Composite materials for thermal energy storage

• US 4,572,864 A
• Filed: 01/04/1985
• Issued: 02/25/1986
• Est. Priority Date: 01/04/1985
• Status: Expired due to Term

• Current Assignee: United States Department of Energy (Government of the United States of America)
• Original Assignee: United States Department of Energy (Government of the United States of America)
• Inventors: Benson, David K., Shinton, Yvonne D., Burrows, Richard W.
• Primary Examiner(s): Van Balen, William J.
• Application Number:
  US06/688,668
• Time in Patent Office: 417 Days
• Field of Search: 252/70, 252/73, 428/305.5, 428/306.6, 428/307.3, 428/307.7, 428/308.4, 428/320.2, 428/321.1, 428/403, 428/404, 428/703, 428/913, 427/230, 427/238, 427/430.1
• US Class Current: 428/305.5
• CPC Class Codes: C09K 5/00 Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
• CPC Class Codes: F28D 20/023 the latent heat storage material being enclosed in granular particles or dispersed in a porous, fibrous or cellular structure
• CPC Class Codes: Y02E 60/14 Thermal energy storage
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/24149 Honeycomb-like
• CPC Class Codes: Y10T 428/249954 With chemically effective material or specified gas other than air, N, or carbon dioxide in void-containing component
• CPC Class Codes: Y10T 428/249994 Composite having a component wherein a constituent is liquid or is contained within preformed walls [e.g., impregnant-filled, previously void containing component, etc.]
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2993 Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]

Abstract

The present invention discloses composite material for thermal energy storage based upon polyhydric alcohols, such as pentaerythritol, trimethylol ethane (also known as pentaglycerine), neopentyl glycol and related compounds including trimethylol propane, monoaminopentaerythritol, diamino-pentaerythritol and tris(hydroxymethyl)acetic acid, separately or in combinations, which provide reversible heat storage through crystalline phase transformations. These phase change materials do not become liquid during use and are in contact with at least one material selected from the group consisting of metals, carbon siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof. Particulate additions, such as aluminum or graphite powders, as well as metal and carbon fibers can also be incorporated therein. Particulate and/or fibrous additions can be introduced into molten phase change materials which can then be cast into various shapes. After the phase change materials have solidified, the additions will remain dispersed throughout the matrix of the cast solid. The polyol is in contact with at least one material selected from the group consisting of metals, carbon siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, and mixtures thereof.

Claims

1. A composite material for thermal energy storage comprising a solid state phase change material selected from the group consisting of pentaerythritol, pentaglycerine, neopentyl glycol, tetramethylol propane, monoaminopentaerythritol, diaminopentaerythritol, tris(hydroxymethyl)acetic acid, and mixtures thereof;

said solid state phase change material contacting materials selected from the group consisting of metals, carbon siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof.

2. The composite material of claim 1, wherein said solid state phase change material incorporates particulate additions of materials selected from the group consisting of metals, carbon, plastic, silica, and mixtures thereof.

3. The composite material of claim 1, wherein said solid state phase change material incorporates fibrous materials selected from the group consisting of glass, carbon, silica, natural fabric, artificial fabric, metals, and mixtures thereof.

4. The composite material of claim 1, wherein said solid state phase change material comprises a component of a passive solar thermal storage unit.

5. The composite material of claim 4, wherein said passive solar thermal storage unit is a Trombe wall.

6. The composite material of claim 4, comprising a component of the floor, wall, or ceiling of a structure.

7. The composite material of claim 1, comprising a heat transfer or heat exchanging material.

8. The composite material of claim 1, wherein the materials contacting said solid state phase change material comprise structural members.

9. The composite material of claim 8, wherein said structural members are selected from the group consisting of single layer, multi-channel, and multi-layer, multi-channel members containing said polyol.

10. The composite material of claim 1, wherein said solid state phase change material is laminated between facing sheets comprising said contact materials.

11. The composite material of claim 10, wherein said solid state phase change material also include additives of said contact materials.

12. The composite material of claim 10, wherein said laminate contains at least one interior sheet of said contact material.

13. The composite material of claim 10, wherein the facing sheets of said laminate are textured.

14. The composite material of claim 10, wherein the facing sheets of said laminate are non-textured.

15. The composite material of claim 1, wherein said solid state phase change material is impregnated with said contact material.

16. The composite material of claim 12, wherein said solid state phase change material is impregnated with contact materials selected from the group consisting of cellulose, natural fabric fibers, artificial fabric fibers, metal fibers, plastic fibers, and mixtures thereof.

17. The composite material of claim 12, wherein said solid state phase change material is impregnated into porous contact materials.

18. The composite material of claim 17, wherein said porous contact materials are selected from the group consisting of cement, concrete, rock, cellulose, gypsum, and vermiculite.

19. A method for impregnating a solid-state phase change material into porous and/or fibrous previously solidified solid substances comprising:

contacting a water solution of the phase change material with the solid-state phase change material to effect impregnating the solid material with the phase change material and removing the water in a manner to rigidly bind residue phase change material to the solid material.

20. The method of claim 19, wherein said water solution is saturated with said phase change material.

21. The method of claim 19, wherein said water solution is heated.

22. The method of claim 19, wherein the porous and/or fibrous substances are heated.

23. The method of claim 19, wherein the porous and/or fibrous substances are selected from the group consisting of wood, wood products, gypsum, cement, concrete, clay, rock, glass, natural fiber, artificial fiber, metal fiber, plastic fiber, and mixtures thereof.

24. The method of claim 19, wherein the contacting is conducted under vacuum.

25. A method for impregnating stone-like construction materials formed from a coalition of previously solidified solid precursor particles into a solid mass comprising:

contacting a sufficient amount of solid-state phase change material with water to form a solution;

utilizing a previously solidified porous aggregate solid material that is compatible with the particles forming the construction material;

contacting the solution of the solid-state phase change material with the porous aggregate in a manner to effect impregnating the aggregate material with the solid-state phase change material and rigidly binding the residue solid-state phase change material to the aggregate material;

contacting the porous aggregate material impregnated with the phase change material with the precursor particles of the construction material to form a combined mass; and

coalescing the combined mass into a solid mass to form the stone-like construction material.

26. The method of claim 25, wherein said solid mass comprises cement, mortar, concrete, porous aggregate, and mixtures thereof.

27. The method of claim 25, wherein the porous aggregate material is selected from the group consisting of vermiculite, perlite, other porous aggregate, and mixtures thereof.

28. A method of impregnating stone-like construction materials formed from a coalition of precursor particles into a solid mass comprising:

contacting a sufficient amount of solid-state phase change material with water to form a solution, contacting the solution of phase change material with a porous aggregate material that is compatible with the particles forming the construction materials;

contacting the porous aggregate-phase change material with the precursor particles of the construction material to form a combined mass; and

coalescing the combined mass into a solid mass to form a stone-like construction material, and wherein said phase change material is selected from the group consisting of pentaerythritol, penthglycerine, neopentyl glycol, tetramethylol propane, monoaminopentaerythritol, diaminopentaerythritol, tris(hydroxymethyl)acetic acid, and mixtures thereof.