Alkaline resistant primer and the use thereof

• US 4,536,534 A
• Filed: 12/29/1983
• Issued: 08/20/1985
• Est. Priority Date: 01/27/1983
• Status: Expired due to Fees

• Current Assignee: Wacker-Chemie GmbH (Dr. Alexander Wacker Familiengesellschaft Mit Beschrã¤Nkter Haftung)
• Original Assignee: Wacker-Chemie GmbH (Dr. Alexander Wacker Familiengesellschaft Mit Beschrã¤Nkter Haftung)
• Inventors: Singer, Robert, Goetze, Richard, Maier, Karl, Kerbl, Maximilian
• Primary Examiner(s): Page, Thurman K.
• Application Number:
  US06/566,522
• Time in Patent Office: 600 Days
• Field of Search: 427/393.6, 427/407.1, 427/387, 524/262, 524/261, 524/265, 524/269, 524/832
• US Class Current: 524/262
• CPC Class Codes: C04B 14/40 Asbestos
• CPC Class Codes: C04B 2111/00112 Mixtures characterised by specific pH values
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/463 Organic solvents
• CPC Class Codes: C04B 41/483 Polyacrylates
• CPC Class Codes: C04B 41/4927 Alkali metal or ammonium salts
• CPC Class Codes: C04B 41/4972 Alkali metal or ammonium salts
• CPC Class Codes: C04B 41/502 Water
• CPC Class Codes: C04B 41/64 Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C09D 133/064 containing anhydride, COOH or COOM groups, with M being metal or onium-cation

Abstract

An aqueous primer based on alkali-soluble acrylic resins and siliconates, especially suitable for strongly alkaline substrates, for example, asbestos cement articles, is provided. The primer is characterized by stability to storage and good compatibility with the substrate and with customary coating agents, and it brings about good water repellence, good stabilization of the substrate and a good binding between the substrate and the final coating.

Claims

1. A primer for mineral substrates that is stable to hydrolysis and to storage and is based on colloidal aqueous solutions of mixtures of synthetic resins, siliconates, organic solvents and additives, consisting essentially in that 100 parts by weight of the primer contains, in addition to water,

from 4 to 15 parts by weight of an alkali-soluble acrylic resin comprising from 86% to 94% by weight of monomer units derived from C₁ to C₈ -alkyl esters of unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid and mixtures thereof, and from 6% to 14% by weight of monomer units derived from the unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof, and having a K-value according to Fikentscher of not more than 50,

from 4 to 40 parts by weight of organic solvents that are water-soluble in the context of the present composition and are selected from the group consisting of compounds containing hydroxy groups, carbonyl groups and mixtures of hydroxy and carbonyl groups

from 0.1 to 1.5 parts by weight of alkali metal organo-siliconates, and an alkalinizing agent selected from the group consisting of of ammonia, organic amines and mixtures thereof in sufficient quantities that the pH of the primer is at least 8,

from 0 to 1 part by weight of at least one compatible anti-foaming agent.

2. The primer of claim 1 having a further content of from 0.2 to 1 part by weight of at least one compatible anti-foaming agent, per 100 parts by weight.

3. The primer of claim 1 having from 6 to 9 parts by weight of said alkali-soluble acrylic resin and from 0.15 to 0.5 parts by weight of said alkali metal organosiliconates.

4. The primer of claim 1 having from 4 to 15 parts by weight of said organic solvents.

5. The primer of claim 3 having from 4 to 15 parts by weight of said organic solvents.

6. The primer of claim 1 having a pH of from 8 to 11.

7. The primer of claim 1 having a pH of from 9 to 10 .

8. The primer of claim 5 wherein said alkali metal siliconate is selected from the group consisting of sodium methylsiliconate, potassium methylsiliconate, sodium propylsiliconate and potassium propylsiliconate.

9. A method of coating strongly alkaline mineral substrates which comprises applying to a strongly alkaline mineral substrate a primer consisting essentially in that 100 parts by weight of the primer contains, in addition to water,

from 4 to 15 parts by weight of an alkali-soluble acrylic resin comprising from 86% to 94% by weight of monomer units derived from C₁ to C₈ -alkyl esters of unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid and mixtures thereof, and from 6% to 14% by weight of monomer units derived from unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof, and having a K-value according to Fikentscher of not more than 50,

from 4 to 40 parts by weight of organic solvents that are water-soluble in the context of the present composition and are selected from the group consisting of compounds containing hydroxy groups, carbonyl groups and mixtures of hydroxy and carbonyl groups

from 0.1 to 1.5 parts by weight of alkali metal organosiliconates, and an alkalinizing agent selected from the group consisting of ammonia, organic amines and mixtures thereof in sufficient quantities that the pH of the primer is at least 8

and from 0 to 1 part by weight of at least one compatible anti-faming agent.

10. The method of claim 9 wherein said primer has a further content of from 0.2 to 1 part by weight of at least one compatible anti-foaming agent, per 100 parts by weight.

11. The method of claim 9 wherein said primer has from 6 to 9 parts by weight of said alkali-soluble acrylic resin and from 0.15 to 0.5 parts by weight of said alkali metal organosiliconates.

12. The method of claim 9 wherein said primer has from 4 to 15 parts by weight of said organic solvents.

13. The method of claim 9 wherein said primer has a pH of from 8 to 11.

14. The method of claim 9 wherein said alkali metal siliconate is selected from the group consisting of sodium methylsiliconate, potassium methylsiliconate, sodium propylsiliconate and potassium propylsiliconate.