Method for adsorbing and storing hydrogen at cryogenic temperatures

• US 4,580,404 A
• Filed: 08/09/1985
• Issued: 04/08/1986
• Est. Priority Date: 02/03/1984
• Status: Expired due to Fees

• Current Assignee: APD Cryogenics, Inc.
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Pez, Guido P., Steyert, William A.
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US06/764,150
• Time in Patent Office: 242 Days
• Field of Search: 62/48, 62/55.5, 62/268, 62/100, 55/269, 417/901, 423/248
• US Class Current: 62/55.5
• CPC Class Codes: F04B 37/04 Selection of specific absorption or adsorption materials
• CPC Class Codes: Y10S 417/901 Cryogenic pumps

Abstract

Hydrogen is stored at cryogenic temperatures by adsorption on porous carbon having a nitrogen BET apparent surface area above about 1500 m² /g. Hydrogen can be adsorbed and desorbed in the context of a cryopump, having as the pumping element a panel, having large particles of pressed porous carbon thereon.

Claims

1. In a high vacuum pump comprising a cryoadsorption pumping element and means for cooling the pumping element to the cryogenic temperature range, the improvement wherein the pumping element comprises porous carbon particles having a nitrogen BET apparent surface area above about 1500 m² /g and dimensions greater than about 1.5×

1.5×

1.5 mm.

2. The pump of claim 1, wherein the porous carbon particles have a bulk density greater than about 0.25 g/cm³ and a cage-like structure which contributes to over 60% of its surface, as measured by phase contrast, high resolution microscopy.

3. The pump of claim 1, wherein the porous carbon particles have a nitrogen BET apparent surface area above about 2000 m² /g.

4. The pump of claim 1, wherein the porous carbon particles have a nitrogen BET apparent surface area above about 2200 m² /g.

5. The pump of claim 1, wherein the porous carbon particles have dimensions greater than about 2×

2×

2 mm.

6. The pump of claim 1, wherein the porous carbon particles have a nitrogen BET apparent surface area greater than 2300 m² /g, made by treating a carbonaceous feed with hydrous potassium hydroxide in an amount of 0.5-5 weights per weight of carbonaceous feed;

precalcining the mixture of hydrous potassium hydroxide and carbonaceous feed at 315°

-482°

C. for 15 min-2 h and calcining the thus pre-calcined feed at 704°

-982°

C. for 20 min-4 h under an inert atmosphere.

7. The pump of claim 1, wherein the pumping element is a panel, having pressed thereon porous carbon particles of nitrogen BET apparent surface area above about 2000 m² /g and dimensions above about 2.5×

2.5×

2.5 mm.

8. A panel assembly for a cryoadsorption pump, comprising a high thermal conductivity metal panel adapted for cooling by a cryogenic fluid, the metal panel having mounted thereon porous carbon particles having a nitrogen BET apparent surface area above 1500 m² /g and dimensions greater than 1.5×

1.5×

1.5 mm.

9. The panel assembly of claim 8, wherein the porous carbon particles have a bulk density greater than about 0.25 g/cm³ and a cage-like structure which contributes to over 60% of its surface, as measured by phase contrast high resolution microscopy.

10. The panel of claim 8, wherein the porous carbon particles have a nitrogen BET apparent surface area above about 2000 m² /g.

11. The panel of claim 8, wherein the porous carbon particles are affixed to the metal panel by pressing.

12. The panel of claim 8, wherein the porous carbon particles are applied to the metal panel in the form of pellets.

13. The panel of claim 8, wherein the porous carbon particles have dimensions above about 2×

2×

2 mm.

14. The panel of claim 13, wherein the panel is a cylindrical surface.

15. The panel of claim 13, wherein the panel is an extended surface.

16. The panel of claim 13, wherein the panel is a surface of revolution.

17. The panel of claim 8, wherein the porous carbon particles have a nitrogen BET apparent surface area above about 2200 m² /g and are applied to the panel in the form of pellets.

18. The panel of claim 8, wherein the panel is an extended surface and the porous carbon particles have a nitrogen BET apparent surface area above about 2000 m² /g and dimensions above about 2×

2×

2 mm.

19. A method for maintaining high initial hydrogen pumping speed, characteristic of adsorbent carbons of 1-1.5 mm or smaller in a high vacuum pump comprising a cryoadsorption pumping element and means for cooling the pumping element to the cryogenic temperature range, comprising using in the cryoadsorption pump the panel assembly of claim 18.

20. A method for maintaining high initial hydrogen pumping speed, characteristic of adsorbent carbons of 1-1.5 mm or smaller in a high vacuum pump comprising a cryoadsorption pumping element and means for cooling the pumping element to the cryogenic temperature range, comprising using in the cryoadsorption pump the panel assembly of claim 8.

21. A method for maintaining high initial hydrogen pumping speed, characteristic of adsorbent carbon particles of 1-1.5 mm or smaller, in a high vacuum pump comprising a cryoadsorption pumping element and means for cooling the pumping element to the cryogenic temperature range, comprising using as pumping element porous carbon particles having a nitrogen BET apparent surface area above 1500 m² /g and dimensions above about 1.5×

1.5×

1.5 mm.

22. The method of claim 21, wherein the porous carbon particles have a bulk density greater than about 0.25 g/cm³ and a cage-like structure which contributes to over 60% of its surface, as measured by phase contrast, high resolution microscopy.

23. The method of claim 21, wherein the porous carbon particles have a nitrogen BET apparent surface area above about 2000 m² /g and dimensions greater than about 2×

2×

2 mm.