Gloss black metalized product and method of preparation

• US 4,535,024 A
• Filed: 11/01/1982
• Issued: 08/13/1985
• Est. Priority Date: 11/01/1982
• Status: Expired due to Fees

• Current Assignee: Transfer Print Foils
• Original Assignee: Transfer Print Foils
• Inventors: Parker, Harry A.
• Primary Examiner(s): HERBERT JR, THOMAS
• Application Number:
  US06/438,220
• Time in Patent Office: 1,016 Days
• Field of Search: 428/457, 428/461, 428/343, 428/31, 428/914, 428/913, 428/425, 428/200, 428/204, 428/469, 428/205, 428/347, 428/201, 428/209, 427/248.1, 427/250, 427/162, 427/383.1, 528/49, 204/159.15, 204/159.14, 156/233
• US Class Current: 428/200
• CPC Class Codes: B44C 1/14 Metallic leaves or foils, e.g. gold leaf
• CPC Class Codes: B44C 1/1737 Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff on a substrate unsuitable for direct deposition
• CPC Class Codes: B44C 3/025 Superimposing layers to produce ornamental relief structures
• CPC Class Codes: B44F 1/02 produced by reflected light, e.g. matt surfaces, lustrous surfaces
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 428/914 Transfer or decalcomania
• CPC Class Codes: Y10T 428/24843 with heat sealable or heat releasable adhesive layer
• CPC Class Codes: Y10T 428/24876 Intermediate layer contains particulate material [e.g., pigment, etc.]
• CPC Class Codes: Y10T 428/24884 Translucent layer comprises natural oil, wax, resin, gum, glue, gelatin
• CPC Class Codes: Y10T 428/24917 including metal layer
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/2817 Heat sealable
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

A glossy black reflective metal coating with improved durability is prepared as a film of an intrinsically blackened chromium-containing metal. A laminate may be prepared with the metal coating bonded to at least one transferable resin film. A particular laminate includes at least one top coat and at least one base coat, with the metal coating located in sandwich relationship therebetween.

Claims

1. A decorative laminate offering a glossy black outer appearance of improved durability, comprising:

A. at least one base film;

B. a translucent, black reflective metal coating comprising a chromium-containing metal having a black appearance, applied over one surface of said base film, said coating formed by heating said metal to an elevated temperature above its boiling point and above the normal vaporization temperature of the metal, and vapor depositing said metal on said base film while maintaining said metal at said elevated temperature; and

C. a top coat comprising a clear thermoplastic resin, applied over the free surface of said translucent metal coating.

2. The laminate of claim 1 wherein

said base film is pigmented,

a tie coat is present between said base film and said translucent metal coating, and

an intermediate coat comprising an organic resinous coating material curable by ultraviolet light is present between said top coat and said translucent metal coating.

3. The laminate of claim 2 further including a heat-sensitive adhesive coating located on the free surface of said base film.

4. A coated article comprising at least one base film having a glossy black reflective metal coating thereon, said coating having improved durability and comprising a vapor deposited film of an intrinsically blackened chromium-containing metal formed by heating said metal prior to conducting the vapor deposition to a temperature above the boiling point of the metal and above the normal vaporization temperature of the metal, and maintaining said metal at said temperature throughout said vapor deposition.

5. The article of claim 4 wherein said metal film is prepared to a thickness offering a translucent visual appearance.

6. A decorative laminate product comprising at least one transferable resin film having bonded thereto the metal coating of claim 4.

7. The article of claim 4 wherein said chromium-containing metal is selected from the group consisting of nickel-chromium alloys, chromium-iron alloys, chromium-steel alloys, pure chromium, and mixtures thereof.

8. The article of claim 7 wherein said chromium-containing metal comprises a nickel-chromium alloy.