Method for imparting elastic properties to a flexible substrate

• US 4,543,099 A
• Filed: 07/19/1982
• Issued: 09/24/1985
• Est. Priority Date: 12/06/1978
• Status: Expired due to Term

• Current Assignee: H.B. Fuller Licensing & Financing, Inc.
• Original Assignee: HB Fuller Company
• Inventors: Bunnelle, William L., Lindmark, Richard C. Jr.
• Primary Examiner(s): Weston, Caleb
• Application Number:
  US06/399,780
• Time in Patent Office: 1,163 Days
• Field of Search: 156/243, 156/244.11, 156/244.23, 156/244.24, 156/210, 156/229, 156/164, 156/183, 156/231, 156/269, 156/324, 156/334, 2/401, 525/97, 525/98, 428/152, 428/517, 428/906, 604/385
• US Class Current: 604/385.24
• CPC Class Codes: A41F 9/02 Expansible or adjustable belts or girdles ; Adjustable fasteners comprising a track and a slide member A41F1/008, A41F9/002 take precedence
• CPC Class Codes: A61F 13/15593 having elastic ribbons fixed thereto; Devices for applying the ribbons
• CPC Class Codes: B32B 2037/1223 film-shaped
• CPC Class Codes: B32B 2307/51 Elastic
• CPC Class Codes: B32B 2309/02 Temperature
• CPC Class Codes: B32B 2309/105 Thickness
• CPC Class Codes: B32B 2309/12 Pressure
• CPC Class Codes: B32B 2555/02 Diapers or napkins
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 37/12 characterised by using adhesives
• CPC Class Codes: B32B 37/144 using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding constructional features for tensioning B32B38/1825
• CPC Class Codes: B32B 37/153 at least one layer is extruded and immediately laminated while in semi-molten state
• CPC Class Codes: B32B 37/203 One or more of the layers being plastic
• CPC Class Codes: B32B 38/06 Embossing
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10S 428/906 Roll or coil
• CPC Class Codes: Y10T 156/1084 of continuous or running length bonded web
• CPC Class Codes: Y10T 428/24446 Wrinkled, creased, crinkled or creped
• CPC Class Codes: Y10T 428/31917 Next to polyene polymer

Abstract

A purpose of the disclosed method is to impart gathers and elasticity to a relatively inelastic film, membrane, or web substrate, through elastic banding with a viscoelastic hot melt pressure-sensitive adhesive (PSA). Typically, the resulting elastic-banded substrate product (e.g. 40) will be cut into discrete units and formed in to garments or body-encircling members such as disposable diapers. One step of the preferred method involves extruding a ribbon or band (13 or 113) comprising a viscoelastic hot melt PSA, which PSA has unusually high cohesion, stretchiness, and elasticity without excessive loss of adhesive bonding strength. (The viscoelastic behavior of the PSA is believed to be determined, at least in part, by the relative size of its crystalline domains and its rubbery domains and the glass transition temperatures and softening point of its components.) A second step of the preferred method involves bringing the band of hot melt (13 or 113) into adherent contact with a surface of a moving continuous substrate (22 or 32 or 132). A typical substrate would be the polyolefin film used in the manufacture of disposable diapers. The band can be bonded to the substrate through a pressure activation technique, wherein the band itself has the necessary inherent adhesive properties.

Claims

1. A method for imparting elastic properties to a flexible substrate, which comprises contacting a surface of the flexible substrate with a band of a self-adhering elastic composition which consists essentially of:

a major amount by weight, not exceeding 70% by weight, of a rubbery block copolymer, which copolymer includes a rubbery midblock portion and which is terminated with vinyl arene endblocks, about 70 to 80% by weight of said rubbery block copolymer comprising said rubbery midblock portion and about 20 to about 30% by weight of said rubbery block copolymer comprising said vinyl arene endblock;

a minor amount by weight, not less than 30% by weight, of a tackifying resin generally compatible with and generally associated with said midblock portion;

- 9% by weight of an aromatic, essentially hydrocarbon resin having a glass transition temperature and a softening point above those of said vinyl arene endblocks and said tackifying resin;

said aromatic, essentially hydrocarbon resin being generally compatible with and generally associated with said endblock; and

0-5% by weight of essentially inert extenders, fillers, pigments, and antioxidants that do not substantially affect the adhesive of elastic properties of the composition;

the foregoing proportions being selected to provide the following pressure-sensitive adhesive and rheological properties;

(i) a tensile strength at 500% elongation, determined at 20°

-25°

C., of at least 50 pounds per square inch;

(ii) a 180°

peel resistance, according to PSTC-1, determined at 20°

-25°

C. for 24 hours after formation of the pressure-sensitive adhesive bond, of at least about 450 grams per 25.4 millimeter-width;

(iii) a dead load deformation, tested at room temperature, 37.8°

C., 43.3°

C., and 48.9°

C. for 3 hours under 1500 g/cm², of less than 50%, where dead load deformation is equal to the increased length minus the original length divided by the original length of a sample at least 25 millimeters in length, and a loss modulus, a storage, modulus, and a loss tangent measured at 0.01-0.25 Hz throughout the temperature range of 25°

-50°

C. as follows;

loss modulus;

4×

10⁴ to 35×

10⁴ dynes/cm²

storage modulus;

75×

10⁴ to 200×

10⁴ dynes/cm²

loss tangent;

0.03 to 0.3.

