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Insecticidal cyclopropane carboxylic acid derivatives with 3-unsaturated-side chain

  • US 4,542,142 A
  • Filed: 11/08/1983
  • Issued: 09/17/1985
  • Est. Priority Date: 11/22/1982
  • Status: Expired due to Term
First Claim
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1. A compound selected from the group consisting of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR58## wherein A'"'"' is selected from the group consisting of (1) ##STR59## wherein B is selected from the group consisting of --CH2 --, ##STR60## and --S--, R4 is selected from the group consisting of hydrogen, --CH3, --C.tbd.N and --C.tbd.CH, D is selected from the group consisting of hydrogen and fluorine, n is an integer from 0, 1 or 2 and R5 is selected from the group consisting of halogen and --CH3 ##STR61## wherein R13 is selected from the group consisting of hydrogen and --CN, ##STR62## wherein R14 is selected from the group consisting of hydrogen, methyl, ethynyl and --CN and R15 and R16 are individually selected from the group consisting of hydrogen, bromine and fluorine and 4 ##STR63## wherein R14 has the above definition, p is 1, R17 is hydrogen, B'"'"' is selected from the group consisting of --O-- and --S--, R is selected from the group consisting of --(CH2)n --C--Hal3, --(CH2)npl --CHHal2, --(CH2)n --CH2 --Hal,--C--(CHal3)3, ##STR64## Hal is a halogen and n is an integer from 1 to 8, the double bond having Z or E geometry.

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