Fusion adhesive which can comprise an isocyanate prepolymer, a thermoplastic polymer and/or a lower molecular weight ketone resin

• US 4,585,819 A
• Filed: 08/14/1984
• Issued: 04/29/1986
• Est. Priority Date: 08/14/1984
• Status: Expired due to Term

• Current Assignee: H.B. Fuller Licensing & Financing, Inc.
• Original Assignee: HB Fuller Company
• Inventors: Bernig, Walter, Windhoff, Jochen, Reischle, Ferdinand
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US06/640,709
• Time in Patent Office: 623 Days
• Field of Search: 524/196, 525/440, 525/457, 525/458, 427/388.1, 427/388.2, 427/389, 427/389.9, 427/391, 427/393, 427/393.5, 428/423.1, 428/423.3, 428/423.4, 428/423.9, 428/425.1, 428/425.8
• US Class Current: 524/196
• CPC Class Codes: C08L 2666/16 Addition or condensation polymers of aldehydes or ketones according to C08L59/00 - C08L61/00; Derivatives thereof
• CPC Class Codes: C09J 175/04 Polyurethanes
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31554 Next to second layer of polyamidoester
• CPC Class Codes: Y10T 428/31558 Next to animal skin or membrane
• CPC Class Codes: Y10T 428/31569 Next to natural rubber
• CPC Class Codes: Y10T 428/31591 Next to cellulosic
• CPC Class Codes: Y10T 428/31605 Next to free metal

Abstract

The present invention relates to fusion adhesives characterized in that they comprise an isocyanate prepolymer, a thermoplastic polyurethane or polyester, and/or a lower molecular weight synthetic resin selected from the group consisting of ketone resins, hydrogenation products of acetophenone condensation resins, and mixtures thereof.

Claims

1. A fusion adhesive which comprises 20-90 percent by weight isocyanate prepolymer, and 5-50 percent by weight lower molecular weight synthetic resin selected from the group consisting of ketone resins, hydrogenated products of acetophenone condensation resins, and mixtures thereof.

2. The fusion adhesive of claim 1 which further comprises up to 75 percent by weight thermoplastic polyurethane.

3. The fusion adhesive of claim 1 which further comprises 10 to 70 percent thermoplastic polyester.

4. The fusion adhesive of claim 1 which comprises 50-75 percent by weight isocyanate prepolymer, 10-40 percent by weight lower molecular weight synthetic resin, and which further comprises 5-55 percent by weight thermoplastic polymer selected from the group consisting of thermoplastic polyurethane, thermoplastic polyester, and mixtures thereof.

5. The fusion adhesive of claim 1 which comprises 50-80 percent by weight isocyanate prepolymer, 20-70 percent by weight lower molecular weight synthetic resin, and which further comprises up to 2 percent by weight thermoplastic polymer selected from the group consisting of thermoplastic polyurethanes, thermoplastic polyesters, and mixtures thereof.

6. A fusion adhesive which comprises 50-75 percent by weight isocyanate prepolymer, and 10-40 percent by weight lower molecular weight synthetic resin selected from the group consisting of ketone resins, hydrogenation products of acetophenone condensation resins, and mixtures thereof.

7. The fusion adhesive of claim 6 which further comprises up to 75 percent by weight thermoplastic polyurethane, and mixtures thereof.

8. A fusion adhesive which comprises 50-80 percent by weight isocyanate prepolymer, and 20-70 percent by weight lower molecular weight synthetic resin selected from the group consisting of ketone resins, hydrogenation products of acetophenone condensation resins, and mixtures thereof.

9. The fusion adhesive of claim 8 which further comprises up to 2 percent by weight thermoplastic polymer selected from the group consisting of thermoplastic polyurethanes, thermoplastic polyesters, and mixtures thereof.

10. A fusion adhesive which comprises 20-90 percent by weight isocyanate prepolymer and 10-70 percent by weight thermoplastic polyester.

11. The fusion adhesive of claim 10 which further comprises up to 50 percent of lower weight molecular weight synthetic resin selected from the group consisting of ketone resins, hydrogenation products of acetophenone condensation resins, and mixtures thereof.

12. A method of bonding substrates which comprises contacting a substrate with a bond-forming amount of a fusion adhesive comprising 20-90 percent by weight isocyanate prepolymer and 5-50 percent by weight lower molecular weight synthetic resin selected from the group consisting of ketone resins, hydrogenation products of acetophenone condensation resins, and mixtures thereof.

13. The method of claim 12 wherein the fusion adhesive further comprises 2-75 percent by weight thermoplastic polymer selected from the group consisting of thermoplastic polyurethanes, thermoplastic polyesters, and mixtures thereof.

14. The method of claim 12 wherein the fusion adhesive further comprises up to about 2 percent by weight of a thermoplastic polymer selected from the group consisting of thermoplastic polyurethanes, thermoplastic polyesters, and mixtures thereof.

15. The method of claim 12 wherein the substrate is selected from the group consisting of thermoplastic materials, thermosetting synthetics, foam material, varnished surfaces, wood and wooden material, paper, leather, synthetic leather, rubber, textiles, non-woven materials, and metals.

17. The product of the method of claim 12.

18. The product of the method of claim 13.

19. The product of the method of claim 14.

20. The product of the method of claim 15.

16. A method of bonding substrates which comprises placing a bond-forming amount of a fusion adhesive comprising 20-90 percent by weight isocyanate prepolymer, 0-50 percent by weight lower moleclar weight synthetic resin, and 10-70 percent by weight thermoplastic polyesters between a first substrate and a second substrate and contacting one of the first and second substrates with the other of the first and second substrates, wherein one of the first and second substrates comprises a foam material and the other of the first and second substrates comprises a material selected from the grop consisting of foam materials, non-woven materials and textiles.

21. The product of the method of claim 16.