2. The method of claim 1 wherein the flexible substrate is substantially inelastic.

3. The method of claim 2 wherein the flexible substrate is pregathered.

4. The method of claim 1 wherein prior to contacting the band with the flexible substrate the band is formed by extruding the self-adhering elastic composition at a temperature above its endblock Tg and cooling the extruded band to a temperature below its endblock Tg but above its midblock Tg.

5. The method of claim 4 wherein the band is simultaneously cooled and contacted with the flexible substrate.

6. The method of claim 1 wherein the band is placed under tension, at a temperature below its endblock Tg, in such a manner that the band is elongated when contacted with the surface of the flexible substrate and when the tension is released, gathers in the substrate form along the line of the bond between the band and the substrate.

7. The method of claim 1 wherein the band is continuously contacted with the surface of the flexible substrate.

8. The method of claim 1 wherein the flexible substrate is less than 3 millimeters thick and comprises a film of a polymeric material, a woven web or a nonwoven web.

9. The method of claim 1 wherein:

(a) the block copolymer comprises at least one substantially amorphous midblock and at least two polyvinyl arene endblocks;

(b) about 20 to 150 parts by weight of the midblock associating resin; and

(c) about 10 to 150 parts by weight of the endblock associating resin which comprises an aromatic, essentially hydrocarbon endblock associating resin having a Tg and a softening point greater than the copolymer endblocks and the midblock associating resin, each per 100 parts by weight of component (a).

10. The method of claim 9 wherein the self-adhering elastic composition has the following rheological properties at a temperature of about 25°

-50°

C.;

space="preserve" listing-type="tabular">______________________________________ 0.01 Hz 0.25 Hz ______________________________________ loss modulus, 10.sup.4 dynes/cm.sup.2 5-25 10-100 storage modulus, 10.sup.4 dynes/cm.sup.2 75-200 75-200 loss tangent 0.05-0.3 0.08-1.0. ______________________________________

11. The method of claim 10 wherein said rheological properties are as follows:

space="preserve" listing-type="tabular">______________________________________ 0.01 Hz 0.25 Hz ______________________________________ loss modulus, 10.sup.4 dynes/cm.sup.2 8-16 13-35 storage modulus, 10.sup.4 dynes/cm.sup.2 100-175 120-200 loss tangent 0.07-0.10 0.1-0.25. ______________________________________

12. The method of claim 11 wherein the dead load deformation of said self-adhering elastic composition at 37.8°

C. for 3 hours, and 1500 g/cm² of cross section, is less than about 50%.

13. An article which comprises a product of the method of claim 11.

14. The article of claim 13 which comprises a disposable diaper.

15. A method for imparting a self-adhering elastic to a flexible substrate comprising the steps of:

(a) unreeling a band of self-adhering elastic composition from a roll, said roll being maintained at a temperature below the softening point of said self-adhering elastic and said band of self-adhering elastic being an extrudate at least 50 microns in thickness which consists essentially of (i) a block copolymer comprising at least one substantially amorphous, rubbery polymeric midblock and at least two glassy poly(vinylarene) endblocks;

(ii) 30-115 parts per hundred of a midblock associating resin; and

(iii) 3-20 parts per hundred of an aromatic, essentially hydrocarbon endblock associating resin having a Tg and a softening point above 115°

C. each per one hundred parts of the block copolymer;

wherein the proportions (i), (ii), and (iii) are selected to provide the following properties;

(i) a tensile strength at 500% elongation, determined at 20°

-25°

C., of at least 50 pounds per square inch;

(ii) a 180°

peel resistance, according to PSTC-1, determined at 20°

-25°

C. 24 hours after formation of the pressure-sensitive adhesive bond, of at least about 450 grams per 25.4 mm-width;

(iii) a dead load deformation, tested at 37.8°

C. and 1500 g/cm², less than 50%; and

(iv) a loss modulus of 5×

10⁴ to 100×

10⁴ dynes/cm², a storage modulus of 65×

10⁴ to 225×

10⁴ dynes/cm², and a loss tangent of 0.3 to 1.0, at 0.01-0.25 Hz at 25°

-50°

C.;

(b) contacting the band of self-adhering elastic with a surface of a flexible substrate forming a bond between the substrate and elastic.

16. The method of claim 15 wherein the substrate is substantially inelastic.

17. The method of claim 15 wherein the band is placed under tension in such a manner that it is elongated when contacted with the flexible substrate and when the tension is released, gathers in the substrate form along the line of the bond between the band and the substrate.

18. The method of claim 15 wherein the band has a backing.

19. The method of claim 18, wherein the backing of the band comprises a release liner which is removed from the band prior to contacting the band with the flexible substrate.

20. The method of claim 18, wherein the backing of the band is substantially elastomeric.

21. The method of claim 18 wherein the self-adhering elastic has been formed by coextruding the backing and the band, and wherein the backing has release characteristics.

22. An article which comprises a product of the method of claim 15.

23. The article of claim 22 which comprises a disposable diaper.