Work-hardenable austenitic manganese steel and method for the production thereof

• US 4,531,974 A
• Filed: 10/11/1983
• Issued: 07/30/1985
• Est. Priority Date: 04/13/1982
• Status: Expired due to Fees

• Current Assignee: Vereinigte Edelstahlwerke Aktiengesellschaft
• Original Assignee: Vereinigte Edelstahlwerke Aktiengesellschaft
• Inventors: Kos, Bernd
• Primary Examiner(s): Rutledge, L. Dewayne
• Assistant Examiner(s): Yee, Deborah
• Application Number:
  US06/540,649
• Time in Patent Office: 658 Days
• Field of Search: 75/123 N, 75/124 B, 75/124 C, 75/126 B, 75/128 A, 75/130 R, 75/129, 148/137, 148/3, 148/38
• US Class Current: 420/73
• CPC Class Codes: C22C 38/04 containing manganese

Abstract

A work-hardenable austenitic manganese steel has a base composition (each in percent by weight) of 0.7 to 1.7 carbon, 5.0 to 18.0 manganese, 0 to 3.0 chromium, 0 to 4.0 nickel, 0 to 2.5 molybdenum, 0.1 to 0.9 silicon, up to 0.1 phosphorus and contains micro-alloying elements of 0.0 to 0.20 titanium, 0.0 to 0.05 zirconium and 0.0 to 0.05 vanadium; the remainder being iron and impurities arising from the melting process. The ratio of carbon to manganese is in the range of 1:4 to 1:14 and the total amount of micro-alloying elements is limited to a range of 0.002 to 0.25 percent by weight. The melt of the base composition is tapped at 1,450° C. to 1,600° C. into a casting ladle in which the micro-alloying elements are added. An ingot is cast, cooled, reheated to austenitization temperatures and quenched.

Claims

1. A work-hardenable austenitic manganese steel having an elongation at rupture of 10 percent to 80 percent, as measured according to L=5 d or L=10 d, and essentially consisting of, each in percent by weight:

0.7 to 1.7 C

5.0 to 18.0 Mn

0 to 3.0 Cr

0 to 4.0 Ni

0 to 2.5 Mo

0.1 to 0.9 Si

up to 0.1 P

with the proviso that the carbon-to -manganese ratio is between 1;

4 and 1;

14, and containing an amount of micro-alloying elements in percent by weight;

0.0 to 0.2 Ti

0.0 to 0.05 Zr

with the proviso that the sum Ti+Zr is in the range of 0.002 percent by weight to 0.25 percent by weight, the remainder iron and impurities arising during the melting process.

2. The austenitic manganese steel as defined in claim 1, wherein:

titanium is the only micro-alloying element and is present in the range of 0.008 percent by weight to 0.20 percent by weight.

3. The austenitic manganese steel as defined in claim 2, further including:

vanadium in the range of 0.01 percent by weight and 0.05 percent by weight with the proviso that the sum of Ti+Zr+V is in the range of 0.002 percent by weight to 0.25 percent by weight.

20. The austenitic manganese steel as defined in claim 1, wherein:

titanium is present in the range of 0.008 to 0.2 percent by weight.

4. A method for producing a work-hardenable austenitic manganese steel casting or ingot, said method comprising the steps of:

melting a charge in an electric furnace to form a melt;

adding slag-forming additives to said melt;

adjusting said melt for an analysis as given below in percent by weight;

0.7 to 1.7 carbon

5.0 to 18.0 manganese

0.0 to 3.0 chromium

0.0 to 4.0 nickel

0.0 to 2.5 molybdenum

0.1 to 0.9 silicon

up to 0.1 phosphorus,

the remainder being iron and impurities originating in the melting process and the ratio of carbon to manganese being in the range of 1;

4 to 1;

14;

heating said melt to a tapping temperature in the range of 1450°

C. to 1600°

C.;

deoxidizing said melt using an element having an affinity for oxygen;

tapping said melt into a casting ladle;

adding to said melt in said casting ladle micro-alloying elements in a amount as given below in percent by weight;

6. The method ac defined in claim 4, wherein:

said melt is heated to a tapping temperature in the range of 1450°

C. to 1525°

C.

7. The method as defined in claim 4, wherein:

said melt is cast at at a temperature in the range of 1420°

C. to 1460°

C. into a mold.

8. The method is defined in claim 4, further including the steps of:

adding in the range of 2 to 10 percent by weight of the final manganese content to said melt in said electric furnace at a maximum temperature of 1525°

C. of said melt and thereafter maintaining said melt at a temperature below 1525°

C.

9. The method as defined in claim 4, wherein:

vanadium is added to said melt at a temperature of said melt in the electric furnace in the range of 1490°

C. to 1525°

C. after deoxidizing the melt.

10. The method as defined in claim 4, wherein:

vanadium is added to said melt in said casting ladle at a temperature of said melt in the range of 1490°

C. to 1525°

C.

11. The method as defined in claim 4, further including the steps of:

reheating said casting or ingot to an austenitizing temperature in the range of 980°

C. to 1150°

C.; and

then rapidly cooling said casting or ingot.

12. The method as defined in claim 4, wherein:

said casting or ingot is reheated to a temperature in the range of 1030°

C. to 1150°

C.

13. The method as defined in claim 4 wherein:

said casting or ingot is reheated to a temperature in the range of 1080°

C. to 1100°

C.

14. The method as defined in claim 4, further including the steps of:

cooling said reheated casting or ingot to a temperature in the range of 980°

C. to 1000°

C.; and

equalizing said temperature in said casting or ingot.

15. The method as defined in claim 4, wherein:

said casting ingot is quenched by alternatingly subjecting the same to coolants of different heat conductivities.

16. The method as defined in claim 14, wherein:

said alternatingly used coolants are water and air.

17. The method as defined in claim 4, wherein:

said casting or ingot is cooled in said mold to a temperature in the range of 800°

C. to 1000°

C.; and

said casting or ingot is removed from said mold and placed in a heat-treating furnace to equalize said temperature.

18. An austenitic manganese steel as produced in accordance with the method of claim 4.

19. The method as defined in claim 4, further including the step of:

adding vanadium in an amount corresponding to a range of 0.01 percent by weight to 0.05 percent by weight with the proviso that the sum of Ti+Zr+V is in the range of 0.018 percent by weight to 0.25 percent by weight.

21. The method as defined in claim 4, wherein:

titanium is added to said melt in said casting ladle in an amount in the range of 0.008 to 0.2 percent by weight.

5. 0 to 0.20 titanium

0.0 to 0.05 zirconium

the sum of the contents of said micro-alloying elements being in the range of 0.002 to 0.25 percent by weight;

casting said melt at a temperature in the range of 1420°

C. to 1490°

C. into a mold and

cooling said melt in said mold to form said casting or ingot.