Continuous charge control for electrochromic layers

• US 4,529,275 A
• Filed: 10/22/1982
• Issued: 07/16/1985
• Est. Priority Date: 10/29/1981
• Status: Expired due to Fees

• Current Assignee: Carl-Zeiss-Stiftung
• Original Assignee: Carl-Zeiss-Stiftung
• Inventors: Ballmer, Horst
• Primary Examiner(s): ARNOLD, BRUCE
• Application Number:
  US06/436,172
• Time in Patent Office: 998 Days
• Field of Search: 350/357
• US Class Current: 359/265
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor

Abstract

A continuous change in color is provided in order to control the absorptance of an electrochromic layer. The quantities of charge to be fed and removed by two sources of constant current are measured with a forward/backward counter. For decoloring processes, smaller amounts of charge are removed from the layer than are supplied to it for corresponding coloring processes. The quantities of charge removal for decoloring processes are, however, slightly greater than the quantities of charge which are theoretically necessary to obtain intermediate values with exactly the same absorptance, thereby assuring against destruction of the layer, even in case of numerous changes between different colorings. Preferred fields of use are lenses, particularly eyeglass lenses, filters and dimmable mirrors, using an applied electrochromic layer whose absorptance is varied.

Claims

1. Apparatus for continuously selective charge control of an electrochromic layer, said layer being uncolored for the case of no charge in said layer and being colored to a progressively increasing state of coloration for progressively increasing charges in said layer, said apparatus comprising:

automatic means for limiting the charge deliverable to said layer to the extent of producing a predetermined fully-colored state of coloration and for limiting the charge removed from said layer to the extent of assuring a fully decolored state of coloration, whereby automatic limits are established for a predetermined range of colorability of said layer;

selectively operable means for selecting a change of state of coloration of said layer within said range regardless of the currently existing state of coloration of the layer, said selectively operable means including a first key for effecting a more colored state of coloration and a second key for effecting a more decolored state of coloration, a constant-current charging circuit connected to charge said layer in the event of first-key actuation, and a constant-current charge-removal circuit connected to remove charge from said layer in the event of second-key actuation;

said automatic means including clock-pulse generator means and an up/down counter, said counter being connected upon first-key actuation for up-counting during periods of first-key actuation, said counter being connected upon second-key actuation for down-counting during periods of second-key actuation, there being an up-counting limit at which first-key actuation is effectively disabled, there being a down-counting limit at which second-key actuation is effectively disabled, and the quantity of charge increment per unit up-count being preselected to be sufficiently greater than the quantity of charge decrement per unit down-count such that the resulting unit down-counted decremental quantum removal of color slightly exceeds the unit up-counted incremental quantum darkening of color.

2. Apparatus according to claim 1, in which the constant current of said charging circuit is preset to a magnitude greater than the constant current of said charge-removal circuit.

3. Apparatus according to claim 1, in which (a) said first key comprises a first touch sensor to initiate a first-key operation, (b) said second key comprises a second touch sensor to initiate a second-key operation, and (c) a third touch sensor is operable to terminate a given key operation.

4. Apparatus according to claim 1, in which said first key comprises a first touch sensor to initiate a first-key operation and a second touch sensor to terminate first-key operation, and in which said second key comprises a third touch sensor to initiate a second-key operation and a fourth touch sensor to terminate second-key operation.

5. Apparatus according to claim 1, in which each of said constant-current circuits is provided by the emitter circuit of a transistor, and in which each transistor is connected by a base resistor to said automatic means.

6. Apparatus according to claim 1, in which a storage device and a comparator responsive to the instantaneous count by said counter are connected to disable key operation at any desired intermediate count within said predetermined range of colorability.

