High resolution in situ ultrasonic corrosion monitor

• US 4,539,846 A
• Filed: 01/10/1984
• Issued: 09/10/1985
• Est. Priority Date: 01/10/1984
• Status: Expired due to Fees

• Current Assignee: United States Department of Energy
• Original Assignee: United States Department of Energy
• Inventors: Grossman, Robert J.
• Primary Examiner(s): Ciarlante, Anthony V.
• Application Number:
  US06/569,700
• Time in Patent Office: 609 Days
• Field of Search: 73/86, 73/597, 73/61.2, 422/53
• US Class Current: 73/597
• CPC Class Codes: G01N 17/00 Investigating resistance of materials to the weather, to corrosion, or to light
• CPC Class Codes: G01N 2291/0258 Structural degradation, e.g. fatigue of composites, ageing of oils
• CPC Class Codes: G01N 29/07 by measuring propagation velocity or propagation time of acoustic waves

Abstract

An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

Claims

1. An in situ ultrasonic corrosion monitoring system comprising:

an elongate corrodible probe including at least one monitoring zone defined between first and second discontinuities, and being adapted to be exposed to a corrosive environment;

means for applying ultrasonic pulses to said monitoring zone of said probe while the probe is exposed to the corrosive environment, for receiving the corresponding pulses reflected from said first and second discontinuities, and for converting the received pulses into corresponding electrical signals; and

signal processing means for determining the time delay intervals between the electrical signals corresponding to the pulses reflected from the first discontinuity and the electrical signals corresponding to pulses reflected from the second discontinuity while the probe is exposed to the corrosive environment, and for providing an indication of the corrosion thickness on the monitoring zone of said probe based on said determination of the time delay intervals.

2. An in situ ultrasonic corrosion monitoring system as claimed in claim 1 wherein said first discontinuity is provided at the junction between said monitoring zone and a lead-in portion of said probe and said second discontinuity is provided at the free end of the probe.

3. An in situ ultrasonic corrosion monitoring system as claimed in claim 1 wherein said pulse generating and receiving means comprises a transducer located at the opposite end of said probe from said monitoring zone.

4. An in situ ultrasonic corrosion monitoring system as claimed in claim 3 wherein said transducer comprises a magnetostrictive transducer.

5. An in situ ultrasonic corrosion monitoring system as claimed in claim 4 wherein said magnetostrictive transducer comprises a magnetostrictive stub attached to a lead-in portion of said probe and a coil surrounding said stub.

6. An in situ ultrasonic corrosion monitoring system as claimed in claim 4 further comprising means for providing an external magnetic field for enhancing the magnetostriction effect of said magnetostrictive transducer.

7. An in situ ultrasonic corrosion monitoring system as claimed in claim 5 wherein said transducer coil comprises a pulsing-receiving coil to which are applied both electrical pulses for pulsing said probe and ultrasonic pulses reflected from said probe.

8. An in situ ultrasonic corrosion monitoring system as claimed in claim 1 wherein said pulse applying means and reflected pulse receiving means comprises a pulser/receiver transducer to which electrical pulses are applied to cause ultrasonic pulses to be applied to the probe and by which ultrasonic pulses reflected by said probe are received and converted into corresponding electrical signals.

9. An in situ ultrasonic corrosion monitoring system as claimed in claim 1 wherein said monitoring system further includes calibration means, including a calibration wire subjected to the same corrosive environment as the probe, for assisting in calibrating the operation of the system.

10. An apparatus as claimed in claim 1 wherein said probe comprises a thin wire and said transducer comprises a magnetostrictive transducer.

11. An in situ corrosion monitoring method comprising:

locating, in a corrosive environment, a corrodible monitoring probe having at least one monitoring zone defined between first and second discontinuities;

applying ultrasonic pulses to the monitoring zone of the said probe;

detecting the ultrasonic pulses reflected from said first and second discontinuities;

determining the time interval between the reflected pulses; and

using the time interval determination to determine the amount of corrosion of said probe.

12. A method as claimed in claim 11 wherein said time interval determinations are made as the monitoring zone of the probe is corroding and a ratio of these measurements to the time interval of the uncorroded monitoring zone is obtained corresponding to the normalized delay time delay interval.

13. A method as claimed in claim 12 wherein said ratio is set equal to ##EQU8## where F₁ is equal to the square of the ultrasonic velocity in the corrosion film divided by the ultrasonic velocity in the base metal;

F₂ is equal to the corrosion film density divided by the base metal density; and

F₃ is the corrosion film cross-sectional area divided by the base metal cross-sectional area.

14. A method as claimed in claim 11 further comprising calibrating the probe using a calibration wire exposed to the same corrosive environment, said calibration wire being removed from the corrosive environment to determine the amount of corrosion thereof.

15. A method as claimed in claim 11 wherein temperature measurements are made within the corrosive environment and used to adjust the measured time intervals to a fixed temperature.