Flexible tape having bridges of electrically conductive particles extending across its pressure-sensitive adhesive layer

• US 4,548,862 A
• Filed: 09/04/1984
• Issued: 10/22/1985
• Est. Priority Date: 09/04/1984
• Status: Expired due to Term

• Current Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: Hartman, Richard B.
• Primary Examiner(s): VAN BALEN, WILLIAM
• Application Number:
  US06/646,825
• Time in Patent Office: 413 Days
• Field of Search: 174/88 R, 174/70 C, 174/94 R, 174/117 R, 174/117 A, 428/323, 428/328, 428/329, 428/356, 428/900, 428/906, 428/922, 428/195, 428/198, 428/204, 428/206, 428/208, 427/47, 427/128, 427/208.4
• US Class Current: 428/323
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H01R 4/04 using electrically conductive adhesives
• CPC Class Codes: H05K 2201/083 Magnetic materials
• CPC Class Codes: H05K 2203/104 Using magnetic force, e.g. to align particles or for a temporary connection during processing
• CPC Class Codes: H05K 3/323 by applying an anisotropic conductive adhesive layer over an array of pads
• CPC Class Codes: Y10S 428/90 Magnetic feature
• CPC Class Codes: Y10S 428/906 Roll or coil
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof
• CPC Class Codes: Y10T 428/257 Iron oxide or aluminum oxide
• CPC Class Codes: Y10T 428/2857 including metal or compound thereof or natural rubber

Abstract

Flexible tape having a pressure-sensitive adhesive layer containing particles, each particle having a ferromagnetic core and an electrically conductive surface. By virtue of the ferromagnetic cores, the particles can be magnetically attracted to form a large number of discrete electrically conductive bridges extending through the thickness of the adhesive layer. The tape can be used both to bond together and to electrically connect individual members of facing arrays of electrodes.

Claims

1. Flexible tape that can adhesively make individual electrical connections between multiple pairs of electrodes without short circuiting electrodes of either array, said tape comprising a pressure-sensitive adhesive layer containing electrically conductive particles in an amount providing less than ten percent by volume of the layer, each of the particles having a ferromagnetic core and an electrically conductive surface, the maximum dimension of substantially every particle being less than the thickness of the layer, the particles together forming a large number of discrete, electrically conductive bridges extending through the thickness of the layer, the adhesive between individual bridges rendering the layer laterally nonconductive.

2. Flexible tape as defined in claim 1 wherein said particles comprise from 0.2 to 5 volume percent of said layer.

3. Flexible adhesive tape as defined in claim 1 wherein most of the particles are flakes and are oriented with their faces generally perpendicular to the layer.

4. Flexible tape as defined in claim 1 wherein each particle has an electrically conductive coating over its ferromagnetic core.

5. Flexible tape as defined in claim 4 wherein the ferromagnetic core comprises nickel.

7. Flexible tape as defined in claim 1 wherein the pressure-sensitive adhesive is crosslinked.

8. Flexible tape as defined in claim 7 wherein said layer is supported by a disposable carrier web which has a low-adhesion surface in contact with the adhesive layer.

9. Flexible tape as defined in claim 1 wherein said layer is supported by a flexible, electrically insulative carrier web which carries a plurality of electrically conductive strips in contact with said layer.

10. Flexible tape as defined in claim 9 wherein each electrically conductive strip is a metal foil.

11. Flexible tape as defined in claim 9 wherein each electrically conductive strip is a thin film metal coating.

12. Flexible tape as defined in claim 1 wherein said layer is supported by a flexible, electrically insulative carrier web which carries a coextensive, electrically conductive layer in contact with said adhesive layer.

6. Flexible tape as defined in claim 6 wherein the coating comprises silver.

13. Method of making a flexible multiple-connector tape comprising the sequential steps of:

(1) coating onto a flexible carrier web a mixture of low-viscosity photopolymerizable monomer and particles, each particle having a ferromagnetic core and an electrically conductive surface, the maximum dimension of substantially every particle being less than the ultimate thickness of the coating,

(2) then simultaneously

(a) subjecting the coating to a magnetic field extending substantially orthogonally to the coating and of a strength sufficient to attract the particles to form a large number of discrete bridges, each extending through the thickness of the coating, and

(b) polymerizing the monomer to fix the bridges of particles within a pressure-sensitive layer which is laterally nonconductive, and

(3) removing the tape from the magnetic field.

14. Method as defined in claim 13 wherein the photopolymerizable monomer has been partially polymerized prior to Step (1) to a viscosity between 1000 and 40,000 cps.

15. Method as defined in claim 13 wherein said particles comprise from 0.2 to 5 volume percent of said photopolymerizable mixture.

16. Method as defined in claim 13 wherein the carrier web is moved continuously through Steps (1) and (2), and after Step (3) is Step (4) winding the tape upon itself in roll form.

17. Method as defined in claim 13 wherein the carrier web is a disposable film having a low-adhesion surface to which the coating is applied.

18. Method as defined in claim 13 wherein the carrier web is electrically insulative.

19. Method as defined in claim 18 wherein the face of the carrier web which is coated in Step 1 carries a plurality of electrically conductive strips.

20. Flexible tape that can adhesively bond an assemblage of electronic components to a heat sink to which heat from the assemblage can be carried off, said tape comprising a pressure-sensitive adhesive layer containing thermally conductive, electrically insulative particles in an amount providing less than ten percent by volume of the layer, each of the particles having a ferromagnetic core and an electrically insulative oxide surface, the maximum dimension of substantially every particle being less than the thickness of the layer, the particles together forming thermally conductive bridges extending through the thickness of the layer.