Curable epoxy resin containing molding compositions

• US 4,532,274 A
• Filed: 04/17/1984
• Issued: 07/30/1985
• Est. Priority Date: 09/30/1982
• Status: Expired due to Fees

• Current Assignee: Union Carbide Corporation (Dow, Inc.)
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Spurr, Orson K.
• Primary Examiner(s): GRIFFIN, RONALD
• Application Number:
  US06/600,222
• Time in Patent Office: 469 Days
• Field of Search: 523/457, 528/93, 528/94, 528/89, 528/110, 528/406, 528/361
• US Class Current: 523/457
• CPC Class Codes: C08G 59/24 carbocyclic
• CPC Class Codes: C08G 59/62 Alcohols or phenols
• CPC Class Codes: C08G 59/68 characterised by the catalysts used
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Abstract

Described herein are curable molding compositions comprising an epoxide resin, a polyol and particular catalysts. These compositions have good pot life and cure rapidly.

Claims

1. A curable molding composition comprising an epoxide resin, a polyol, a hardener, and a catalyst selected from the group consisting of amine, quaternary ammonium or phosphonium compounds which when combined, in an amount of from 0.5 to about 10 parts by weight per 100 parts by weight of resin, with said epoxide resin, said polyol, said hardener, and 60 percent by weight, based on the total weight of the formulation, of aluminum trihydrate produce a composition characterized by a peak exotherm of 210°

C. or less, a time to peak exotherm of 10.5 or less minutes in a mold at 150°

C., and a time for the viscosity of the composition to reach 3000 centipoise at 80°

C. of 30 minutes or greater.

2. A curable composition as defined in claim 1 wherein the epoxide resin is a cycloaliphatic epoxide.

3. A curable composition as in claim 2 wherein the cycloaliphatic epoxide has the formula:

##STR12## wherein R₁ through R₉, which are the same or different are hydrogen or alkyl radicals generally containing one to nine carbon atoms inclusive;

R is a valence bond or a divalent hydrocarbon radical generally containing one to nine carbon atoms inclusive.

4. A curable composition as in claim 2 wherein the cycloaliphatic epoxide has the formula:

##STR13## wherein R₁ through R₉ which are the same or different are hydrogen or alkyl radicals generally containing one to nine carbon atoms inclusive.

5. A curable composition as in claim 2 wherein the cycloaliphatic epoxide has the formula:

##STR14## wherein the R groups are the same as different and are monovalent substituents or monovalent hydrocarbon radicals.

6. A curable composition as in claim 2 wherein the cycloaliphatic epoxide is 3,4-epoxycyclohexylmethyl-3,4-epoxy-cyclohexane carboxylate.

7. A curable composition as in claim 2 wherein the cycloaliphatic epoxide is bis(3,4-epoxycyclohexylmethyl)-adipate.

8. A curable composition as in claim 2 wherein the cycloaliphatic epoxide is 2-(3,4-epoxycyclohexyl-5,5-spiro-3,4-epoxy)cylohexane-meta dioxane.

9. A curable composition as in claim 1 wherein the polyol is a polycaprolactone polyol.

10. A curable composition as in claim 1 which contains a filler.

11. A curable composition as in claim 1 wherein the filler is selected from clay, silica, aluminum trihydrate, or mixtures thereof.

12. The composition of claim 1 wherein the catalyst is selected from the group consisting of pyridine-N-oxide, 1,4-diazabicyclo [2.2.2] octane, 2-methylimidazole, 2-phenyl-imidazole, 1vinyl-2-methyl imidazole, 1-acetyl imidazole, n-propyl triphenyl phosphonium bromide, benzyl triphenyl phosphonium bromide and chloride, n-heptyl triphenyl phosphonium bromide, ethyl triphenyl phosphonium bromide and iodide, n-hexyl triphenyl phosphonium bromide, and bis(dimethylaminoethyl) ether.

13. A curable composition as in claim 12 wherein the catalyst is 1,4-diazabicyclo [2.2.2]octane.