Process and device for the production of gaseous oxygen at elevated pressure

• US 4,555,256 A
• Filed: 05/02/1983
• Issued: 11/26/1985
• Est. Priority Date: 05/03/1982
• Status: Expired due to Fees

• Current Assignee: Linde AG (Linde Plc)
• Original Assignee: Linde AG (Linde Plc)
• Inventors: Skolaude, Werner, Eggendorfer, Gunnar
• Primary Examiner(s): Sever, Frank
• Application Number:
  US06/490,359
• Time in Patent Office: 939 Days
• Field of Search: 62/9, 62/11, 62/23, 62/24, 62/25, 62/27, 62/28, 62/29, 62/31, 62/34, 62/38, 62/39, 62/43, 62/18
• US Class Current: 62/646
• CPC Class Codes: F25J 2205/32 as direct contact cooling tower to produce a cooled gas stream, e.g. direct contact after cooler [DCAC]
• CPC Class Codes: F25J 2240/10 the fluid being air
• CPC Class Codes: F25J 2245/02 Recycle of a stream in general, e.g. a by-pass stream
• CPC Class Codes: F25J 2245/40 the recycled stream being air
• CPC Class Codes: F25J 3/0409 of oxygen
• CPC Class Codes: F25J 3/04157 Afterstage cooling and so-called "pre-cooling" of the feed air upstream the air purification unit and main heat exchange line F25J3/04618 takes precedence
• CPC Class Codes: F25J 3/04218 Parallel arrangement of the main heat exchange line in cores having different functions, e.g. in low pressure and high pressure cores F25J3/04503 takes precedence
• CPC Class Codes: F25J 3/04224 Cores associated with a liquefaction or refrigeration cycle
• CPC Class Codes: F25J 3/04296 Claude expansion, i.e. expanded into the main or high pressure column
• CPC Class Codes: F25J 3/04303 Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
• CPC Class Codes: F25J 3/04345 and comprising a gas work expansion loop
• CPC Class Codes: F25J 3/04357 and comprising a gas work expansion loop
• CPC Class Codes: F25J 3/04387 using liquid or hydraulic turbine expansion
• CPC Class Codes: F25J 3/04393 using multiple or multistage gas work expansion
• CPC Class Codes: F25J 3/04412 in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
• CPC Class Codes: Y10S 62/94 High pressure column

Abstract

In the production of gaseous oxygen, a process and apparatus is used which requires low temperature rectification of air. The air is compressed, purified and cooled in a first heat exchanger while a second gas stream is compressed to elevated pressure, and is cooled in a second heat exchanger. Liquid oxygen removed from rectification is pressurized to a desired pressure and is evaporated and heated in heat exchange with the compressed gas stream.

Claims

1. Process for the production of gaseous O at an elevated pressure by low temperature rectification of air, comprising reducing energy requirements for production of oxygen by compressing, purifying and at least in part cooling the air in a first heat exchange in heat exchange with rectification product, passing the air to the rectification, compressing a second gas stream to a higher pressure, cooling the second gas stream, after compressing, in a second heat exchanger in heat exchange with rectification product, withdrawing heat at an intermediate point along the second heat exchanger, whereby temperature differences at a cold end of the second heat exchanger are reduced, adding the withdrawn heat to the first heat exchanger, whereby less air is required for heating at a cold end of the first heat exchanger, expanding the second gas stream, after cooling, and passing the second gas stream, after expanding to the rectification, and cooling a third gas stream to be fractionated in heat exchange with fractionation product, liquid oxygen being withdrawn from the rectification, and being pumped to the desired pressure, and, in heat exchange with the compressed gas stream, being evaporated and heated, whereby energy requirements for the production of oxygen is reduced.

2. Process according to claim 1, characterized in that the third gas stream is further compressed before cooling.

3. Process according to claim 1, characterized in that the third gas stream after expansion is passed either to the rectification or into nitrogen, drawn off from the rectification.

4. Process according to claim 1, characterized in that the third gas stream is removed from first heat exchanger, essentially at the point where heat is added.

5. Process according to claim 1, characterized in that the second partial stream is engine expanded.

6. Process according to claim 1, characterized in that for heat transfer purposes, a portion of the second compressed gas stream, before cooling is complete, is cooled in heat exchange with a portion of gas stream from the rectification, which is to be heated in the first heat exchanger.

7. Process according to claim 1, characterized in that the compression of the second gas stream occurs in two steps, whereby between the two steps a partial stream branches off, is cooled in a second heat exchanger and before heat exchange is completed, is engine expanded and passed into the rectification.

8. Process according to claim 1, characterized in that a portion of second gas stream, compressed to its final pressure, branches off before completion of the heat exchange, is engine expanded and passed into the rectification.

9. Process according to claim 1, characterized in that nitrogen from the rectification, is passed through the first and the second heat exchanger, in part, respectively, and a portion of the nitrogen is transferred from an intermediate point of the second heat exchanger to the nitrogen at an intermediate point of first heat exchanger.

10. Process according to claim 1, characterized in that the second gas stream is a partial stream of the air to be fractionated or a gas stream from the high pressure stage.

11. Process according to claim 1, characterized in that the power gained in the expansion of the second and/or third gas stream is used for its compression.

12. Process according to claim 1, characterized in that a portion of the second gas stream is used as the third partial stream, whereby the second gas stream is split into first and second partial streams, which are cooled in the second heat exchanger, separate from each other, at different pressures, and in that a partial stream having the lower pressure, is removed from the second heat exchanger at a higher temperature than the higher compressed second partial stream, thereupon is engine expanded and, at least in part, is passed to the rectification.

13. Process according to claim 12, characterized in that the second partial stream, being at elevated pressure, is engine expanded after cooling.

14. Process according to claim 12, characterized in that the first partial stream, being at lower pressure, after exiting from the first compression stage, is after-compressed before cooling.

15. Process according to claim 12, characterized in that the pressure of the first partial stream, having the lower pressure, ranges between 10 and 60 bar.

16. Process according to claim 12, characterized in that the first partial stream, having the lower pressure, is withdrawn from the second heat exchanger in the area of the smallest temperature differential between the second partial stream, having the higher pressure, and oxygen.

17. Process according to claim 12, characterized in that the output realized in the expansion of one or both partial streams is utilized for the after-compression of one or both partial streams.

18. Process according to claim 12, characterized in that heat is transferred from an intermediate point of one heat exchanger to an intermediate point of the other heat exchanger.

19. Process according to claim 12, characterized in that a portion of the compressed, purified air is branched off at an intermediate point of the first heat exchanger, is engine expanded and passed into the rectification.

20. Process according to claim 19, characterized in that the branched off portion of air is after-compressed before cooling.

21. Process according to claim 12, characterized in that the second gas stream is a partial stream of the incoming air.

22. Process according to claim 12, characterized in that the second gas stream is withdrawn from pressure stage and is heated and compressed before the splitting.

23. Process according to claim 22, characterized in that before compression of the second gas stream, a portion is branched off and is after-compressed, cooled in one of the heat exchangers, is withdrawn therefrom at an intermediate point, is engine expanded and passed into the rectification.

24. Process according to claim 1, characterized in that as said third gas stream a portion of the compressed purified air is cooled in the first heat exchanger, then is removed at least in part, at an intermediate point therefrom, and is engine expanded.