Aqueous emulsions containing hydrophilic silicone-organic copolymers

• US 4,584,337 A
• Filed: 12/18/1984
• Issued: 04/22/1986
• Est. Priority Date: 12/18/1984
• Status: Expired due to Term

• Current Assignee: Dow, Inc.
• Original Assignee: Dow, Inc.
• Inventors: Lee, Chi-long, Shyu, Wen-Bin
• Primary Examiner(s): Briggs, Sr., Wilbert J.
• Application Number:
  US06/683,303
• Time in Patent Office: 490 Days
• Field of Search: 524/806, 524/457, 524/866, 524/500, 524/547, 525/479, 528/26, 528/28, 424/78
• US Class Current: 524/500
• CPC Class Codes: C08F 290/068 Polysiloxanes
• CPC Class Codes: C08G 18/61 Polysiloxanes
• CPC Class Codes: C08G 18/8116 esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group

Abstract

This present invention provides aqueous emulsions which are capable of depositing coatings and membranes of hydrophilic, water-absorbing silicone-organic polymer elastomers. The elastomers are free radical polymerized copolymers of (A) from 50 to 95 parts by weight of block copolymers containing polydiorganosiloxane segments and polyalkyleneoxy segments which block copolymers contain terminal aliphatically unsaturated groups such as those derived from the reaction of isocyanatoethyl methacrylate with terminal free hydroxyl groups present on the polyalkyleneoxy segments and (B) from 5 to 50 parts by weight of at least one substantially water insoluble aliphatically unsaturated organic monomer which is compatible with (A) such as methyl methacrylate. The aqueous emulsions are useful for forming coatings and membranes of the above elastomers and also provide a vehicle for the deposition of coatings of such elastomers which are capable of controllably releasing bioactive agents such as insecticides or herbicides which are dispersed within the elastomer film deposited from the aqueous emulsion.

Claims

1. An aqueous emulsion containing a hydrophilic, water-absorbing, silicone-organic copolymer elastomer consisting essentially of the product obtained upon reacting

(A) from 50 to 95 parts by weight of at least one block copolymer of the formula ##STR7## wherein a is an integer of from 4 to 49, inclusive,

b is an integer of from 0 to 15, inclusive,

c is an integer having a value of from 2 to 4, inclusive,

d is an integer of from 0 to 25, inclusive,

e is an integer of from 5 to 50 inclusive

d+e is no greater than 50 and e is greater than or equal to d,

f is 0 or 1,

f'"'"' is 0 or 1,

f+f'"'"'+b is at least 2,

R is a monovalent hydrocarbon or halohydrocarbon radical of from 1 to 6 inclusive carbon atoms which is free of aliphatic unsaturation,

R'"'"' is a methyl or a phenyl radical,

Z is a monovalent radical selected from the group consisting of CH₂ ═

CR"COOR"'"'"'NHCOO--, CH₂ ═

CHCH₂ NHCOO-- and CH₂ ═

CR"COO--,

R" is an alkyl radical of from 1 to 4 inclusive carbon atoms or hydrogen, and

R"'"'"' is a divalent hydrocarbon radical of from 1 to 6 inclusive carbon atoms with

(B) from 5 to 50 parts by weight of at least one substantially water insoluble aliphatically unsaturated organic monomer which is compatible with said (A), said reaction being conducted under free radical polymerization conditions in the presence of water and an effective amount of a surfactant and wherein the dry elastomer obtained upon removal of the water is hydrophilic and capable of absorbing at least 3% by weight of water based upon the total weight of said elastomer.

2. The emulsion as claimed in claim 1 wherein said (B) is at least one monomer of the formula ##STR8## Wherein W is selected from the group consisting of --COOR"", --OOCCH₃ and --C₆ H₅ wherein R"" is an alkyl radical of from 1 to 6 inclusive carbon atoms.

3. The emulsion as claimed in claim 2 wherein a is an integer of from 8 to 14, inclusive, c is 3 or 4, d is 0, e is an integer of from 10 to 20, inclusive, R is a methyl, phenyl or 3,3,3-trifluoropropyl radical, and Z is CH₂ ═

CR"COO(CH₂)₂ NHCOO--, and the surfactant is an anionic surfactant.

4. The emulsion as claimed in claim 3 wherein R and R'"'"' are each methyl radicals and wherein said composition contains from 30 to 50 parts by weight of said (B).

5. The emulsion as claimed in claim 3 wherein b is 0.

6. The emulsion as claimed in claim 5 wherein R and R'"'"' are each methyl radicals.

7. The emulsion as claimed in claim 3 wherein said emulsion contains from 30 to 50 parts by weight of said (B) and said (B) is selected from the group consisting of CH₂ ═

CCH₃ COOCH₃, CH₂ ═

CHC₆ H₅ and mixtures thereof.

8. The emulsion as claimed in claim 6 wherein said emulsion contains from 30 to 50 parts by weight of said (B) and said (B) is selected from the group consisting of CH₂ ═

CCH₃ COOCH₃, CH₂ ═

CHC₆ H₅ and mixtures thereof.

9. The emulsion as claimed in claim 1 which additionally contains dispersed within said emulsion at least one bioactive agent which is compatible with said emulsion.

10. The emulsion as claimed in claim 3 which additionally contains dispersed within said emulsion at least one bioactive agent which is compatible within said emulsion dispersion.

11. The emulsion as claimed in claim 4 which additionally contains dispersed within said emulsion at least one bioactive agent which is compatible with said emulsion.

12. The emulsion as claimed in claim 6 which additionally contains dispersed within said emulsion at least one bioactive agent which is compatible with said emulsion.