Combination fluid bed dry distillation and coking process for oil/tar sands

• US 4,561,966 A
• Filed: 09/28/1984
• Issued: 12/31/1985
• Est. Priority Date: 09/28/1984
• Status: Expired due to Fees

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Owen, Hartley, Zahner, John C., Haddad, James H.
• Primary Examiner(s): Gantz, D. E.
• Assistant Examiner(s): Caldarola, Glenn A.
• Application Number:
  US06/655,272
• Time in Patent Office: 459 Days
• Field of Search: 208/11 R, 208/127, 201/31, 201/22, 201/44
• US Class Current: 208/410
• CPC Class Codes: C10G 1/006 Combinations of processes provided in groups C10G1/02 - C10G1/08
• CPC Class Codes: C10G 1/02 by distillation

Abstract

A process and apparatus for direct coking of tar sands which includes contacting the tar sand with heat transfer particles resulting from combustion of coked sand effluent from the coking process, and transporting the combination up a riser/mixer to a coking vessel whereby separation of oil and hydrocarbon gases from the sand is initiated. The tar sand is introduced into a fluid coking vessel which has at least two coking zones. The first coking zone is substantially at the top of the vessel whereas the second coking zone is immediately below the first coking zone and includes a stream of hot spent sand so that a more severe coking temperature is present in the second coking zone. A product stream of oil and light hydrocarbon gases, recovered from the riser/mixer and coking process, is directed to a separator located above said coking vessel in which the heavy oil is removed and preferably directed to the second coking zone.

Claims

1. A process for direct coking tar sands comprising:

contacting tar sand with heat transfer particles heated to a temperature of about 1200°

F. obtained as defined below in a ratio of tar sand to heat transfer particles of from about 1 to 1 to about 1 to 5, in a contact zone at the lower end of a riser/mixer,

injecting a lift gas containing less than a sufficient amount of molecular oxygen to support combustion into said contact zone to fluidize, mix, and transport said tar sand and said heat transfer particles upwardly through said riser/mixer into an overhead fluid coking vessel positioned substantially vertically above said riser/mixer,

introducing the effluent from said riser/mixer into a first coking zone of said fluid coking vessel located substantially above and at the top of said riser/mixer, said first coking zone maintained at a temperature of from about 825°

F. to about 950°

F.,

moving said effluent downwardly in said overhead coking vessel into at least a second coking zone located below said first coking zone,

feeding at least one stream of heat transfer particles obtained as defined below into at least said second coking zone to maintain the temperature of said second zone at from about 50°

F. to about 100°

F. higher than the preceding coking zone,

recovering a stream of oil and light hydrocarbon gases liberated from said tar sand in said riser/mixer and said fluid coking vessel,

withdrawing stripped coked sands and heat transfer particle burden from said fluid coking vessel,

conveying said burden to a combustor, and

combusting said stripped coked sand to produce said heat transfer particles used to contact said tar sand and to maintain said elevated temperature in said at least second coking zone.

2. The process of claim 1, wherein a stream of stripping gas is introduced into said fluid coking vessel.

3. The process of claim 1, wherein said stream of recovered oil and light hydrocarbon gases is directed to a scrubbing and fractionating tower positioned substantially vertically above said fluid coking vessel wherein heavy oil is separated from said stream.

4. The process of claim 3, wherein said heavy oil is fed into said second coking zone whereby said heavy oil is further coked at the elevated temperature present in said second coking zone.

5. The process of claim 1, wherein said lift gas is selected from the group consisting of steam air, light ends off-gas recovered from said product stream and combinations thereof.

6. The process of claim 1, wherein a portion of said heat transfer particles resulting from said combustion is recycled directly to said combustor with said withdrawn stripped coked sand/heat transfer particle burden thereby raising the temperature of said coked sand for combustion.

7. The process of claim 1, wherein said heat transfer particles further comprises catalyst particulate.

8. The process of claim 1, wherein said effluent and said heat transfer particles are contacted in additional coking zones.

9. The process of claim 1, wherein there are more than one stream of heat transfer particles fed into said at least second coking zone.

10. The process of claim 1, wherein heat is recovered from hot effluent streams selected from the group consisting of net make resulting from said combustor, hot flue gases generated by said conbustor, and said stream liberated from said tar sand in said riser/mixer and said fluid coking vessel.

11. The process of claim 7, wherein said catalyst particulate is selected from the group consisting of spent FCC catalyst and discarded FCC catalyst.