Graded affinity photovoltaic cell

• US 4,542,256 A
• Filed: 04/27/1984
• Issued: 09/17/1985
• Est. Priority Date: 04/27/1984
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: University of Delaware
• Inventors: Wiedeman, Scott
• Primary Examiner(s): Weisstuch, Aaron
• Application Number:
  US06/604,786
• Time in Patent Office: 508 Days
• Field of Search: 136/249 TJ, 136/255, 136/258 AM, 357/2, 357/30, 29/572, 427/74, 427/39, 427/86
• US Class Current: 136/249
• CPC Class Codes: H01L 31/065 the potential barriers being only of the graded gap type
• CPC Class Codes: H01L 31/075 the potential barriers being only of the PIN type, e.g. amorphous silicon PIN solar cells
• CPC Class Codes: Y02E 10/548 Amorphous silicon PV cells

Abstract

An improved photovoltaic cell, and method for its manufacture, comprising front and back electrically conductive layers between which is sandwiched a primary light-absorbing layer of amorphous semiconducting material displaying low photogenerated carrier mobility below about 50 cm² /V second, the constitution of which primary layer is fabricated to provide an affinity gradient reducing back-diffusion of a preselected species of photogenerated carrier (electrons or holes) to thereby forestall non-productive recombination with carriers of opposite type.

Claims

1. An improved photovoltaic cell comprising at least a front electrically conductive layer upon which radiation is incident and a back electrically conductive layer, between which is sandwiched a primary light-absorbing layer of substantially intrinsic amorphous semiconducting material displaying low photogenerated carrier mobility below about 50 cm² /Voltsecond, the constitution of said primary light-absorbing layer being fabricated to provide an affinity gradient at one end of said primary light-absorbing layer adjacent one of said front and back electrically conductive layers for reducing back diffusion of a preselected species of photogenerated carrier chosen from electrons and holes to thereby reduce non-productive recombination with carriers of opposite type.

2. An improved photovoltaic cell according to claim 1 wherein both ends of said primary light-absorbing layer of amorphous semiconducting material are provided with appropriate affinity gradients to thereby prevent non-productive recombination with carriers of opposite type.

3. An improved photovoltaic cell according to claim 1 comprising at least two primary light-absorbing layers in tandem wherein at least one of said primary light-absorbing layers is provided with an appropriate affinity gradient to thereby prevent non-productive recombination with carriers of opposite type.

4. An improved photovoltaic cell according to claim 3 wherein each primary light absorbing layer is provided with the appropriate affinity gradient to thereby prevent non-productive recombination with carriers of opposite type.

5. An improved photovoltaic cell according to claim 1 wherein said primary light-absorbing layer is selected from the group consisting of SiGe, SiC, SiN, SiO, SiSn, and elemental Si.

6. In the method of manufacturing an improved photovoltaic cell comprising at least a front electrically conductive layer upon which radiation is incident and a back electrically conductive layer between which is sandwiched a primary light-absorbing layer of substantially intrinsic amorphous semiconducting material displaying low photogenerated carrier mobility below about 50 cm² /V-second, the step of providing an affinity gradient for said primary light-absorbing layer in the region adjacent one of said front and back electrically conductive layers for reducing back diffusion of a preselected species of photogenerated carrier chosen from electrons and holes to thereby reduce non-productive recombination with carriers of opposite type.

7. The method of manufacturing an improved photovoltaic cell according to claim 6 wherein said affinity gradient is fabricated utilizing alloy compostion tapering, sputtering, chemical vapor deposition, glow discharge, hydrogenation, fluorination, and combinations thereof.

8. The method of manufacturing an improved photovoltaic cell according to claim 6 wherein said primary light absorbing layer is fabricated from a-SiGe and said affinity gradient is provided by tapering the composition of at least one end of said primary absorbing layer during manufacture by simultaneously supplying flowing streams of silane, germane:

hydrogen and hydrogen in varying amounts preselected to taper the composition of at least one end region from the original composition of said a-SiGe to a terminal value at the distal end of said end region of substantially a-Si, zero Ge.