Disinfection and sterilizing solution of peracetic acid and nitric acid

• US 4,587,264 A
• Filed: 02/03/1983
• Issued: 05/06/1986
• Est. Priority Date: 02/24/1982
• Status: Expired due to Term

• Current Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Original Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Inventors: Jourdan-Laforte, Eric, Le Rouzic, Daniel
• Primary Examiner(s): Friedman, Stanley J.
• Application Number:
  US06/463,617
• Time in Patent Office: 1,188 Days
• Field of Search: 424/317, 514/557
• US Class Current: 514/557
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 37/16 containing the group; Thio analogues thereof

Abstract

Commercial solutions of noncorrosive and time-stable carboxylic peracids, particularly peracetic acid, contain an acid of oxidizing nature, such as nitric acid, present in a weight percentage at least equal to that of the carboxylic peracid. Such solutions, diluted with ordinary water, are useful for the sterilization and microbiological disinfection of asceptic enclosures, and of equipment of the food industry, particularly the milk industry, with reduced risk of corrosion to the equipment.

Claims

1. A concentrated solution for dilution with chloride ion-containing water to provide a diluted non-corrosive disinfecting and sterilizing solution, said concentrated solution containing between 1 and 20% by weight of peracetic acid, further containing nitric acid in a weight percentage 3 to 5 times that of said peracetic acid.

2. The concentrated solution according to claim 1, wherein said solution contains between 2 and 5% by weight of peracetic acid.

3. The concentrated solution according to claim 2, wherein the concentration of said nitric acid is approximately 8% by weight up to 5 times the weight percentage of said peracetic acid.

4. A diluted non-corrosive disinfecting and sterilizing solution comprising the solution according to claim 3 diluted with ordinary chloride ion-containing water to provide a concentration of peracetic acid therein of between 30 and 300 mg/liter.

5. The concentrated solution according to claim 1 wherein the concentration of nitric acid is approximately 6-15% by weight.

6. The concentrated solution of claim 1 comprising approximately 2% by weight of peracetic acid and 8% by weight of nitric acid.

7. A diluted, non-corrosive disinfecting and sterilizing solution comprising the solution according to claim 6 diluted with ordinary, chloride-containing water to provide a concentration of peracetic acid of about 50 mg of peracetic acid per liter.

8. The concentrated solution according to claim 1 containing, by weight, approximately 2% peracetic acid, 6.1% acetic acid, 19.9% hydrogen peroxide, 8% nitric acid, 0.3% hydroxyethane-diphosphonic acid and 63.7% water.

9. The concentrated solution according to claim 1 wherein the concentration of said nitric acid is approximately 8% by weight up to 5 times the weight percentage of said peracetic acid.

11. A method of disinfecting and sterilizing an aseptic enclosure or a food industry apparatus or circuit, comprising applying thereto the non-corrosive disinfecting and sterilizing solution according to claim 9.

10. A method of preparing a disinfecting and sterilizing solution of a carboxylic peracid comprising introducing nitric acid into a 2-5% by weight commercial solution of peracetic acid, said nitric acid being added in such an amount that its weight percentage in the mixture corresponds to 3 to 5 times that of said peracetic acid;

then mixing the resultant solution with ordinary water until a concentration of peracetic acid of between 30 and 300 mg/liter is obtained.