7. Apparatus according to claim 1, in which said electrochromic layer is a sunglass element.

8. Apparatus according to claim 1, in which said electrochromic layer is an element of a dimmable mirror.

9. Apparatus according to claim 1, in which said electrochromic layer is an element of an optical filter.

10. Apparatus for continuously selective charge control of an electrochromic layer, said layer being uncolored for the case of no charge in said layer and being colored to a progressively increasing state of coloration for progressively increasing charges in said layer, said apparatus comprising:

automatic means for limiting the charge deliverable to said layer to the extent of producing a predetermined fully colored state of coloration and for limiting the charge removed from said layer to the extent of assuring a fully decolored state of coloration, whereby automatic limits are established for a predetermined range of colorability of said layer, means including an optical sensor, for effecting a change of state of coloration of said layer within said range of colorability regardless of the currently existing state of coloration of the layer, said last-mentioned means including a comparator producing a first output signal for effecting a more colored state upon the output of said sensor exceeding a predetermined value, said comparator producing a second output signal for effecting a more decolored state upon the output of said sensor falling below said predetermined value, a constant-current charging circuit connected to said layer in the event of said first output signal, and a constant-current charge-removal circuit connected to remove charge from said layer in the event of said second signal;

said automatic means including clock-pulse generator means and an up/down counter, said counter being connected in response to said first signal for up-counting during periods of first-signal duration, said counter being connected in response to said second signal for down-counting during periods of second-signal duration, there being an up-counting limit at which first-signal response is effectively disabled, there being a down-counting limit at which second-signal response is effectively disabled, and the quantity of charge increment per unit up-count being preselected to be sufficiently greater than the quantity of charge decrement per unit down-count such that the resulting unit down-counted decremental quantum removal of color slightly exceeds the unit up-counted incremental quantum darkening of color.

11. Apparatus according to claim 10, in which said electrochromic layer is an optical element in the path of light exposure to said optical sensor, whereby said electrochromic layer operates to maintain light exposure to said optical sensor at substantially the level established by said predetermined value at said comparator.

12. Apparatus according to claim 10, in which said electrochromic layer is a sunglass element.

13. Apparatus according to claim 10, in which said electrochromic layer is an element of a dimmable mirror.

14. Apparatus according to claim 10, in which said electrochromic layer is an element of an optical filter.

16. Apparatus according to claim 13, in which said clock-pulse generator means comprises a first clock-pulse generator operated by said first key for up-counting and a second clock-pulse generator operated by said second key for down-counting, the pulse frequency of said first generator being greater than the pulse frequency of said second generator.

15. Apparatus for continuously selective charge control of an electrochromic layer, said layer being uncolored for the case of no charge in said layer and being colored to a progressively increasing state of coloration for progressively increasing charges in said layer, said apparatus comprising:

automatic means for limiting the charge deliverable to said layer to the extent of producing a predetermined fully-colored state of coloration and for limiting the charge removed from said layer to the extent of assuring a fully decolored state of coloration, whereby automatic limits are established for a predetermined range of colorability of said layer;

selectively operable means for selecting a change of state of coloration of said layer within said range regardless of the currently existing state of coloration of the layer, said selectively operable means including a first key for effecting a more colored state of coloration and a second key for effecting a more decolored state of coloration, a constant-current charging circuit connected to charge said layer in the event of first-key actuation, and a constant-current charge-removal circuit connected to remove charge from said layer in the event of second-key actuation;

said automatic means including clock-pulse generator means and an up/down counter, said counter being connected upon first-key actuation for up-counting during periods of first-key actuation, said counter being connected upon second-key actuation for down-counting during periods of second-key actuation, there being an up-counting limit at which first-key actuation is effectively disabled, and there being a down-counting limit at which second-key actuation is effectively disabled.

17. Apparatus according to claim 15, in which said clock-pulse generator means comprises a plurality of clock-pulse generators of different pulse frequency, the respective generators of said plurality being operated by said first key and dependent upon the instantaneous level of count by said counter.

