Optical absorption analyzer

• US 4,525,069 A
• Filed: 04/23/1982
• Issued: 06/25/1985
• Est. Priority Date: 05/19/1981
• Status: Expired due to Fees

• Current Assignee: Horiba Limited 2 Miyanohigashi-Machi Kissyoin Minami-Ku Kyoto Japan
• Original Assignee: Horiba Limited
• Inventors: Tanaka, Masaru, Noguchi, Naoki, Yoshino, Kenji, Saitoh, Osamu
• Primary Examiner(s): Evans, F. L.
• Application Number:
  US06/371,484
• Time in Patent Office: 1,159 Days
• Field of Search: 356/319, 356/435, 356/448, 356/222, 356/229, 356/437, 250/458.1, 250/461.1, 250/461.2, 250/564, 250/565
• US Class Current: 356/435
• CPC Class Codes: G01J 1/1626 Arrangements with two photodetectors, the signals of which are compared
• CPC Class Codes: G01N 21/274 Calibration, base line adjustment, drift correction

Abstract

An optical absorption analyzer for determining the concentration of low concentration components of a sample gas. Inexpensive voltage to frequency converters, up/down counters, and integrators are used to obtain a high accuracy determination which is independent of fluctuations in the strength of the light source used in the analyzer.

Claims

1. An optical absorption analyzer for determining the concentration of a particular component of a gas mixture, said analyzer comprising:

a light source;

first and second optical detectors and at least one cell arranged in an optical path between said light source and said first and second optical detectors, said detectors and at least one cell arranged such that during a first process, one of either a zero gas and a sample gas to be measured is passed through said at least one cell and, during a second process, the gas different from that of said first process is passed through said at least one cell;

a gain control circuit connected to an output of said first optical detector for controlling the amplitude of a first signal which is output by said first optical detector;

a differential amplifier connected to outputs of said gain control circuit and said second optical detector for amplifying the difference between said first signal and a second signal which is output by said second optical detector, said differential amplifier having an output which is fed back to said gain control circuit for controlling the operation thereof;

an integrator connected to said output of said second optical detector for integrating said second signal and for outputting an agreement signal when the integrated value reaches a predetermined value; and

a signal processing circuit means having an input connected to an output of said differential amplifier and having means for integrating, storing and comparing signals input thereto;

wherein, during said first process, the gain of said gain control circuit is controlled so that said first signal from said first optical detector is equal in value to said second signal from said second optical detector at a predetermined accuracy, and said output from said differential amplifier is integrated by said signal processing means from an instant of time when said integrator begins to integrate to an instant of time when said integrator outputs said agreement signal which is input to said signal processing means and the resulting integrated value is stored by said signal processing circuit means; and

wherein,

during said second process, said signal output from said differential amplifier is integrated by said signal processing circuit means from an instant of time when said integrator begins to integrate to an instant of time when said integrator outputs said agreement signal, and the resulting integrator value is then compared with said integrated value stored during said first process so as to analyze said component to be analyzed.

2. An optical absorption analyzer as set forth in claim 1, wherein said at least one cell comprises first and second cells which are separately arranged in two optical paths between said light source and said first and second optical detectors, and wherein said zero gas is continuously passed through said first cell while said zero gas is passed through a second cell during first process and said sample gas is passed through said second cell during said second process.

3. An optical absorption analyzer as set forth in claim 1, wherein said at least one cell comprises first and second cells which are separately arranged in two optical paths between said light source and said first and second optical detectors, and wherein said zero gas is passed through said first cell while said sample gas is passed through said second cell in said first process and said sample gas is passed through said first cell while said zero gas is passed through said second cell in said second process.

4. An optical aborption analyzer as set forth in any one of claims 1 to 3, further comprising a sequence controller means having inputs connected to said integrator and having outputs connected to control inputs of said gain control circuit and said integrator and said processing circuit means for controlling the operation of said analyzer during said first process and said second process.

5. An optical absorption analyzer as set forth in any one of claims 1 to 3, wherein said integrator and said signal processing circuit means comprise digital circuit elements for digitally performing said integrating and processing.

6. An optical absorption analyzer as set forth in claim 4, wherein said integrator and said signal processing circuit means comprise digital circuit elements for digitally performing said integrating and processing.