Process for converting ligneous matter of vegetable origin by torrefaction, and product obtained thereby

• US 4,553,978 A
• Filed: 08/23/1982
• Issued: 11/19/1985
• Est. Priority Date: 08/28/1981
• Status: Expired due to Term

• Current Assignee: Association Pour La Recherche et Le Developpement Des Methodes et Processus Industriels Armines
• Original Assignee: Association pour la Recherche et le Développement des méthodes et processus Industriels
• Inventors: Yvan, Schwob
• Primary Examiner(s): Gantz, D. E.
• Assistant Examiner(s): MCFARLANE, ANTHONY R
• Application Number:
  US06/410,636
• Time in Patent Office: 1,184 Days
• Field of Search: 44/1 R, 44/1 E, 44/1 D, 44/93, 44/10 A, 44/10 B, 44/10 D, 44/1 F, 44/77, 201/2.5, 201/6, 201/23, 562/515, 562/607, 208/10, 585/240, 585/16
• US Class Current: 44/280
• CPC Class Codes: C10B 53/02 of cellulose-containing material production of pyroligneous acid C10C5/00
• CPC Class Codes: C10G 1/00 Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal mechanical winning of oil from oil-shales, oil-sand, or the like B03B
• CPC Class Codes: C10L 5/44 on vegetable substances
• CPC Class Codes: C10L 9/083 Torrefaction
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The present invention relates to a process for converting ligneous matter of vegetable origin by torrefaction, and to the product obtained. Wood or any other ligneous matter is subjected in a neutral atmosphere to a treatment of torrefaction at a temperature of between 200° and 280° C., and preferably between 240° and 260° C. for a duration of 30 mins. to 5 hours. The product of the invention is not fermentable, it has a specific mass close to 0.25 kg/dm³, a calorific power of at least about 5000 kcal/kg, a content of fixed carbon of 35 to 40% and can be broken up by hand; it may be used as fuel in boilers and in gas generators.

Claims

1. A process for converting ligneous matter to a torrefied wood product comprising:

(1) slowing and progressively heating a feed consisting essentially of fragmented ligneous matter in a medium which under the heating conditions is substantially inert to the ligneous matter, and wherein the heating conditions are such that all of the ligneous matter being heated reaches a temperature of at least 200°

C. but none of the ligneous matter reaches a temperature which exceeds 280°

C.

(2) maintaining the said heating step for a period of 0.5 to 5 hours;

(3) removing pyroligneous gaseous products from the medium during the heating period;

(4) cooling the heated product; and

(5) recovering the resulting torrefied wood product.

2. The process of claim 1, wherein the ligneous matter is agglomerated before being subjected to the heating operation.

3. The process of claim 1, wherein the matter is heated in a liquid bath.

4. The process of any one of claims 2 and 3, wherein after the operation of conversion by heating, suspending the torrefied wood product in a solvent selected from the group consisting of fuel, alcohol and oxo-process product, and then hydrogenating said product by scavenging the torrefied wood product/solvent mixture with hydrogen at a temperature of about 250°

C. to render the product totally soluble in the solvent and thus obtain a liquid fuel.

5. The process of claim 1 where said heating step occurs only below 260°

C.

6. The process of claim 1 where said medium is gaseous.

7. The process of claim 1 where said medium is nitrogen.

8. The process of claim 1 where the hygroscopicity of said torrefied wood product is less than about 3%.

9. The process of claim 8 where said torrefied wood product has a caloric value of at least 5000 k cal/kg and a fixed carbon content of between 35 and 40%.

10. The process of claim 9 where said product is not fermentable.

11. The process of claim 1, wherein said temperature is between 230°

C. and 260°

C.

12. The process of claim 4, wherein said solvent is fuel or alcohol.

13. Torrefied ligneous matter of vegetable origin having a fixed carbon content of between 35 and 40%, a caloric value of at least 5000 kcal/kg A hydroscopicity of less than 3% and not being fermentable.

14. A liquid fuel obtained by suspending the matter of claim 13 in a solvent selected from the group consisting of fuel, alcohol and oxo-process product, and then scavenging the matter/solvent mixture with hydrogen at a temperature of about 250°

C. to render the matter totally soluble in the solvent.

15. The liquid fuel of claim 14, wherein said solvent is fuel or alcohol.