Process for separating gaseous mixtures using a semipermeable membrane constructed from substituted poly(arylene oxide) polymer

• US 4,586,939 A
• Filed: 11/29/1983
• Issued: 05/06/1986
• Est. Priority Date: 08/26/1982
• Status: Expired due to Fees

• Current Assignee: Standard Oil Company (BP PLC)
• Original Assignee: Standard Oil Company (BP PLC)
• Inventors: Li, George S.
• Primary Examiner(s): Therkorn, Ernest G.
• Application Number:
  US06/556,181
• Time in Patent Office: 889 Days
• Field of Search: 210/654, 210/490, 210/500.2, 210/506, 55/16, 55/158, 429/249, 429/253, 521/27, 204/296, 585/818, 585/819
• US Class Current: 95/47
• CPC Class Codes: B01D 53/22 by diffusion manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00
• CPC Class Codes: B01D 71/5223 Polyphenylene oxide, phenyl ether polymers or polyphenylethers

Abstract

The process for the separation of gases from a mixture is improved by using as the separation vehicle a single layer semipermeable membrane containing at least about 25 weight percent, based upon the total weight of the membrane, of at least one substituted poly(arylene oxide) polymer containing at least about 50 mole percent of structural units of the formula ##STR1## wherein each R is independently a C₁ to C₈ aliphatic; a C₅ to C₇ cycloaliphatic; a C₁ to C₈ alkoxy radical; a C₆ to C₁₂ aromatic radical or an inertly-substituted derivative of any one of them, each radical being free of a tertiary alpha-carbon atom, each X is independently hydrogen or a radical at least the size of a chloride radical, with the proviso that at least one X is not hydrogen. The process can also be practiced with a semipermeable membrane containing at least about 50 weight percent, based upon the total weight of the membrane, of at least one substituted poly(arylene oxide) copolymer containing from about 80 to 95 mole percent of structural units of the formula ##STR2## and from about 5 to 20 mole percent of structural units of the formula ##STR3##

Claims

1. In a process for the separation of gases from a mixture containing at least two gases into two fractions, one fraction being enriched with at least one of said gases and the other fraction being depleted in same, the process comprising:

contacting the gaseous mixture with a semipermeable membrane in such a manner that a portion of the gaseous mixture selectively passes through the membrane resulting in the enriched fraction being on one side of the membrane and the depleted fraction being on the other side of the membrane, the improvement comprising

the use of a single layer semipermeable membrane containing at least about 25 weight percent, based upon the total weight of the membrane, of at least one substituted poly(arylene oxide) polymer containing at least about 50 mole percent of structural units of the formula ##STR12## wherein each R is independently a C₁ to C₈ aliphatic radical;

a C₅ to C₇ cycloaliphatic radical;

a C₁ to C₈ alkoxy radical;

a C₆ to C₁₂ aromatic radical or an inertly-substituted derivative of any one of them, each radical being free of a tertiary alpha-carbon atom; and

each X is independently hydrogen or a halide radical at least the size of a chloride radical, with the proviso that at least one X is not hydrogen.

2. The process of claim 1 wherein each R is independently a C₁ to C₈ alkyl radical.

3. The process of claim 2 wherein each R is a methyl radical.

4. The process of claim 3 wherein said halide is a bromide radical.

5. The process of claim 4 wherein the substitute poly(arylene oxide) polymer contains at least about 75 mole percent of the structural units of formula I.

6. The process of claim 5 wherein the gaseous mixture is natural gas.

7. The process of claim 5 wherein the gaseous mixture is air.

8. The process of claim 4 wherein the substituted poly(arylene oxide) polymer consists essentially of structural units of formula I.

9. The process of claim 8 wherein the membrane contains at least about 50 weight percent, based upon the total weight of the membrane, of at least one substituted poly(arylene oxide) polymer.

10. The process of claim 9 wherein the membrane contains at least one substituted poly(arylene oxide) polymer in combination with a compatible polymer.

11. The process of claim 10 wherein the compatible polymer is poly(aryl sulfone) or poly(2,6-dimethyl-p-phenylene oxide).

12. The process of claim 8 wherein the membrane contains at least about 75 weight percent, based upon the total weight of the membrane, of at least one substituted poly(arylene oxide) polymer.

13. The process of claim 12 wherein the membrane is a hollow fiber.

14. The process of claim 13 wherein the membrane has a thickness less than about 10 mils.

15. The process of claim 8 wherein the membrane contains essentially ring-brominated poly(2,6-dimethyl-p-phenylene oxide).

16. The process of claim 1 wherein the membrane is cast as a coating on a substrate.

17. The process of claim 15 wherein the coated substrate is a hollow fiber.

18. The process of claim 1 wherein the gases in said mixture are selected from the group consisting of hydrogen, helium, oxygen, nitrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, ammonia, water vapor and C₁ to C₄ hydrocarbons.

19. In a process for the separation of gases from a mixture containing at least two gases into two fractions, one fraction being enriched with at least one of said gases and the other fraction being depleted in same, the process comprising:

contacting the gaseous mixture with a semipermeable membrane in such a manner that a portion of the gaseous mixture selectively passes through the membrane resulting in the enriched fraction being on one side of the membrane and the depleted fraction being on the other side of the membrane, the improvement comprising

the use of a semipermeable membrane containing at least about 50 weight percent, based upon the total weight of the membrane, of at least one substituted poly(arylene oxide) copolymer containing from about 80 to 95 mole percent of structural units of the formula ##STR13## and from about 5 to 20 mole percent of structural units of the formula ##STR14##

20. The process of claim 19 wherein the substituted poly(arylene oxide) copolymer contains 95 mole percent of the structural units of formula III and 5 mole percent of the structural units of formula IV.

21. The process of claim 19 wherein the membrane contains 100 weight percent of the copolymer formed by structural units of formula III and formula IV.

22. The process of claim 21 wherein the gaseous mixture is air.

23. The process of claim 21 wherein the gaseous mixture is natural gas.

24. The process of claim 19 wherein the membrane is cast as a coating on a substrate.

25. The process of claim 24 wherein the coated substrate is a hollow fiber.

26. The process of claim 19 wherein the membrane is a hollow fiber.

27. The process of claim 26 wherein the membrane has a thickness less than about 10 mils.

28. The process of claim 19 wherein the gases in said mixture are selected from the group consisting of hydrogen, helium, oxygen, nitrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, ammonia, water vapor and C₁ to C₄ hydrocarbons.