Reinforced consumable electrode, electrochemical cell and method

• US 4,555,454 A
• Filed: 04/17/1985
• Issued: 11/26/1985
• Est. Priority Date: 04/17/1985
• Status: Expired due to Fees

• Current Assignee: Westinghouse Electric Corporation (Paramount Global (f/k/a ViacomCBS Inc.))
• Original Assignee: Gould, Inc. (Transdigm Group Incorporated)
• Inventors: Shuster, Nicholas
• Primary Examiner(s): Walton, Donald L.
• Application Number:
  US06/724,322
• Time in Patent Office: 223 Days
• Field of Search: 429/67, 429/212, 429/217, 429/118, 429/119, 429/81, 429/234, 429/235, 429/50
• US Class Current: 429/51
• CPC Class Codes: H01M 4/12 of consumable metal or alloy electrodes use of alloy compositions as active materials H01M4/38
• CPC Class Codes: H01M 50/40 Separators; Membranes; Diaphragms; Spacing elements inside cells
• CPC Class Codes: H01M 50/70 Arrangements for stirring or circulating the electrolyte
• CPC Class Codes: H01M 6/04 Cells with aqueous electrolyte

Abstract

A consumable metal electrode incorporates a fibrous reinforcing network of electrically insulating material extending through at least a portion of the body of the electrode and disposed in close proximity to a surface of the electrode which will be contacted by liquid electrolyte and eroded during operation of an electrochemical cell incorporating the electrode. Local turbulence is generated by the fibrous network at the electrode surface during operation of the cell in order to maximize electrical output.

Claims

1. An electrode suitable for use in an electrochemical cell, comprising:

(a) a solid body of a reactive metal which is consumable by reaction with a liquid electrolyte, said body defining at least one surface to be contacted by said electrolyte during operation;

(b) a fibrous network of electrically insulating reinforcing material at least partially embedded in said body with at least a portion of said network disposed in said body in close proximity to said surface for contact with said electrolyte as metal at said surface is consumed by reaction with said electrolyte.

2. The electrode of claim 1 wherein said network extends from said body through said surface.

3. The electrode of claim 1 wherein said network is entirely contained within said body.

4. The electrode of claim 1 wherein said network comprises a plurality of discrete fibers.

5. The electrode of claim 4 wherein said fibers are of a material selected from the group consisting of ceramic materials and synthetic polymers.

6. The electrode of claim 5 wherein said synthetic polymer is an aromatic polyamide.

7. The electrode of claim 4 wherein said fibers are dispersed in said body as bundles of fibers.

8. The electrode of claim 1 wherein said fibrous network comprises reticulated foam.

9. The electrode of claim 8 wherein said foam is of a resilient compressible material.

10. The electrode of claim 9 wherein said compressible material is a synthetic polymer.

11. The electrode of claim 10 wherein said synthetic polymer is polyurethane.

12. The electrode of claim 8 wherein said foam is rigid.

13. The electrode of claim 12 wherein said foam comprises a rigid three-dimensional screen.

14. The electrode of claim 13 wherein said screen is of a material selected from the group consisting of rigid synthetic polymers and metal.

15. The electrode of claim 14 wherein said screen is of rigid polypropylene.

16. The electrode of claim 14 wherein said screen comprises metal coated with an electrically insulated material.

17. An electrochemical cell comprising an anode, a cathode spaced from said anode to define a reaction space, and means externally connecting said anode and said cathode to define an electrical circuit, said anode comprising the electrode of claim 1.

18. The cell of claim 17 wherein the reactive metal of said anode comprises an alkali metal.

19. The cell of claim 18 wherein said alkali metal comprises lithium.

20. The cell of claim 17 wherein the fibrous network of said anode comprises reticulated foam of a resilient compressible material extending from the body of said anode through said anode surface into said reaction space.

21. The cell of claim 17 wherein said anode and said cathode are separated by a means selected from the group consisting of a rigid screen and reticulated compressible foam.

22. A method of generating electrical energy comprising the step of introducing an electrolyte into the reaction space defined between the anode and cathode of the electrochemical cell of claim 17.