Dual mixed refrigerant natural gas liquefaction

• US 4,545,795 A
• Filed: 10/25/1983
• Issued: 10/08/1985
• Est. Priority Date: 10/25/1983
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Liu, Yu-Nan, Pervier, James W.
• Primary Examiner(s): Sever, Frank
• Application Number:
  US06/545,409
• Time in Patent Office: 714 Days
• Field of Search: 62/9, 62/11, 62/40, 62/335
• US Class Current: 62/613
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0055 originating from an incorporated cascade
• CPC Class Codes: F25J 1/0212 as a single flow MCR cycle
• CPC Class Codes: F25J 1/0267 using flash gas as heat sink
• CPC Class Codes: F25J 1/0268 using a dedicated refrigeration means F25J1/0296 takes precedence
• CPC Class Codes: F25J 1/0292 Refrigerant compression by cold or cryogenic suction of the refrigerant gas
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2220/64 Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
• CPC Class Codes: F25J 2270/12 External refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/18 External refrigeration with incorporated cascade loop

Abstract

A process and apparatus is described for liquefying natural gas using two closed cycle, multicomponent refrigerants wherein a low level refrigerant cools and liquefies the gas by indirect heat exchange and a high level refrigerant cools and partially liquefies the low level refrigerant by indirect multistage heat exchange. The high level refrigerant is phase separated in order to use lighter refrigerant components to perform the final lowest level of refrigeration while the liquid phase of the separation is split and then expanded for refrigeration duty in order to avoid multiple flash separations wherein heavier components are used to provide the lower levels of refrigeration.

Claims

1. A process for the liquefaction of natural gas using two closed cycle, multicomponent refrigerants wherein high level refrigerant cools a low level refrigerant and the low level refrigerant cools and liquefies the natural gas, comprising the steps of:

a. cooling and liquefying a natural gas stream by heat exchange with a low level multicomponent refrigerant in a first closed refrigeration cycle, which refrigerant is rewarmed during said heat exchange,

b. compressing said rewarmed low level refrigerant to an elevated pressure and aftercooling it against an external cooling fluid,

c. further cooling said low level refrigerant by indirect multiple stage heat exchange against a high level multicomponent refrigerant in a second closed refrigeration cycle, which high level refrigerant is rewarmed during said heat exchange,

d. compressing said rewarmed high level refrigerant to an elevated pressure and aftercooling it against an external cooling fluid to partially liquefy said refrigerant,

e. phase separating said high level refrigerant into a vapor phase refrigerant stream and a liquid phase refrigerant stream such that lighter refrigerant components are available for lower level refrigeration duty in the cooling step of clause c,

f. subcooling and expanding portions of the liquid phase refrigerant stream to lower temperature and pressure in multiple stages to provide the cooling of the low level refrigerant of step (c) and to cool and liquefy the vapor phase refrigerant stream of step (e),

g. cooling and then expanding the liquefied vapor phase refrigerant stream to lower temperature and pressure to provide the lowest stage of cooling to the low level refrigerant.

2. The process of claim 1 wherein the vapor phase high level refrigerant stream is initially cooled against the liquid phase high level refrigerant stream and then is phase separated into a light vapor phase stream, which is further cooled and expanded to provide the lowest stage of cooling to the low level refrigerant, and into a light liquid phase stream which is combined with the liquid phase refrigerant stream.

3. The process of claim 2 wherein the vapor phase high level refrigerant stream is cooled, phase separated, and further cooled in a plurality of stages.

4. The process of claim 1 wherein the low level refrigerant is phase separated and the liquid phase provides the initial cooling of the natural gas, while the vapor phase is split into a first stream which is cooled against the liquid phase and a second stream which is cooled against flash gas from the product liquefied natural gas before said first and second streams are combined to provide the final cooling and liquefaction of the natural gas.

5. The process of claim 1 wherein the compression of the low level refrigerant is conducted in multiple stages.

6. The process of claim 1 wherein the compression of the high level refrigerant is conducted in multiple stages.

7. The process of claim 1 wherein the external cooling fluid is water at ambient conditions.

8. The process of claim 7 wherein the water is below 65°

F.

9. The process of claim 1 wherein the multicomponent refrigerants comprise two or more components selected from the following group:

methane, ethane, ethylene, propane, propylene, butane, pentane and nitrogen.

10. An installation for the liquefaction of natural gas using two closed cycle, multicomponent refrigerants wherein high level refrigerant cools a low level refrigerant and the low level refrigerant cools and liquefies the natural gas, comprising:

a. a heat exchanger for cooling and liquefying natural gas against a low level refrigerant;

b. at least one compressor for compressing the low level refrigerant to an elevated pressure;

c. an auxiliary heat exchanger for indirectly cooling the low level refrigerant against high level refrigerant in multiple stages;

d. a phase separator for separating the low level refrigerant into a vapor phase stream and a liquid phase stream;

e. means for conveying the vapor phase stream and the liquid phase stream separately to said heat exchanger of paragraph (a) and recycling same to said compressor of paragraph (b);

f. at least one compressor for compressing high level refrigerant to an elevated pressure;

g. an aftercooling heat exchanger for cooling the compressed high level refrigerant against an external cooling fluid;

h. a phase separator for separating the high level refrigerant into a vapor phase stream and a liquid phase stream such that lighter refrigerant components are available for lower level refrigeration duty in the auxiliary heat exchanger of clause c;

i. means for conveying said high level vapor phase stream through said auxiliary heat exchanger and expanding said stream in order to provide the lowest stage of cooling to the low level refrigerant stream;

j. means for conveying said high level liquid phase stream through said auxiliary heat exchanger including means for separating portions of said stream therefrom and then individually expanding them to a lower temperature and pressure to cool said low level refrigerant;

k. means for recycling the high level refrigerant for recompression.

11. The apparatus of claim 10 including a phase separator for separating the high level vapor phase stream of paragraph (h) into a light vapor phase stream and a light liquid phase stream.

12. The apparatus of claim 11 including a plurality of phase separators for separating high level vapor phase refrigerant into light vapor phase streams and light liquid phase streams.

13. The apparatus of claim 10 wherein the compressors have multiple stages.