Seal for reactive metal anode

• US 4,564,570 A
• Filed: 10/15/1984
• Issued: 01/14/1986
• Est. Priority Date: 10/15/1984
• Status: Expired due to Fees

• Current Assignee: Westinghouse Electric Corporation (Paramount Global (f/k/a ViacomCBS Inc.))
• Original Assignee: Gould, Inc. (Transdigm Group Incorporated)
• Inventors: Gordon, Arnold Z.
• Primary Examiner(s): Walton, Donald L.
• Application Number:
  US06/661,061
• Time in Patent Office: 456 Days
• Field of Search: 429/213, 429/66, 429/27, 429/28, 429/19, 429/212, 429/68, 429/234
• US Class Current: 429/212
• CPC Class Codes: H01M 12/02 Details of electrodes H01M4/00; of non-active parts H01M50/00
• CPC Class Codes: H01M 2300/0025 Organic electrolyte
• CPC Class Codes: H01M 4/12 of consumable metal or alloy electrodes use of alloy compositions as active materials H01M4/38
• CPC Class Codes: H01M 50/191 Inorganic material
• CPC Class Codes: H01M 50/193 Organic material
• CPC Class Codes: H01M 50/46 Separators, membranes or diaphragms characterised by their combination with electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An edge seal for a lithium or other consumable metal anode comprises a hydrophobic, chemically inert polymer coating having a high ratio of flexural modulus to flexural strength, a low Izod impact value, and low elongation properties.

Claims

1. A seal for a reactive metal anode of an electrochemical cell comprising said anode, a cathode, and an electrolyte in which said anode and said cathode are in contact during operation of said cell, said anode defining a first surface which contacts said electrolyte and at least one additional surface at the perimeter of at least a portion of said first surface, said seal comprising a coating on said additional surface of a hydrophobic polymer which is substantially chemically inert with respect to said reactive metal and said electrolyte and wherein:

(a) the ratio of the flexural modulus to the flexural strength of said polymer is at least about 25;

(b) the Izod impact value of said polymer is less than or equal to about 2.0 ft.-lb./in.; and

,

(c) the percent elongation of said polymer is less than or equal to about 20%.

2. The seal of claim 1 wherein said polymer is selected from the group consisting of paraffins, polyolefins, polyacrylates, polystyrenes and polyethers.

3. The seal of claim 1 wherein said polymer contains a filler.

4. The seal of claim 3 wherein said filler is selected from the group consisting of pyrolized polyacrylonitrile fiber, glass, glass fiber, pyrolized pitch fiber, graphite fiber, aluminum flakes and mineral filler.

5. The seal of claim 1 wherein the physical characteristics of said polymer further satisfy the equation:

##EQU2##

6. The seal of claim 1 wherein said polymer is polymethylmethacrylate.

7. The seal of claim 1 wherein said polymer is polystyrene.

8. The seal of claim 1 wherein said reactive metal is an alkali metal.

9. The seal of claim 8 wherein said alkali metal is lithium.

10. The seal of claim 9 wherein said polymer is polymethylmethacrylate.

11. The seal of claim 9 wherein said polymer is polystyrene.

12. An electrochemical cell comprising a reactive metal anode, a cathode, and an electrolyte in which said anode and said cathode are in contact during operation of said cell, said anode defining a first surface which contacts said electrolyte and at least one additional surface at the perimeter of at least a portion of said first surface, and a seal on said additional surface comprising a coating of a hydrophobic polymer which is substantially chemically inert with respect to said reactive metal and said electrolyte and wherein:

(a) the ratio of the flexural modulus to the flexural strength of said polymer is at least about 25;

(b) the Izod impact value of said polymer is less than or equal to about 2.0 ft.-lb./in.; and

,

(c) the percent elongation of said polymer is less than or equal to about 20%.

13. The cell of claim 12 wherein said polymer is selected from the group consisting of paraffins, polyolefins, polyacrylates, polystyrenes and polyethers.

14. The cell of claim 12 wherein said polymer contains a filler.

15. The cell of claim 14 wherein said filler is selected from the group consisting of pyrolized polyacrylonitrile fiber, glass, glass fiber, pryolized pitch fiber, graphite fiber, aluminum flakes and mineral filler.

16. The cell of claim 12 wherein the physical characteristics of said polymer further satisfy the equation:

##EQU3##

17. The cell of claim 12 wherein said polymer is polymethylmethacrylate.

18. The cell of claim 12 wherein said polymer is polystyrene.

19. The cell of claim 12 wherein said reactive metal is an alkali metal.

20. The cell of claim 19 wherein said alkali metal is lithium.

21. The cell of claim 20 wherein said polymer is polymethylmethacrylate.

22. The cell of claim 20 wherein said polymer is polystyrene.