Enhanced 2-hydroxy-4-methylthiobutanoic acid compositions and method of preparation

• US 4,579,962 A
• Filed: 02/24/1984
• Issued: 04/01/1986
• Est. Priority Date: 02/24/1984
• Status: Expired due to Term

• Current Assignee: Novus International, Inc. (Nippon Soda Company Limited)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Takano, Masaharu
• Primary Examiner(s): Sneed, Helen M. S.
• Application Number:
  US06/583,463
• Time in Patent Office: 767 Days
• Field of Search: 260/429.9, 562/581, 514/494, 514/557, 556/131
• US Class Current: 556/131
• CPC Class Codes: C07C 323/00 Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups

Abstract

Enhanced HMBA compositions which comprise 2-hydroxy-4-methylthiobutanoic acid and at least one metallic cation selected from the group consisting of sodium, potassium, magnesium and zinc ions are disclosed. The enhanced HMBA compositions are prepared by contacting HMBA and predetermined metallic cation(s) in molar ratios which are hyperstoichiometric and less than about five.

Claims

1. A composition consisting essentially of 2-hydroxy-4-methylthiobutanoic acid and at least one metallic cation selected from the group consisting of sodium, potassium, magnesium and zinc ions in which the molar ratio of 2-hydroxy-4-methylthiobutanoic equivalency to metallic cation is hyperstoichiometric and less than about five.

2. A composition consisting essentially of 2-hydroxy-4-methylthiobutanoic acid and sodium ion in which the molar ratio of 2-hydroxy-4-methylthiobutanoic acid equivalency to sodium ion is greater than one and less than about five.

3. A composition consisting essentially of 2 hydroxy-4-methylthiobutanoic acid and potassium ion in which the molar ratio of 2-hydroxy-4-methylthiobutanoic acid equivalency to potassium ion is greater than one and less that about five.

4. A composition consisting essentially of 2-hydroxy-4-methylthiobutanoic acid and magnesium ion in which the molar ratio of 2-hydroxy-4-methylthiobutanoic acid equivalency to magnesium ion is greater than two and less than about five.

5. A composition consisting essentially of 2-hydroxy-4-methylthiobutanoic acid and zinc ion in which the molar ratio of 2-hydroxy-4-methylthiobutanoic acid equivalency to zinc ion is greater than two and less than about five.

6. A method for preparing enhanced 2-hydroxy-4-methylthiobutanoic acid compositions which comprises contacting 2-hydroxy-4-methylthiobutanoic acid and at least one metallic cation selected from the group consisting of sodium, potassium, magnesium and zinc ions from a suitable cation donor wherein, the molar ratio of 2-hydroxy-4-methylthiobutanoic acid to metallic cation is hyperstoichiometric and less than about five.

7. The method of claim 6 further comprising drying the enhanced 2-hydroxy-4-methylthiobutanoic acid compositions.

8. The method of claim 6 in which the metallic cation donor is selected from the group consisting of hydroxides, oxides, bicarbonates, carbonates, acetates, halides, nitrates, phosphates, and sulfates.

9. The method of claim 6 in which the metallic cation donor is selected from the group consisting of hydroxides, oxides, bicarbonates and carbonates.

10. The method of claim 6 further comprising the presence of water.