Flexible absorbent boards

• US 4,551,142 A
• Filed: 06/06/1984
• Issued: 11/05/1985
• Est. Priority Date: 10/05/1979
• Status: Expired due to Term

• Current Assignee: McNeil-PPC Incorporated (Johnson & Johnson)
• Original Assignee: Personal Products Co. (Johnson & Johnson)
• Inventors: Kopolow, Steven L.
• Primary Examiner(s): Rosenbaum, C. Fred
• Assistant Examiner(s): Vinyard, Sherri
• Application Number:
  US06/617,786
• Time in Patent Office: 517 Days
• Field of Search: 604/368, 604/374, 604/375, 604/365, 604/379, 604/380
• US Class Current: 604/368
• CPC Class Codes: A61L 15/28 Polysaccharides or their derivatives A61L15/225 takes precedence
• CPC Class Codes: A61L 15/60 Liquid-swellable gel-forming materials, e.g. super-absorbents
• CPC Class Codes: C08L 1/08 Cellulose derivatives
• CPC Class Codes: C08L 1/26 Cellulose ethers
• CPC Class Codes: D21H 11/00 Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
• CPC Class Codes: D21H 13/00 Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material chemical features in the manufacture of artificial fibres D01F
• CPC Class Codes: D21H 5/12 characterised by the use of special fibrous materials felts or other non-woven fabrics D04

Abstract

An absorbent material is provided for body fluid absorbent products which material has relatively high tensile strength, and is extremely flexible and may be incorporated into absorbent products without substantial loss in user'"'"'s comfort. The material is made by forming a slurry of water wherein the solids comprise cellulosic fibers and hydrocolloidal material. The wet web is formed from the slurry and the web is then dried. The dry web is then compacted to a density of at least 110% and preferably at least 150% based on the density of the dry web. The resulting product has a tensile strength of at least 10 Kg/cm² and the Gurley Stiffness of less than about 40 gm.

Claims

1. A product made by the process comprising:

forming a slurry of water is no more than about 0.1% by weight solids, said solids comprising cellulosic fibers and particulate hydrocolloidal material in a ratio of at least 0.01 grams of hydrocolloidal material per gram of cellulose fibers;

forming a wet web from said slurry;

drying said web to a water content of less than 10.0% by weight to form an undensified dry web;

and increasing the density of said dry web by at least 10%;

whereby said densified dry web has a high tensile strength and low stiffness relative to said undensified dry web, said densified web having a tensile of at least 10 kg/cm², a Gurley Stiffness of less than 40 grams, and a thickness of more than 0.3 mm.

2. The board of claim 1 comprising cellulosic fibers and particulate hydrocolloidal material in a ratio of at least 110% of the density of the uncompacted dry board.

3. The board of claim 1 having a Gurley Stiffness of less than 12 gms.

4. The board of claim 1 having a thickness of at least 0.6 mm.

5. The board of claim 1 having been compacted in a dry state to a density of at least 150% of the density of the uncompacted dry board.

6. The board of claim 1 wherein said particulate hydrocolloidal material can absorb 10 times its dry weight of water.

7. The board of claim 6 wherein said particulate hydrocolloidal material can absorb from about 15 to about 30 times its dry weight of water.

8. The board of claim 1 wherein said hydrocolloidal material is a polymer having hydrophilic groups bonded to the backbone hereof.

9. The board of claim 1 wherein said hydrocolloidal material is a polysaccharide having bonded to the polymer backbone hydrophilic moieties selected from the group consisting of carboxyalkyl, phosphonoalkyl, sulphoalkyl, or phosphoryl.

10. The board of claim 9 wherein said hydrocolloidal material is crosslinked.

11. The board of claim 9 wherein said hydrocolloidal material is crosslinked.

12. The board of claim 8 wherein said hydrocolloidal material is a polysaccharide having hydrophilic chains grafted thereto.

13. The board of claim 12 wherein said hydrophilic chains have the formula ##STR2## wherein A and B are selected from the group consisting of --OR³, --O(alkali metal), --OHNH₃, --NH₂, wherein R¹, R² and R³ are selected from the group consisting of hydrogen and alkyl having 1 to 4 carbon atoms, wherein r is an integer having a value of 0 to about 5000, s is an integer having a value of 0 to about 5000, r plus s is at least 500, p is an integer having a value of zero or 1 and q is an integer having a value of 1 to 4.

14. The board of claim 13 wherein said hydrophilic chains are hydrolyzed polyacrylonitrile chains.

15. The board of claim 13 wherein said hydrophilic chains are copolymers of polyacrylamide and sodium polyacrylate.

16. The board of claim 8 wherein said hydrocolloidal material is a synthetic polymer.

17. The board of claim 16 wherein said synthetic polymer is selected from the group consisting of polyacrylonitrile, grafted polyacrylonitrile, polyvinyl alcohol, hydrophilic polyurethane poly(alkyl phosphonates), partially hydrolyzed polyacrylamides, sulfinated polystyrene, or poly(alkylene oxide).