18. Apparatus for continuously selective charge control of an electrochromic layer, said layer being uncolored for the case of no charge in said layer and being colored to a progressively increasing state of coloration for progressively increasing charges in said layer, said apparatus comprising:

automatic means for limiting the charge deliverable to said layer to the extent of producing a predetermined fully colored state of coloration and for limiting the charge removed from said layer to the extent of assuring a fully decolored state of coloration, whereby automatic limits are established for a predetermined range of colorability of said layer;

means including an optical sensor, for effecting a change of state of coloration of said layer within said range of colorability regardless of the currently existing state of coloration of the layer, said last-mentioned means including a comparator producing a first output signal for effecting a more colored state upon the output of said sensor exceeding a predetermined value;

said comparator producing a second output signal for effecting a more decolored state upon the output of said sensor falling below said predetermined value, a constant-current charging circuit connected to charge said layer in the event of said first output signal, and a constant-current charge-removal circuit connected to remove charge from said layer in the event of said second signal;

said automatic means including clock-pulse generator means and an up/down counter, said counter being connected in response to said first signal for up-counting during periods of first-signal duration, said counter being connected in response to said second signal for down-counting during periods of second-signal duration, there being an up-counting limit at which first-signal response is effectively disabled, and there being a down-counting limit at which second-signal response is effectively disabled.

19. Apparatus for continuously selective charge control of an electrochromic layer, said layer being uncolored for the case of no charge in said layer and being colored to a progressively increasing state of coloration for progressively increasing charges in said layer, said apparatus comprising:

automatic means for limiting the charge deliverable to said layer to the extent of producing a predetermined fully-colored state of coloration and for limiting the charge removed from said layer to the extent of assuring a fully decolored state of coloration, whereby automatic limits are established for a predetermined range of colorability of said layer;

selectively operable means for selecting a change of state of coloration of said layer within said range regardless of the currently existing state of coloration of the layer, said selectively operable means including a first key for effecting a more colored state of coloration and a second key for effecting a more decolored state of coloration, a constant-current charging circuit connected to charge said layer in the event of first-key actuation, and a constant-current charge-removal circuit connected to remove charge from said layer in the event of second-key actuation, the constant-current rates being substantially the same;

said automatic means including clock-pulse generator means and an up/down counter, said counter being connected upon first-key actuation for up-counting during periods of first-key actuation, said counter being connected upon second-key actuation for down-counting during periods of second-key actuation, there being an up-counting limit at which first-key actuation is effectively disabled, there being a down-counting limit at which second-key actuation is effectively disabled, and said clock-pulse generator means comprising a first clock-pulse generator operated by said first key for up-counting and a second clock-pulse generator operated by said second key for down-counting, the pulse frequency of said first generator being preselected to be sufficiently greater than the pulse frequency of said second generator that the quantity of charge increment per unit up-count is less than the quantity of charge decrement per unit down-count, to the extent that the resulting unit down-counted decremental quantum removal of color slightly exceeds the unit up-counted incremental quantum darkening of color.

20. Apparatus for continuously selective charge control of an electrochromic layer, said layer being uncolored for the case of no charge in said layer and being colored to a progressively increasing state of coloration for progressively increasing charges in said layer, said apparatus comprising:

automatic means for limiting the charge deliverable to said layer to the extent of producing a predetermined fully-colored state of coloration and for limiting the charge removed from said layer to the extent of assuring a fully decolored state of coloration, whereby automatic limits are established for a predetermined range of colorability of said layer;

selectively operable means for selecting a change of state of coloration of said layer within said range regardless of the currently existing state of coloration of the layer, said selectively operable means including a first key for effecting a more colored state of coloration and a second key for effecting a more decolored state of coloration, a constant-current charging circuit connected to charge said layer in the event of first-key actuation, and a constant-current charge-removal circuit connected to remove charge from said layer in the event of second-key actuation;

said automatic means including a single clock-pulse generator of a single clock-pulse frequency, and an up/down counter, said counter being connected upon first-key actuation for up-counting during periods of first-key actuation, said counter being connected upon second-key actuation for down-counting during periods of second-key actuation, there being an up-counting limit at which first-key actuation is effectively disabled, there being a down-counting limit at which second-key actuation is effectively disabled, and the charging current being so selected in excess of the charge-removal current that the quantity of charge increment per unit up-count is greater than the quantity of charge decrement per unit down-count, to the extent that the resulting unit down-counted decremental quantum removal of color slightly exceeds the unit up-counted incremental quantum darkening of color.