Apparatus for the electrochemical detection of the oxygen content of liquids

• US 4,576,704 A
• Filed: 01/29/1985
• Issued: 03/18/1986
• Est. Priority Date: 06/02/1983
• Status: Expired due to Term

• Current Assignee: Züllig AG Rheineck (Danaher Corporation)
• Original Assignee: Züllig AG Rheineck (Danaher Corporation)
• Inventors: Zullig, Hans, Chiusole, Erwin
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): Nguyen, Nam X.
• Application Number:
  US06/703,229
• Time in Patent Office: 413 Days
• Field of Search: 204/402, 204/422
• US Class Current: 204/402
• CPC Class Codes: G01N 27/38 Cleaning of electrodes
• CPC Class Codes: G01N 27/49 Systems involving the determination of the current at a single specific value, or small range of values, of applied voltage for producing selective measurement of one or more particular ionic species

Abstract

In an apparatus for determining the oxygen content of a liquid by measuring the electric current between two electrodes (20, 21) of different materials which are immersed into the liquid, each electrode (20, 21) is embedded in its own body (18, 19) of insulating material in such a manner that only one end surface (20a, 21a) of each electrode is free and may be electrochemically active. The respective structural units (13, 14) consisting of an electrode and insulating body are pressed via associated springs (30, 31) at a common grinding device (28) displaceable by a driving apparatus, which grinding device serves for cleaning the free electrode end surfaces (20, 21a). The spring force by means of which the pressing to the grinding device (28) occurs is individually adjustable for each of the structural units (13, 14) by adjustment of a support ring (32,35) for the relevant spring (30, 31) to match the hardness, abrasion-resistance and corrosion properties of the material of the revelant electrode.

Claims

1. In an apparatus for the electrochemical measurement of the oxygen content of liquids, said apparatus including first and second electrodes whose free ends can be immersed in the liquid whose oxygen content is to be measured, the oxygen content of the liquid being measured by an electric current occurring between the two electrodes, the apparatus also including a rotatable grinding device which can contact the free ends of said electrodes to clean them while the shape, size and mutual spacing of the free ends of said electrodes remain unchanged, the improvement wherein

said first and second electrodes are embedded in respective first and second annular bodies of insulating material, each of said first and second annular bodies having an axial end surface which faces the liquid whose oxygen content is to be measured, the free ends of said first and second electrodes being exposed at the axial end surface of the respective annular body in which it is embedded, said first and second annular bodies being axially movable relative to one another,

said apparatus includes first and second spring means which respectively cooperate with said first and second annular bodies to individually bias their said axial end surfaces toward said rotatable grinding device, and

said apparatus includes at least one adjusting means for determining the biasing force of one of said first and second spring means exerted on its associated annular body, adjustment of said adjusting means enabling a uniform cleaning of the free ends of said two electrodes by said grinding device.

2. The apparatus as defined in claim 1, including a housing in which said first and second annular bodies are located, said housing including an opening therein;

wherein each of said first and second annular bodies includes an axial slot therein; and

including a pin means which is extendable through said opening in said housing to engage in the axial slot in each of said first and second annular bodies to prevent them from rotating while allowing axial displacement thereof.

3. The apparatus as defined in claim 2, including a rotatable shaft connected to said rotatable grinding device, said rotatable shaft coaxially extending through said first and second annular bodies.

4. The apparatus as defined in claim 3, wherein said first and second spring means comprise respective first and second helical compression springs which coaxially surround said rotatable shaft, each helical compression spring having a first end which contacts its associated annular body and an opposite second end.

5. The apparatus as defined in claim 4, including two adjusting means, a first adjusting means for said first helical compression spring means and a second adjusting means for said second helical compression spring.

6. The apparatus as defined in claim 5, wherein each of said two adjusting means comprises a support ring which is axially adjustably positionable with respect to said housing, each support ring contacting the second end of an associated helical compression spring.

7. The apparatus as defined in claim 6 wherein said first and second annular bodies comprise substantially cylindrical outer and inner sleeves.