Methods of manufacturing abrasive articles

• US 4,588,420 A
• Filed: 07/22/1982
• Issued: 05/13/1986
• Est. Priority Date: 07/22/1982
• Status: Expired due to Fees

• Current Assignee: Ramron-Bancroft Incorporated
• Original Assignee: Superior Finishes, Inc.
• Inventors: Charvat, Vernon K.
• Primary Examiner(s): Derrington, James
• Application Number:
  US06/399,592
• Time in Patent Office: 1,391 Days
• Field of Search: 51/295, 51/298, 523/139, 264/71, 264/162
• US Class Current: 51/298
• CPC Class Codes: B24D 13/00 Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor
• CPC Class Codes: B24D 18/0009 using moulds or presses
• CPC Class Codes: B29C 39/025 for making multilayered articles
• CPC Class Codes: B29C 39/10 incorporating preformed parts or layers, e.g. casting around inserts or for coating articles coating a surface by casting in general B05D1/30, B29C39/126 takes precedence
• CPC Class Codes: B29C 67/244 by vibrating the composition before or during moulding
• CPC Class Codes: B29C 70/64 the filler influencing the surface characteristics of the material, e.g. by concentrating near the surface or by incorporating in the surface by force
• CPC Class Codes: B29K 2063/00 Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
• CPC Class Codes: B29L 2031/736 Grinding or polishing equipment
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives

Abstract

New molded products and methods of manufacturing the same are described. More particularly, the molded products comprise thermoset resins and intimately dispersed inorganic solid particles, and the method comprises in its broadest sense, preheating a thermosetting organic resin and a catalyst for the resin to a temperature sufficient to reduce the viscosity of the resin and catalyst to that of a very fluid liquid, and also preheating discrete inorganic solid particulates prior to mixing of the particulates with the fluid resin-catalyst mixture. Such regulated preheating of the resin, catalyst and particulates results in improved wetting of the particulates with the resin-catalyst mixture and in the release of air bubbles during the mixing operation thereby resulting in molded products having improved properties, particularly products wherein the resin is in relatively unstressed and unflawed condition. Various molded products, including filters, molds, and abrasive articles such as grinding wheels are described.

Claims

1. The method of making molded abrasive articles comprising thermoset resins and discrete abrasive particles which comprises the steps of

(a) preheating a thermosetting organic resin and a catalyst for the resin to a temperature sufficient to reduce the viscosity of the resin and catalyst to less than 10 centipoises, the amount of resin and catalyst being at least 2.5% by volume in excess of that required to fill the interstices between the abrasive particles,

(b) preheating the discrete abrasive particles to a temperature above about 60°

C.,

(c) mixing such heated abrasive particles with such preheated resin-catalyst mixture with agitation to wet such abrasive particles with the resin-catalyst mixture and release gas bubbles to form a flowable mixture free of abrasive particle agglomerations,

(d) discharging said flowable mixture into an open mold permitting continued release and escape of gas bubbles from such resin-catalyst and the particles in such mixture to settle to concentrate such particles closely together with the interstices therebetween substantially filled with such resin-catalyst mixture and thereby forming a thin upper superficial layer of substantially abrasive-free resin catalyst mixture above such concentrated particles in such mold, and

(e) curing the mixture in the mold to a solid article of desired shape.

2. The method of claim 1 wherein the thin superficial layer is machined off from the cured article obtained in step (e).

3. The method of claim 1 wherein the mold is vibrated to settle and concentrate such particles prior to curing in step (e).

4. The method of claim 3 wherein such particles are thus concentrated at least as closely as the dry pack density thereof.

5. The method of claim 2 wherein the resin-catalyst mixture is employed in an amount of from about 2.5% to about 10% by volume in excess of that required to fill the interstices between such particles.

6. The method of claim 1 wherein said resin is an epoxy resin.

7. The method of claim 6 wherein such mold is shaped to form an abrasive wheel, and the thin superficial layer of substantially abrasive-free resin is subsequently machined off from the side of the cured abrasive wheel thus produced.