Electrochemical cell

• US 4,581,305 A
• Filed: 06/25/1984
• Issued: 04/08/1986
• Est. Priority Date: 06/25/1984
• Status: Expired due to Term

• Current Assignee: Pacesetter Incorporated (Abbott Laboratories)
• Original Assignee: Cordis Corporation (Cardinal Health, Inc.)
• Inventors: Jones, W. Kinzy, Tataria, Harshad
• Primary Examiner(s): LeFevour, Charles F.
• Application Number:
  US06/623,965
• Time in Patent Office: 652 Days
• Field of Search: 429/90, 429/91, 429/194, 429/197, 429/220
• US Class Current: 429/91
• CPC Class Codes: H01M 4/58 of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: H01M 6/5055 End of discharge indicated by a voltage step

Abstract

The electrochemical cell comprises an outer conductive housing, an anode material within the housing, a cathode material within the housing, and porous insulating means separating the anode material from the cathode material, and an electrolyte inside the housing and within the porous insulating means. The cathode material is a mixture of a metallic halogen compound and a metallic sulfide compound less electrochemically reactive with the anode material than the metallic halogen compound. The metallic halogen compound and the less electrochemically reactive metallic sulfide compound are mixed in a proportion whereby a first voltage potential can be developed between the metallic halogen compound and the anode material until the metallic halogen compound is depleted so that a second voltage potential different than the first voltage potential can be developed between the less reactive metallic sulfide compound and the anode material after the metallic halogen compound is depleted in order to indicate depletion of the metallic halogen compound and the approaching end of life of the cell.

Claims

1. An electrochemical cell comprising:

an outer conductive housing, an lithium anode within said housing;

a cathode material within said housing, said cathode material being a mixture of a low conductivity cupric halide and a higher conductivity cupric sulfide with no free sulfur in the cell, said cupric sulfide being less electrochemically reactive with said anode material than said cupric halide; and

porous insulating means with a non-aqueous electrolyte contained therein positioned between said anode material and said cathode material, a first voltage potential being developed between said cupric halide and said anode material until said cupric halide is depleted so that a second voltage potential different than the first voltage potential can be developed between said less reactive cupric sulfide and said anode material after said cupric halide is depleted in order to indicate depletion of said cupric halide and the approaching end of life of said cell.

2. The cell of claim 1 wherein said cupric halide is cupric fluoride.

3. The cell of claim 2 wherein the ratio of cupric fluoride to cupric sulfide is 80 Mole % cupric fluoride to 20 Mole % cupric sulfide.

4. The cell of claim 1 wherein said electrolyte is lithium perchlorate dissolved in a mixture of dioxolane, 1,2 dimethoxy ethane and 3,5 diemthylisoxazole.

5. The cell of claim 1 wherein said second voltage potential is less than said first voltage potential.

6. The cell of claim 1 wherein the first voltage potential is approximately 3.4v and the second voltage potential is approximately 2.1v.