Antistatic compositions comprising polymerized oxyalkylene monomers and an inorganic tetrafluoroborate, perfluoroalkyl carboxylate, hexafluorophosphate or perfluoroalkylsulfonate salt

• US 4,582,781 A
• Filed: 08/01/1984
• Issued: 04/15/1986
• Est. Priority Date: 08/01/1984
• Status: Expired due to Fees

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Chen, Janglin, Kelly, James E., Plakunov, James
• Primary Examiner(s): BRAMMER, JACK
• Application Number:
  US06/636,764
• Time in Patent Office: 622 Days
• Field of Search: 430/527, 430/528, 430/529, 430/530, 430/631, 430/637, 430/966, 428/421, 428/422, 428/341
• US Class Current: 430/527
• CPC Class Codes: C08K 3/32 Phosphorus-containing compounds
• CPC Class Codes: C08K 3/38 Boron-containing compounds
• CPC Class Codes: C08K 5/098 Metal salts of carboxylic acids
• CPC Class Codes: C08K 5/42 Sulfonic acids; Derivatives thereof
• CPC Class Codes: C09K 3/16 Anti-static materials
• CPC Class Codes: G03C 1/853 Inorganic compounds, e.g. metals
• CPC Class Codes: Y10S 430/167 X-ray
• CPC Class Codes: Y10T 428/273 of coating
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated

Abstract

Antistatic compositions are disclosed comprising a hydrophilic binder, surface-active polymer having polymerized oxyalkylene monomers and an inorganic salt characterized in that the salt is selected from the group consisting of inorganic tetrafluoroborates, perfluoroalkyl carboxylates, hexafluorophosphates and perfluoroalkyl sulfonates.

Claims

1. An element comprising a support and a layer of an antistatic composition comprising a hydrophilic binder, a surface-active polymer having polymerized oxyalkylene monomers and an inorganic salt characterized in that the salt is selected from the group consisting of inorganic tetrafluoroborates, perfluoroalkyl carboxylates, hexafluorophosphates and perfluoroalkyl sulfonates.

3. The element of claim 1 or 2 wherein the oxyalkylene monomer is selected from the group consisting of oxyethylene and oxypropylene and the salt is selected from the group consisting of alkali metal perfluoromethanesulfonates, alkali metal tetrafluoroborates, alkali metal perfluoropropyl carboxylates, alkali metal hexafluorophosphates and alkali metal perfluorobutanesulfonates.

4. The element of claim 1 or 2 wherein the polymer is selected from the polymers of Table I and the salt is selected from the group consisting of potassium trifluoromethanesulfonate, potassium perfluorobutanesulfonate, potassium trifluoroacetate, potassium perfluorobutanoate, lithium tetrafluoroborate, potassium hexafluorophosphate and lithium trifluoromethanesulfonate.

5. The element of claim 1 or 2 wherein the antistatic layer comprises from 5 to 500 mg of polymerized polyoxyalkylene monomers per square meter of the layer, from 5 to 500 mg of the inorganic salt per square meter and from 0.1 to 10 gm of the binder per square meter.

2. A photographic element comprising a support having thereon a radiation-sensitive layer and a layer of an antistatic composition comprising a hydrophilic binder, a surface-active polymer having polymerized oxyalkylene monomers and an inorganic salt characterized in that the salt is selected from the group consisting of inorganic tetrafluoroborates, hexafluorophosphates, perfluoroalkyl carboxylates and perfluoroalkyl sulfonates.

6. The element of claim 2 wherein the photographic element is a radiographic element having a silver halide emulsion on each side of the support and wherein the antistatic layer overcoats each of the radiographic emulsions.

7. The element of claim 2 wherein the antistatic composition is coated on the support surface which is remote from the radiation-sensitive layer.