Method and apparatus for purification of water

• US 4,525,253 A
• Filed: 06/28/1984
• Issued: 06/25/1985
• Est. Priority Date: 02/15/1983
• Status: Expired due to Fees

• Current Assignee: Med Products Incorporated
• Original Assignee: Med Products Incorporated
• Inventors: Hayes, Daniel F., Sias, Robert G., Waldron, John W., Chesney, Lloyd
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Beggs, Jr., B. J.
• Application Number:
  US06/625,718
• Time in Patent Office: 362 Days
• Field of Search: 204/149, 204/152, 204/293, 204/228, 204/271, 204/273, 204/275, 204/276
• US Class Current: 210/748.18
• CPC Class Codes: C02F 1/4606 for producing oligodynamic substances to disinfect the water
• CPC Class Codes: C02F 2103/42 from bathing facilities, e.g. swimming pools

Abstract

A method and apparatus for purifying water includes a pump and purification cell, the cell having two electrodes, at least one of which electrodes is approximately 92 percent copper, 3 percent silver and 5 percent nickel, by weight. An electrical potential is developed between the electrodes and caused to alternate in polarity to prevent plating. Copper and silver ions are released into the water at adjustable rate, where they cooperatively destroy bacteria, algae, and the like.

Claims

1. A method for purifying a body of water, comprising the steps of:

circulating the water over two electrodes, the electrodes being solid bars, the water being circulated in a discontinuous path defined by an enclosure for the electrodes, at least one of the electrodes being wired to ground potential through a resistor, at least one of the electrodes comprising an alloy of;

approximately 85% to 93% copper, by weight;

approximately 1.5% to 5% silver, by weight;

approximately 2.5% to 7% nickel, by weight;

simultaneously releasing copper ions and silver ions into the circulating water at concentration levels which are effective to substantially reduce algae and bacteria levels, but which are substantially less than the levels otherwise necessary to be so effective when released independently, by developing an electrical potential between the electrodes, whereby the water may be purified without need for chlorine treatment; and

,

sensing and indicating fouling of the electrodes by monitoring the potential of the electrode wired through the resistor, fouling being detected by a drop in said potential.

2. The method of claim 1, comprising the step of releasing the copper ions at a level in the range at approximately 350 to 500 parts per billion and releasing the silver ions at a level in the range of approximately 25 to 45 parts per billion.

3. The method of claim 1, wherein both of the electrodes are formed from the alloy.

4. The method of claim 3, further comprising the steps of applying the electrical potential from a direct current source and periodically reversing the polarity of the source.

5. The method of claim 4, comprising the step of reversing the polarity at a duty cycle of approximately 50% and a period in the range of approximately 10 to 40 seconds per cycle.

6. The method of claim 5, wherein the water is circulated over at least one electrode comprising an alloy of approximately 90 to 92% copper, by weight;

approximately 2-4% silver, by weight; and

, approximately 4-6% nickel, by weight.

7. The method of claim 6, wherein the water is circulated over at least one electrode having a composition of about 92% copper, about 3% silver, and about 5% nickel.

8. The method of claim 5, comprising the steps of reversing the polarity at a period in the range of approximately 20-34 seconds per cycle.

9. The method of claim 1, wherein the water is circulated over at least one electrode comprising an alloy of approximately 90 to 92% copper, by weight;

approximately 2-4% silver, by weight; and

, approximately 4-6% nickel, by weight.

10. The method of claim 9, wherein the water is circulated over at least one electrode having a composition of about 92% copper, about 3% silver, and about 5% nickel.

11. An apparatus for purifying a body of water, comprising:

a purification cell defining a water flow path and having at least one discontinuous surface for disturbing the path;

means for circulating the water through the cell;

two electrodes disposed in the cell and thereby immersible in the circulating water, at least one of the electrodes comprising an alloy of;

approximately 85% to 93% copper, by weight;

approximately 1.5% to 5% silver, by weight; and

,

approximately 2.5% to 7% nickel, by weight;

means for detecting electrode fouling; and

,

means for developing an electrical potential between the electrodes, under the influence of which copper ions and silver ions are simulataneously released into the water at concentration levels which are effective to substantially reduce algae and bacteria levels in the water, but which are less than the levels otherwise necessary to be so effective when released independently, whereby, the body of water may be purified without need for chlorine treatment.

12. The apparatus of claim 11, wherein the means for developing the electrical potential induces the release of the copper ions at a level in the range of approximately 350 to 500 parts per billion and the release of the silver ions at a level in the range of approximately 25 to 45 parts per billion.

13. The apparatus of claim 11, wherein both of the electrodes comprise the alloy.

14. The apparatus of claim 13, wherein the means for developing the electrical potential includes a direct current source connected to the electrodes and means for periodically reversing the polarity of the direct current source.

15. The apparatus of claim 14, wherein the means for reversing polarity operates at a duty cycle of approximately 50% and at a period in the range of approximately 10 to 40 seconds per cycle.

16. The apparatus of claim 15, wherein said electrodes comprise an alloy of:

approximately 90 to 92% copper, by weight;

approximately 2-4% silver, by weight; and

,

approximately 4-6% nickel, by weight.

17. The apparatus of claim 16, wherein said electrodes comprise an alloy of about 92% copper, about 3% silver and about 5% nickel, by weight.

18. The apparatus of claim 15, wherein the means for reversing polarity has a period in the range of approximately 20-34 seconds per cycle.

19. The apparatus of claim 11, wherein said electrodes comprise an alloy of:

approximately 90 to 92% copper, by weight;

approximately 2-4% silver, by weight; and

,

approximately 4-6% nickel, by weight.

20. The apparatus of claim 19, wherein said electrodes comprise an alloy of about 92% copper, about 3% silver and about 5% nickel, by weight.

21. The apparatus of claim 11, wherein the purification cell comprises a substantially cylindrical container having a cylindrical portion, a flattened portion, and a stepwise connection between the cylindrical and flattened portions, thereby causing water to swirl through a baffle formed by the stepwise connection.

22. The apparatus of claim 11, wherein the discontinuous surface includes a stepwise decrease in diameter of the purification cell.

23. The apparatus of claim 22, wherein the container comprises a removable sealing end cap, the electrode being end-wise attached to the cap and removable together with the cap, whereby the electrode is conveniently accessible for cleaning.

24. The apparatus of claim 11, wherein at least one of the electrodes is a solid bar of said alloy, the bar being removably disposed parallel to the axis of said cylindrical container and extending longitudinally into the cylindrical container, at least to a level defined by the discontinuous surface.

25. The apparatus of claim 24, wherein the solid bar electrode disposed in the cell wired as an anode and the other electrode is at least one of a screen wired as cathode.

26. The apparatus of claim 11, wherein the means for detecting and indicating electrode fouling comprises a comparator wired to compare the voltage at one of the electrodes to a predetermined reference voltage defined by a voltage divider, the comparator activating a warning lamp when the voltage at the electrode falls below the reference voltage thereby indicating an output current below a predetermined standard.

27. The apparatus of claim 11, further comprising means for adjusting the output voltage at the electrode including a control potentiometer.