Purification of bisphenols by removing residual solvent

• US 4,533,764 A
• Filed: 03/29/1984
• Issued: 08/06/1985
• Est. Priority Date: 03/29/1984
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Chang, Feng-Chih, Wernl, Susan A., Busby, David E.
• Primary Examiner(s): Lone, Werren B.
• Application Number:
  US06/594,963
• Time in Patent Office: 495 Days
• Field of Search: 568/724, 568/749, 568/748
• US Class Current: 568/724
• CPC Class Codes: C07C 37/84 by crystallisation
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

Occluded organic solvent is removed from bisphenol crystals by placing in water maintained at a temperature sufficient to form a molten water-bisphenol phase, holding at that temperature for a time sufficient to transfer the organic solvent to the water phase, flash distilling the organic solvent, cooling molten water-bisphenol phase to produce crystallization and thereafter recovering the bisphenol.

Claims

1. A process for purifying a bisphenol to remove small amounts of organic solvent remaining from a crystallization which comprises (a) adding bisphenol crystals containing said solvent to water maintained at a temperature which will produce a water-bisphenol molten phase, (b) maintaining that temperature for a period of time sufficient to permit the organic solvent to transfer to said water, (c) flash distilling substantially all of said solvent away from said water, (d) cooling said molten bisphenol-water phase to precipitate the crystalline bisphenol, and (e) separating said crystalline bisphenol from said water and (f) drying said crystalline bisphenol.

2. The process of claim 1 wherein the bisphenol is p,p'"'"'-isopropylidene diphenol.

3. The process of claim 2 wherein the temperature of the water in step (a) is about 100°

C.

4. The process of claim 3 wherein the time in step (b) is at least about one minute.

5. The process of claim 4 wherein the time in step (b) is from about 5 to about 50 minutes.

6. The process of claim 5 wherein the pressure is maintained at about atmospheric.

7. A process for purifying a bisphenol to remove small amounts of organic solvent remaining from a crystallization which comprises (a) adding bisphenol crystals containing said solvent to water maintained at a temperature which will produce a water-bisphenol molten phase, (b) maintaining that temperature for a period of time sufficient to permit the organic solvent to transfer to said water, (c) flash distilling substantially all of said solvent away from said water, (d) stripping said water from said molten water-bisphenol phase, (e) separating solid bisphenol as a prill or flake and (f) drying said prill or flake.