Electro-optical switching and memory display device

• US 4,571,029 A
• Filed: 12/29/1983
• Issued: 02/18/1986
• Est. Priority Date: 12/29/1983
• Status: Expired due to Fees

• Current Assignee: Associated Universities, Inc.
• Original Assignee: United States Department of Energy
• Inventors: Skotheim, Terje A., Linkous, Clovis A., O'Grady, William E.
• Primary Examiner(s): Morgenstern, Norman
• Application Number:
  US06/566,757
• Time in Patent Office: 782 Days
• Field of Search: 350/357
• US Class Current: 359/266
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor

Abstract

An electro-optical display device having a housing with wall means including one transparent wall and at least one other wall. Counter electrodes are positioned on the transparent wall and display electrodes are positioned on the other wall with both electrodes in electrically conductive relationship with an electrolyte. Circuit means are connected to the display and counter electrodes to apply different predetermined control potentials between them. The display electrodes are covered with a thin electrically conductive polymer film that is characterized according to the invention by having embedded in it pigment molecules as counter ions. The display device is operable to be switched to a plurality of different visual color states at an exceptionally rapid switching rate while each of the color states is characterized by possessing good color intensity and definition.

Claims

1. An electro-optical display device comprising;

wall means defining a housing, said wall means including a transparent wall and at least one other wall,

display electrode means positioned on the inner side of said other wall,

counter electrode means positioned on the inner side of said transparent wall,

a thin electrically conductive polymer film incorporating pigment molecules embedded therein as counter ions, said film being disposed over the display electrode means,

an electrolyte disposed within said housing and in conductive relationship with said counter electrode means and said film over the display electrode means,

said display electrode means and said counter electrode means being adapted to have electric circuit means connected to them for selectively varying the electric potential applied by them across the electrolyte and the polymer film,

said device being operable to electronically and rapidly change said pigment molecules embedded in the polymer film, responsive to predetermined variations in the electric potential applied across said film, thereby to selectively quickly change the color of said film as it is seen through said transparent wall.

2. An invention as defined in claim 1, wherein said polymer film has a generally uniform thickness over said display electrode means in the range of 0.01 to 1.0 micron.

3. An invention as defined in claim 2, wherein the generally uniform thickness of said film is in the range of 0.05 to 0.1 micron, and whereby the time required for the film to change color responsive to the occurrence of said predetermined variation in applied potential is less than 20 milliseconds.

4. An invention as described in claim 1, wherein said display electrode means comprises a plurality of discrete display electrodes, and said thin polymer film comprises a plurality of discrete sections each disposed respectively over one of said discrete display electrodes, said discrete sections of film being spaced from one another to prevent visual blurring between them.

5. An invention as defined in claim 1, wherein said display electrode means comprises a layer of electrically conductive material, and wherein said electrically conductive polymer film forms a continuous layer of film over said display electrode, said continuous layer of film having a generally uniform thickness in the range of 0.01 and 1.0 micron.

6. An invention as defined in claim 1, wherein said polymer film is polypyrrole, and wherein said embedded pigment molecules are tetrasulfonated cobalt phthalocyanine, whereby the film is changed to a blue color responsive to said applied potential being made more positive than 0.0 volts relative to the electrolyte, and the film is changed to a pale yellow or yellowish green color responsive to said applied potential being made more negative than -0.3 volts relative to said electrolyte.

7. An invention as defined in claim 1, wherein said polymer film is selected from the group consisting of polypyrrole, poly(N-phenyl pyrrole), poly(N-methyl pyrrole) polyaniline, polythiophene, polybithiophene, polyfuran and polyazulene.

8. An invention as defined in claim 7, wherein said embedded pigment molecules are essentially all of one metal phthalocyanine (PC) selected from the group consisting of:

monosulfonated cobalt PC, tetrasulfonated cobalt PC, copper PC, and iron PC.

9. An invention as defined in claim 7, wherein said embedded pigment molecules are essentially all of one rare earth diphthalocyanine (diPC), selected from the group consisting of scandium diPC and lutetium diPC.

10. An invention as defined in claim 7, wherein about half of said embedded pigment molecules are of a first, and about half of said molecules are of a second metal phthalocyanine (PC), both halves being selected from the group consisting of monosulfonated cobalt PC, tetrasulfonated cobalt PC, copper PC and iron PC, whereby the color of said polymer film is changed to a plurality of different colors respectively, responsive to said applied potential being changed to different predetermined voltages relative to the voltage of said electrolyte.

11. An invention as defined in claim 7, wherein a first portion of said pigment molecules are tetrasulfonated cobalt phthalocyanine, and a second portion of said pigment molecules are copper PC, whereby the polymer film has a pale yellow or yellowish green color responsive to said applied potential being made more negative than -0.3 volts;

the film color is changed to a blue color responsive to said potential being made more positive than 0.0 volts; and

the film color is further changed to a purple color responsive to said potential being made more positive than 0.8 volts, all of said voltages being relative to the potential of said electrolyte.

12. An invention as defined in claim 7, wherein said embedded pigment molecules comprise a plurality of either metal phthalocyanines (PC) or rare earth diphthalocyanines (diPC) taken, respectively from the groups consisting of CoPC, CuPC, FePC, scandium diPC and lutetium diPC, whereby said polymer film is changed to a plurality of different colors corresponding to the potentials at which the different counter ions are electronically changed responsive respectively to said applied potential being varied to a plurality of predetermined different voltages relative to the base voltage of said display electrode means.