class Codes: H01M 4/661 Metal or alloys, e.g. alloy coatings H01M4/669 take precedence
• CPC Class Codes: H01M 4/663 containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
• CPC Class Codes: H01M 6/04 Cells with aqueous electrolyte
• CPC Class Codes: H01M 6/34 Immersion cells, e.g. sea-water cells

Abstract

A flexible, water activated electrochemical cell and battery suitable generally for application in marine devices requiring low power levels for long periods of time without maintenance or replacement is fabricated in the shape of a rope. This novel shape permits extension of the rope battery cells over long distances and greatly increases the rates at which deleterious reaction products can be liberated to the surrounding water and thus greatly improves the efficiency of low drain water activated batteries.

Claims

1. A structure for a rope battery employing sea water as the electrolyte comprising a flexible rope which is relatively long compared to its diameter and which consists essentially of a flexible inner core, wherein said inner core comprises at least one continuous, flexible, solid wire, wherein said inner core is surrounded by a thin, porous, flexible insulating separator sleeve which is in turn surrounded by a thin outer flexible layer consisting essentially of twisted, felted or braided strands of metal or graphite, and wherein said inner core consists essentially of corrodible material selected from the group comprising magnesium, aluminum, zinc, and alloys thereof.

2. A rope battery as in claim 1, wherein said flexible separator sleeve consists essentially of a porous layer of paper, cloth, fiberglass, microporous plastic, or other like materials which is permeable to the flow of liquids and gases therethrough.

3. A rope battery as in claim 1, wherein said flexible outer layer consists essentially of twisted or braided strands of metal or graphite which are coated with catalytic amounts of hydrogen evolution catalyst selected from the group comprising platinum, palladium, ruthenium and nickel or alloys thereof.

4. A rope battery as in claim 1, wherein said rope battery is surrounded by a porous, flexible sleeve which is permeable to the flow of liquids and gases therethrough and which mechanically protects the outer layer of twisted, felted or braided strands from damage.

5. A rope battery as in claim 1, wherein said flexible outer layer consists essentially of twisted, felted or braided strands of electrically conductive substrate which is in direct contact with a layer of cathode depolarizer selected from the group comprising manganese dioxide, lead chloride, silver chloride, cuprous/silver chloride, cuprous thiocyanate, or trichloromelamine.

6. A rope battery as in claim 1, wherein said flexible inner core consists essentially of a single flexible solid wire and/or a bundle of small wires of chemically inert material in intimate contact with a mixture of an electrically conductive material and a cathode depolarizer selected from the group comprising manganese dioxide, lead chloride, silver chloride, cuprous/silver chloride, cuprous thiocyanate, or trichloromelamine.

7. A rope battery as in claim 1, wherein said flexible inner core contains a flexible insulated electrical cable for connecting rope single cell batteries together into rope batteries consisting of a plurality of cells connected in series, with said flexible insulated electrical cable running the entire length of the multicell battery and connecting at the bitter end to the terminal electrode.

8. A rope battery as in claim 1, wherein said flexible outer layer consists essentially of twisted, felted or braided strands of corrodible anode material(s) selected from the group comprising aluminum, magnesium, zinc or alloys thereof.

9. A rope battery according to claim 1 comprising a plurality of cells wherein the the ropes are electrically connected together in such a fashion that the anode of one rope battery cell is connected to the cathode of the next cell, with the unconnected electrodes at the bitter ends forming the positive and negative terminals, and with the current returned from one end of the battery to the other by means of an insulated connecting cable.

10. A water activated battery comprising a long flexible rope which consists essentially of two electrically conducting ropes of dissimilar materials held apart by a flexible insulating spacer.

11. A rope battery as in claim 10, wherein one of the two conducting ropes consists essentially of a single flexible solid wire and/or bundle of wires of corrodible material selected from the group comprising magnesium, aluminum and zinc or alloys thereof.

12. A rope battery as in claim 10, wherein one of the two conducting ropes consists essentially of twisted, braided or felted strands of inert metal or graphite which are coated with catalytic amounts of hydrogen evolution catalyst selected from the group comprising platinum, palladium, ruthenium and nickel or alloys thereof.

13. A rope battery as in claim 10, wherein one of the two conducting ropes consists essentially of twisted, braided or felted strands of inert metal or graphite which are in direct contact with a layer of cathode depolarizer selected from the group comprising manganese dioxide, lead chloride, silver chloride, cuprous/silver chloride, cuprous thiocyanate, or trichloromelamine.

14. A rope battery as in claim 10, wherein said flexible insulating spacer contains a flexible insulated electrical cable for passing electrical current from one end of the rope to the other.

15. A rope battery according to claim 10, comprising a plurality of cells connected in series with the battery current returned from the terminal located at the rope'"'"'s bitter end by means of a flexible insulated electrical cable located within the flexible insulating spacer.