Preliminarily foamed particles of non-crosslinked polypropylene-type resin

• US 4,567,208 A
• Filed: 12/05/1984
• Issued: 01/28/1986
• Est. Priority Date: 12/07/1983
• Status: Expired due to Term

• Current Assignee: Japan Styrene Paper Corporation
• Original Assignee: Japan Styrene Paper Corporation
• Inventors: Kuwabara, Hideki, Sudo, Yoshimi
• Primary Examiner(s): Ivy, C. Warren
• Application Number:
  US06/678,679
• Time in Patent Office: 419 Days
• Field of Search: 521/59, 521/58, 521/134
• US Class Current: 521/59
• CPC Class Codes: C08J 2323/16 Ethene-propene or ethene-propene-diene copolymers
• CPC Class Codes: C08J 9/18 by impregnating polymer particles with the blowing agent
• CPC Class Codes: C08J 9/228 Forming foamed products
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 2207/02 Heterophasic composition
• CPC Class Codes: C08L 23/14 Copolymers of propene C08L23/16 takes precedence
• CPC Class Codes: Y10S 264/16 Molding foamed polypropylen articles

Abstract

Preliminarily foamed particles of a non-crosslinked polypropylene-type resin based on a mixture of 10 to 95% by weight of an alpha-olefin/propylene random copolymer having an amount of the heat of crystallization of not more than 10 cal/g in differential scanning calorimetry and 90 to 5% by weight of an ethylene/propylene random copolymer as a base resin, said preliminarily foamed particles having such a crystal structure that when a DSC curve is drawn by heating 1 to 3 mg of the preliminarily foamed particles to 220° C. at a rate of 10° C./min. by means of a differential scanning calorimeter, a high temperature peak is observed at a higher temperature than the temperature of the peak inherent to the base resin. These preliminarily foamed articles can be molded under lower vapor pressures than in the prior art.

Claims

1. Preliminarily foamed particles of a non-crosslinked polypropylene copolymer resin comprising, as a base resin, a mixture of 10 to 95% by weight of an alpha-olefin/propylene random copolymer wherein the alpha-olefin has at least 4 carbom atoms and having an amount of the heat of crystallization of not more than 10 cal/g, as measured by differential scanning calorimetry, and 90 to 5% by weight of an ethylene/propylene random copolymer having an ethylene content of from 3 to 15 mole%, said preliminarily foamed particles having been foamed under conditions such that the maximum temperature of the particles during foaming is in the range of from Tm-25°

C. to Tm-5°

C., wherein Tm is the temperature at which the melting of the resin particle ends, and wherein the crystal structure of the preliminarily foamed particles is such that when a differential scanning calorimetry thermogram is drawn by heating 1 to 3 mg of the preliminarily foamed particles to 220°

C. at a rate of 10°

C./min. by means of a differential scanning calorimeter, a high temperature peak is observed at a higher temperature than the temperature of the peak inherent to the base resin.

2. The preliminarily foamed particles of claim 1 wherein the difference between the temperature of the inherent peak and the temperature of the high temperature peak is at least 5°

C.

3. The preliminarily foamed particles of claim 1 wherein the alpha-olefin of the alpha-olefin/propylene random copolymer is 1-butene, 1-pentene, or 1-hexene.

4. The preliminarily foamed particles of claim 1 wherein the alpha-olefin of the alpha-olefin/propylene random copolymer is 1-butene.

5. The preliminarily foamed particles of claim 4 wherein the 1-butene content of the alpha-olefin/propylene random copolymer is at least 20 mole%.

6. The preliminarily foamed particles of claim 1 wherein the propylene content of the alpha-olefin/propylene random copolymer is at most 80 mole%.