Selective gas detection and measurement system

• US 4,542,640 A
• Filed: 09/15/1983
• Issued: 09/24/1985
• Est. Priority Date: 09/15/1983
• Status: Expired due to Fees

• Current Assignee: Mosaic Co. /Old/ (The Mosaic Company)
• Original Assignee: Paul K. Clifford
• Inventors: Clifford, Paul K.
• Primary Examiner(s): Kreitman, Stephen A.
• Application Number:
  US06/532,651
• Time in Patent Office: 740 Days
• Field of Search: 73/23, 73/27 R, 324/71.5, 340/632, 340/633, 340/634, 422/98
• US Class Current: 73/31.06
• CPC Class Codes: G01N 27/122 Circuits particularly adapted therefor, e.g. linearising circuits
• CPC Class Codes: G01N 33/0031 comprising two or more sensors, e.g. a sensor array

Abstract

A gas detecting system for determining the presence and concentrations of a number of selected toxic, combustible, or reducing gases in an atmosphere. The system includes a plurality of semiconductor gas sensors, each of which differs from each of the others in its response to at least one of the selected gases. The system includes a means of processing the responses of each sensor to produce an indication of each of the gas concentrations. The system may also produce indications of the measurement accuracy of each gas concentration, which can be used to determine the presence of gases not selected for detection.

Claims

1. A system for selectively detecting, measuring, and identifying a selected number of gases in an atmosphere comprising:

a plurality of semiconductor sensors, greater or equal in number to the number of selected gases, each with a predetermined response characteristic which differs from the response characteristic of each of the other sensors in its response to at least one of the set of selected gases;

means, coupled to each of said sensors, for deriving a plurality of electrical signals, each of said signals representing the response to said atmosphere of a respectively different one of said sensors; and

electrical signal processing means, responsive to said plurality of derived signals, for developing respective indications of the concentrations of each of said selected gases as solutions of a set of equations, each of which is of the form ##EQU3## in which F(R) indicates a known and previously measured function of the response signal R of the particular sensor, j is a counter which indicates the gas type, M is the number of selected gases, [G_j ] represent the concentrations of the selected gases, n_ij are numerical constants of the particular sensor, Σ

is the symbol representing summation, i is a counter which distinguishes individual terms in the summation, L is the total number of terms in the summation, π

is the symbol representing products, and the K_i are previously measured numerical constants of the particular sensor.

2. The system of claim 1, wherein said electrical signal processing means includes means for determining the errors associated with each gas concentration indication.

3. The system of claim 1, wherein said electrical signal processing means includes means for indicating the presence of a gas or gases other than those selected for detection.

4. The system of claim 1, wherein said plurality of semiconductor sensors is fabricated on a single substrate.

5. The system of claim 1, wherein said electrical signal processing means includes means for indicating when the concentration of a selected one of said selected gases or of a combination of said selected gases exceeds a predetermined threshold value.

6. A system according to claim 1, including

a plurality of sensor heads each in separate locations dispersed about an environment, one of said heads including said plurality of semiconductor sensors, the others of said heads each consisting of an additional plurality of semiconductor sensors, and

means responsive to signals derived from the sensors of said other heads to determine the concentrations of selected sets of gases at each of said other sensor head locations.

7. The system of claim 1, wherein the differences of said response characteristics of at least some of said sensors result from differences in their preparation.

8. The system of claim 1, wherein the differences of said response characteristics of at least some of said sensors result from differences in their operating temperature.

9. The system of claim 1, wherein the differences of said response characteristics of at least some of said sensors result from differences in their combination with a filtering structure.

10. A system of claim 1, wherein at least one of said plurality of sensors is a semiconductor sensor.

11. A system of claim 1, wherein at least one of said plurality of sensors is a solid state sensor.

12. A system of claim 1, wherein at least one of said plurality of sensors is a homogeneous sensor.

13. The system of claim 1, wherein the differences of said response characteristics of at least some of said sensors result from differences in their composition.

14. The system of claim 1, wherein said electrical signal processing means comprises a digital processor.

15. A method for selectively detecting a selected number of gases in an atmosphere, comprising:

deriving from a plurality of sensors a plurality of electrical signals, each of said signals representing the response to said atmosphere of a respectively different one of said sensors, said plurality of sensors being greater or equal in number to the number of selected gases and each having a response characteristic which differs from the response characteristic of each of the other sensors in its response to at least one of the set of selected gases; and

electrically processing said plurality of derived signals, for developing respective indications of the concentrations of each of said selected gases as solutions of a set of nonlinear equations, said set of nonlinear equations including terms proportional to products of powers of gas concentrations.

16. A method according to claim 15, wherein each of said equations is of the form:

##EQU4## in which F(R) indicates a known and previously measured function of the response signal R of the particular sensor, j is a counter which indicates the gas type, M is the number of selected gases, [G_j ] represent the concentrations of the selected gases;

n_ij are numerical constants of the particular sensor, Σ

is the symbol representing summation, i is a counter which distinguishes individual terms in the summation, L is the total number of terms in the summation, π

is the symbol representing products, and the K_i are previously measured numerical constants of the particular sensor.