Electronic display element

• US 4,586,792 A
• Filed: 08/31/1984
• Issued: 05/06/1986
• Est. Priority Date: 08/31/1984
• Status: Expired due to Term

• Current Assignee: State of Rhode Island and Providence Plantations
• Original Assignee: Board of Governors For Higher Education State of Rhode Island, Providence Plantations
• Inventors: Yang, Sze C., Durand, Richard R. Jr.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Jaconetty, Kenneth
• Application Number:
  US06/646,232
• Time in Patent Office: 613 Days
• Field of Search: 350/357, 350/363
• US Class Current: 359/273
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte

Abstract

An electronic display device having a polyaniline film coated on a transparent electrode. The film has electrochromic properties and will display at least three distinct reproducible color changes.

Claims

1. An electronic display element which comprises:

first and second electrodes in electrolytic communication at least one of said electrodes being transparent;

a polymer formed from monomeric aniline coated on one of said electrodes the polymer characterized in that it will display at least three distinct color changes in response to voltages applied to the electrodes which color changes are reproduceable.

2. The display element of claim 1 wherein the electrodes are transparent conductive coatings.

3. The display element of claim 2 wherein the transparent conductive coatings are metal coatings.

4. The display element of claim 3 wherein the transparent conductive coatings are selected from the group consisting of tin oxide, indium oxide, gold and/or platinum.

5. The display element of claim 1 wherein the electrolyte is selected from the group consisting of trifluoroacetate, trifluoromethane sulfonate, trifluoroacetic acid, sodium trifluoroacetate, hydrochloric acid, potassium chloride and/or phthalate buffer solutions.

6. The display element of claim 1 wherein the polymer is formed by the polymerization of the monomers selected from the group consisting of:

##STR5## wherein R₁ -R₈ =any one of the following groups;

--H, --(CH₂)_n CH₃ (n=o to

     10), --OCH₃, --OC₂ H₅ --Cl, --F, --Br, --I, --CN, --SO₃ H, ##STR6## (where m, n, 1=0 to 5 and X=any of the above groups that define R1-R8).