Hydrodesulfurization of coke

• US 4,529,501 A
• Filed: 05/29/1984
• Issued: 07/16/1985
• Est. Priority Date: 07/03/1980
• Status: Expired due to Fees

• Current Assignee: The Research Council of Alberta
• Original Assignee: The Research Council of Alberta
• Inventors: George, Zacheria M.
• Primary Examiner(s): Gantz, D. E.
• Assistant Examiner(s): Caldarola, Glenn A.
• Application Number:
  US06/614,485
• Time in Patent Office: 413 Days
• Field of Search: 208/127, 208/131
• US Class Current: 208/127
• CPC Class Codes: C10B 55/00 Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material cracking oils C10G
• CPC Class Codes: C10B 57/06 containing additives
• CPC Class Codes: C10L 9/02 by chemical means

Abstract

The extent of hydrodesulfurization of coke formed by coking bitumen is enhanced by the addition of small amounts of sodium hydroxide to the bitumen prior to coking the same.

Claims

1. A method for the production of coke having a decreased sulfur content, which comprises:

adding sodium hydroxide to a sulfur-containing bitumen in an amount of about 0.3 to about 0.8 wt.% NaOH based on bitumen,

coking the bitumen after addition of said sodium hydroxide to form a sulfur-containing coke, and

hydrodesulfurizing said coke using a flowing hydrogen stream, said sodium hydroxide being effective to result in removal of at least a major proportion of the sulphur contained in said coke during said hydrodesulfurizing step.

2. The method of claim 1 wherein said amount of sodium hydroxide is about 0.4 to about 0.5 wt.% NaOH.

3. The method of claim 1 wherein said bitumen is bitumen recovered from oil sands and said coking is effected by delayed coking to result in a coke containing about 5.5 to 6 wt.% sulfur.

4. The method of claim 1 wherein said bitumen is bitumen recovered from oil sands and said coking is effected by fluid coking to result in a coke containing about 5.5 to 6 wt.% sulfur.