Process and apparatus for preparing or reacting alkanolamines

• US 4,567,303 A
• Filed: 08/06/1984
• Issued: 01/28/1986
• Est. Priority Date: 03/15/1980
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Hammer, Hans, Mueller, Herbert, Jeschek, Gerhard, Scharf, Emil, Schoenleben, Willibald, Hertel, Otto, Boettger, Guenter
• Primary Examiner(s): Shaver, Paul F.
• Application Number:
  US06/638,522
• Time in Patent Office: 540 Days
• Field of Search: 564/475, 564/478
• US Class Current: 564/475
• CPC Class Codes: C07D 295/088 to an acyclic saturated chain

Abstract

In preparing or reacting alkanolamines, especially at high temperatures, the use of substantially nickel-free alloy steels prevents corrosion and discoloration.

Claims

1. A process for preparing colorless alkanolamines and/or alkylenediamines which comprises thermally reacting ammonia or a reactive amine and an alkylene oxide or alkanolamine in a reactor in which the corrosion-sensitive parts of the reactor are made of substantially nickel-free stainless steel.

2. The process of claim 1, wherein a corrosion-resistant ferritic steel containing less than 0.5% of nickel and/or less than 0.025% carbon is used.

3. The process of claim 1, wherein a substantially nickel-free material is used at specific points, especially at points which normally suffer corrosion.

4. The process of claim 1, wherein the alkylene oxide used is ethylene oxide or propylene oxide.

5. A process for separating by distillation the reaction products of a reaction mixture containing ammonia or a reactive amine and an alkylene oxide or alkanolamine which comprises heating the mixture in an apparatus in which the corrosion-sensitive parts are made of substantially nickel-free stainless steel.

6. The process of claim 5 wherein the corrosion-sensitive parts are made of a corrosion-resistant ferritic steel containing less than 0.5% of nickel and/or less than 0.025% carbon.

7. The process of claim 5 wherein the corrosion-sensitive parts are made of a substantially nickel-free material.