Hydrogen generator

• US 4,543,246 A
• Filed: 10/04/1984
• Issued: 09/24/1985
• Est. Priority Date: 10/04/1984
• Status: Expired due to Term

• Current Assignee: Clifford F. Houser
• Original Assignee: Clifford F. Houser
• Inventors: Houser, Clifford F.
• Primary Examiner(s): Doll, John
• Assistant Examiner(s): Langel, Wayne A.
• Application Number:
  US06/657,508
• Time in Patent Office: 355 Days
• Field of Search: 423/648 R, 423/659, 423/657, 422/62, 422/109, 422/233, 422/235
• US Class Current: 423/648.1
• CPC Class Codes: B01J 7/02 by wet methods
• CPC Class Codes: C01B 3/08 with metals
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A gas generator in which the gas is produced by a reaction between a solid metal and a liquid reactant. The generator is operated to produce hydrogen intended as an energy source particularly for operating internal combustion engines. A solid reactant is reacted with a liquid reactant under conditions in which both reactants are moving and continuously maintained under operating conditions. The solid is in the form of metal balls which are conveyed through a reaction chamber on inclined perforate channels. The liquid reactant is sprayed over the moving balls. Waste solid reaction products are removed by the rolling action of the balls on the perforate channels and the washing action of the sprayed liquid reactant. In the production of hydrogen, aluminum metal balls are used and the liquid reactant is a solution of sodium hydroxide. Because the reaction is exothermic, excess heat is removed by cooling the liquid reactant.

Claims

1. A gas generator for continuously producing a gas by the reaction of a solid and a liquid reactant. comprising, in combination:

a supply of balls made from a solid reactant material;

a reaction chamber;

means for conveying said balls from said supply through said reaction chamber and back to said supply;

spray means within said reaction chamber for directing a spray of liquid reactant on to said balls passing therethrough;

means for delivering said liquid reactant from a sump, through said spray means and into contact with said balls and back to said sump; and

means for delivering gas generated by the contact of said liquid reactant and said solid reactant balls from said reaction chamber.

2. The gas generator of claim 1 wherein said means for conveying the balls through the reaction chamber includes an inclined surface within said chamber;

and further including;

means for introducing the balls one at a time to said inclined surface in a manner such that the balls are conveyed up said inclined surface by pushing against one another.

3. The gas generator of claim 2 wherein said inclined surface comprises a plurality of channels in which the balls are conveyed in single rows and the conveying means includes a pawl and rachet wheel means to introduce the balls one at a time to said chamber.

4. The gas generator of claim 3 wherein said channels are made from perforate material so as to facilitate the flow of liquid reactant away from said balls for return to said pump along with solid products of reaction which can be removed from said balls by rolling contact with said perforate channels.

5. The gas generator of claim 4 wherein said channels are made in the form of screen mesh tubing.

6. The gas generator of claim 1 further comprising:

means for removing said balls from said conveying means when the balls become undersized due to the continuing reaction.

7. The gas generator of claim 1 comprising:

control means for maintaining the concentration of said liquid reactant.

8. The gas generator of claim 1 further comprising:

control means for maintaining the temperature of said liquid reactant.

9. The gas generator of claim 1 wherein the the solid reactant balls are made of aluminum.

10. The method of producing a gas by the exothermic reaction of a solid and liquid reactant wherein the solid reactant is in the form of balls, comprising the following steps, in combination:

causing the balls to move in a continuous flow path;

spraying the balls with said liquid reactant over a portion of said flow path;

removing the gas formed by the reaction of said liquid reactant with the solid reactant balls;

controlling the temperature by removing the excess heat generated from the exothermic reaction by heat exchange to said liquid reactant;

removing solid products of reaction formed by said reaction, at least in part, by filtration of said liquid reactant.

11. The method of producing gas according to claim 10 wherin the solid reactant balls are aluminum, the liquid reactant includes sodium hydroxide and the solid products of reaction include sodium aluminate.

12. The method of producing a gas according to claim 10 wherein the rate of gas production is controlled by the rate at which the liquid reactant is sprayed on said balls of solid reactant.