Method of processing nickel-titanium-base shape-memory alloys and structure

• US 4,533,411 A
• Filed: 11/15/1983
• Issued: 08/06/1985
• Est. Priority Date: 11/15/1983
• Status: Expired due to Term

• Current Assignee: Memry Corporation
• Original Assignee: Raychem Corporation (TE Connectivity Limited)
• Inventors: Melton, Keith N.
• Primary Examiner(s): Skiff, Peter K.
• Application Number:
  US06/553,005
• Time in Patent Office: 630 Days
• Field of Search: 148/11.5 R, 148/11.5 F, 148/11.5 C, 148/11.5 N, 148/12.7 B, 148/12.7 R, 148/402, 420/587
• US Class Current: 148/402
• CPC Class Codes: C22F 1/006 Resulting in heat recoverable alloys with a memory effect

Abstract

Method of processing nickel-titanium-base shape-memory alloys to substantially suppress the two-way effect including the steps of cold working and low-temperature annealing without restraint. A composite structure is also provided including a nickel-titanium-base shape-memory alloy with the two-way effect substantially suppressed.

Claims

1. A method of processing nickel-titanium-base shape-memory alloys to substantially suppress the two-way effect which comprises:

providing a nickel-titanium-based shape-memory alloy in the austenitic state in a specified shape;

cold working said alloy in the martensitic state from 15% to 40% to provide a microstructure containing a high concentration of substantially random dislocations;

annealing said alloy without restraint at 300°

C. to 500°

C. for at least 20 minutes to rearrange the dislocations into an ordered network of dislocations comprising essentially dislocation-free cells surrounded by walls of higher dislocation density;

providing said alloy in a desired shape while maintaining the dislocation-free cells obtained in the annealing step; and

deforming the alloy in the martensitic state;

whereby when the alloy is recovered by heating the alloy to the austenitic state and subsequently cooled to the martensitic state, the alloy substantially retains said desired shape.

2. A method according to claim 1 wherein after the step of deforming the alloy, the method further comprises heating said alloy to the austenitic state to recover and substantially retain said desired shape.

3. A method according to claim 1 wherein said alloy is annealed for from 20 to 90 minutes.

4. A method according to claim 2 wherein the alloy is subsequently cooled to the martensitic state and substantially retains said desired shape.

5. A method according to claim 2 wherein the step of heating said alloy is at a temperature higher than the temperature at which the alloy is fully pseudoelastic.

6. A method according to claim 5 wherein said heating temperature is in excess of 125°

C.

7. A method according to claim 1 wherein the alloy is hot worked in the austenitic state to provide said alloy in a specified shape.

8. A method according to claim 1 wherein said desired shape is machined or stamped after annealing and before deforming.

9. A coupling member produced by the process of processing nickel-titanium-base shape-memory alloys to substantially suppress the two-way effect which comprises:

providing a nickel-titanium-base shape-memory alloy in the austenitic state in a specified shape;

cold working said alloy in the martensitic state from 15% to 40% to provide a microstructure containing a high concentration of substantially random dislocations;

annealing said alloy without restrain at 300°

C. to 500°

C. for at least 20 minutes to rearrange the dislocations into an ordered network of dislocations comprising essentially dislocation-free cells surrounded by walls of higher dislocation density and to provide said alloy in a desired shape; and

deforming the alloy in the martensitic state;

whereby when the alloy is recovered by heating the alloy to the austenitic state and subsequently cooled to the martensitic state, the alloy will revert to the martensitic state without exhibiting the two-way effect.

10. The coupling member produced by the process according to claim 9 wherein after the step of deforming the alloy, the process further comprises heating said alloy to the austenitic state to recover and substantially retain said desired shape.

11. The coupling member produced by the process according to claim 10 wherein the alloy is subsequently cooled to the martensitic state and substantially retains said desired shape.