Fluorosilicone rubber composition, process and polymer

• US 4,585,848 A
• Filed: 11/22/1982
• Issued: 04/29/1986
• Est. Priority Date: 04/09/1981
• Status: Expired due to Term

• Current Assignee: Edwin R. Evans, Matsumoto, Makoto
• Original Assignee: Edwin R. Evans, Matsumoto, Makoto
• Inventors: Matsumoto, Makoto, Evans, Edwin R.
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US06/443,545
• Time in Patent Office: 1,254 Days
• Field of Search: 528/15, 528/32, 528/31, 556/454
• US Class Current: 528/15
• CPC Class Codes: C08G 77/24 halogen-containing groups
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/08 containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen

Abstract

High strength solvent resistant rubber compositions comprise a vinyl terminated fluorosilicone copolymer gum having a controlled, low amount of backbone vinyl unsaturation, a conventional platinum curing agent, and a crosslinker containing a least two Si-H bonds.

Claims

1. In a solvent resistant room temperature vulcanizable silicone rubber composition comprising

(A) a mixture composed of

(i) a vinyl-terminated base polymer, said base polymer being prepared by copolymerization of methyl-3,3,3-trifluoropropylsiloxane cyclic trimer and octamethylcyclotetrasiloxane, and the viscosity of said base polymer varies from 1,000 to 200,000 centipoise at 25°

C., and

(ii) a platinum catalyst, and

(B) alone, or in admixture with base polymer (i),

(iii) a cross-linking polymer selected from

(a) a resin having ##STR10## and SiO₂ units where the R to Si ratio varies from 1.0 to 2.7;

(b) a resin having ##STR11## units, SiO₂ units and RR³ SiO units where the R to Si ratio varies from 1.2 to 2.7;

(c) a polymer of the formula;

##STR12## where R is alkyl of from 1 to 8 carbon atoms or phenyl, R¹ is perfluoroalkyl of from 1 to 8 carbon atoms, s is at least 1, t and z may be zero or a positive integer and the viscosity or the polymer varies from 10 to 1,000 centipoise at 25°

C., where the concentration of siloxy units taken t times varies from 0 to 75 mole percent, and R³ is alkyl of 1 to 8 carbon atoms, or --CH₂ CH₂ R¹ ;

or a mixture of (a), (b) and (c), the total composition (A) and (B) comprising per 100 parts by weight of a base polymer (i), from 0.1 to 50 parts per million of platinum catalyst (ii), and from 1 to 50 parts of cross-linking polymer (iii), the improvement wherein the cyclic trimer used in the preparation of said base polymer (i) contains no more than 1.0 weight percent of a difluoropropenyl-containing compound of the formula ##STR13##

2. The composition of claim 1 which also includes from 5 to 100 parts of a filler which is selected from the class consisting of titanium dioxide, lithopone, zinc oxide, zirconium silicate, silica aerogel, iron oxide, diatomaceous earth, calcium carbonate, fumed silica, precipitated silica, glass fibers, magnesium oxide, chromic oxide, zirconium oxide, aluminum oxide, alpha quartz, calcined clay, asbestos, carbon, graphite, cork, cotton and synthetic fibers.

3. The composition of claim 2 wherein said filler is fumed silica, precipitated silica, each of which has been treated with a silicone compound, or a mixture thereof.

4. The composition of claim 1 wherein R is methyl, R¹ is CF₃, and R³ is --CH₂ CH₂ CF₃.

5. The composition of claim 3 where the silicone compound is silazane.

6. The composition of claim 1 wherein the platinum catalyst is a platinum complex with an alcohol.

7. The composition of claim 1 wherein there is present in the total composition from 100 to 10,000 parts per million of a cure inhibitor selected from an organic hydroperoxide, dialkylmaleate, or dialkylmaleimide.

8. The composition of claim 7 wherein the cure inhibitor is dialkylmaleate.

9. The composition of claim 1 wherein the concentration of units taken y times in base polymer (i) varies from 26 to 29 mole percent.

10. The composition of claim 1 wherein the viscosity of polymer (i) is in the range of 20,000 to 85,000 centipoise at 25°

C.

11. A process for forming a solvent resistant silicone elastomer comprising (a) mixing component (A) and component (B), (A) and (B) being as defined in claim 1, and (b) allowing the mixture to cure.

12. In a vinyl-terminated polymer prepared by copolymerization of methyl-3,3,3-trifluoropropyl-siloxane cyclic trimer and octamethylcyclotetrasiloxane, said polymer having a viscosity of from 1,000 to 200,000 centipoise at 25°

C., the improvement wherein the cyclic trimer used in preparation of said polymer contains no more than 1.0 weight percent of a difluoropropenyl-containing compound of the formula ##STR14##