Organic electroluminescent devices having improved power conversion efficiencies
First Claim
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1. In an electroluminescent device comprising, in sequence, an anode electrode, a hole-injecting zone, an organic luminescent zone, and a cathode electrode, at least one of said electrodes being capable of transmitting at least 80% of radiation having wavelengths longer than 400 nm,the improvement wherein said luminescent zone comprises an electron-transporting compound that provides a maximum electroluminescent quantum efficiency of at least about 5×
- 10-4 photons/electron, when used in a test device driven at no more than the lesser of (i) 25 volts and (ii) the voltage which produces the maximum power conversion efficiency of said device, said test device comprising (1) a hole-injecting zone consisting essentially of 1,1-bis-(4-di-p-tolylaminophenyl)cyclohexane, said hole-injecting zone and said luminescent zone having a combined thickness of no more than 1 micron, (2) an anode electrode that transmits at least 80% of radiation having wavelengths longer than 400 nm, and (3) an indium cathode,and wherein said device has a power conversion efficiency of at least 9×
10-5 w/w and said zones have a combined thickness that is no greater than about 1 micron.
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Abstract
Electroluminescent devices are disclosed comprising a hole-injecting zone and an adjacent organic luminescent zone, the device having a power conversion efficiency of at least 9×10-5 w/w and said zones having a combined thickness no greater than about 1 micron.
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Citations
9 Claims
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1. In an electroluminescent device comprising, in sequence, an anode electrode, a hole-injecting zone, an organic luminescent zone, and a cathode electrode, at least one of said electrodes being capable of transmitting at least 80% of radiation having wavelengths longer than 400 nm,
the improvement wherein said luminescent zone comprises an electron-transporting compound that provides a maximum electroluminescent quantum efficiency of at least about 5× - 10-4 photons/electron, when used in a test device driven at no more than the lesser of (i) 25 volts and (ii) the voltage which produces the maximum power conversion efficiency of said device, said test device comprising (1) a hole-injecting zone consisting essentially of 1,1-bis-(4-di-p-tolylaminophenyl)cyclohexane, said hole-injecting zone and said luminescent zone having a combined thickness of no more than 1 micron, (2) an anode electrode that transmits at least 80% of radiation having wavelengths longer than 400 nm, and (3) an indium cathode,
and wherein said device has a power conversion efficiency of at least 9×
10-5 w/w and said zones have a combined thickness that is no greater than about 1 micron. - View Dependent Claims (2, 3, 4, 5, 6)
- 10-4 photons/electron, when used in a test device driven at no more than the lesser of (i) 25 volts and (ii) the voltage which produces the maximum power conversion efficiency of said device, said test device comprising (1) a hole-injecting zone consisting essentially of 1,1-bis-(4-di-p-tolylaminophenyl)cyclohexane, said hole-injecting zone and said luminescent zone having a combined thickness of no more than 1 micron, (2) an anode electrode that transmits at least 80% of radiation having wavelengths longer than 400 nm, and (3) an indium cathode,
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7. In an electroluminescent device comprising, in sequence, an anode electrode, a hole-injecting zone, an organic luminescent zone, and a cathode electrode, at least one of said electrodes being capable of transmitting at least 80% of radiation having wavelengths longer than 400 nm, the improvement wherein said hole-injecting zone comprises an amine that transmits at least about 90% of radiation having wavelengths greater than 400 nm, at least one nitrogen atom of the amine being trisubstituted with substituents at least one of which is aryl, said amine being solid at room temperature and having the structural formula ##STR28## wherein Q1 and Q2 are individually moieties containing nitrogen and at least 3 carbocyclic rings at least one of which is aromatic, and,
G is a linking group or a carbon-to-carbon bond, whereby said amine is thin-film-forming.
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8. In an electroluminescent device comprising, in sequence, an anode electrode, a hole-injecting zone, an organic luminescent zone, and a cathode electrode, at least one of said electrodes being capable of transmitting at least 80% of radiation having wavelengths longer than 400 nm, the improvement wherein said hole-injecting zone comprises an amine selected from the group consisting of
bis(4-dimethylamino-2-methylphenyl)phenylmethane; - N,N,N-tri(p-tolyl)amine;
1,1-bis(4-di-p-tolylaminophenyl)cyclohexane; and 1,1-bis(4-di-p-tolylaminophenyl)-4-phenylcyclohexane.
- N,N,N-tri(p-tolyl)amine;
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9. In an electroluminescent device comprising, in sequence, an anode electrode, a hole-injecting zone, an organic luminescent zone, and a cathode electrode,
at least one of said electrodes being capable of transmitting at least 80% of radiation having wavelengths longer than 400 nm, the improvement wherein said hole-injecting zone comprises 1,1-bis(4-di-p-tolylaminophenyl)cyclohexane; -
and said luminescent zone comprises 2,5-bis(5,7-di-t-pentyl-2-benzoxazolyl)-1,3,4-thiadiazole; said two zones having a combined thickness no greater than about 1 micron.
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Specification